• International Journal of Industrial Entomology and Biomaterials
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• 제10권2호
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• pp.107-117
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• 2005

Oral supplementation of minerals mixture of potassium bromide and nickel sulphate on $CSR_2,\;CSR_4\;and\;CSR_2{\times}CSR_4$ crossbreed races with different concentrations (70, 110 and $160\;{\mu}g/ml$) were fed to the fifth instar larvae. Two of the four normal feeds per day was substituted with treated leaves fed to silkworm at fifth instar larvae. The controls were fed with the leaves sprayed with distilled water and normal leaves. The $CSR_4$ race treated larvae showed a significant increase in silkgland weight, cocooning percentage, female cocoon weight, male cocoon weight, male cocoon shell weight, male cocoon shell ratio, filament length, filament weight, denier, fecundity, number of eggs per ovariole and length of the ovariole when compared with those of the corresponding parameters of the carrier control, whereas in $CSR_2\;and\;CSR_2{\times}CSR_4$ crossbreed races showed a significant increase in larva1 weight and other parameters similar to that of $CSR_4$ race. The results suggested that the silkgland showed good response to minerals mixture of potassium bromide and nickel sulphate only in $CSR_4$ race when compared with those of other two races of the silkworm, B. mori.

• Membrane and Water Treatment
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• 제2권4호
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• pp.267-279
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• 2011

At steady state, the simultaneous transport of sulphuric acid and nickel sulphate through an anion-exchange membrane Neosepta-AFN (Astom Corporation, Tokyo, Japan) was investigated in a two-compartment counter-current dialyzer with single passes. The transport was quantified by the recovery yield of acid, rejection of salt and four phenomenological coefficients, which were correlated with the acid and salt concentrations in the feed. The phenomenological coefficients were determined by the numerical integration of the basic differential equations describing the concentration profiles of the components in the dialyzer. This integration was combined with an optimizing procedure. The experiments proved that the acid recovery yield is in the limits from 63 to 91 %, while salt rejection is in the limits from 79 to 97 % in the dependence on the volumetric liquid flow rate and composition of the feed.

• 한국표면공학회지
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• 제29권6호
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• pp.724-727
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• 1996

Electrolytic impregnation of nickel hydroxide into porous sintered nickel plaque from various nickel solutions were carried out at room or high temperatures and current density range of 2.5mA $cm^{-2}$ to 25mA $cm^{-2}$. The morphology of the deposited surface was observed with an electron microscope and the surface products were analyzed by means of X-ray diffraction method. Nickel hydroxide was deposited in nickel nitrate electrolyte, while deposits from sulphate or chloride solutions were almost metallic nickel. The loading level of nickel hydroxide from nitrate solutions was 1.6g$cm^{-3}$ void volume and the appearance of the surface was good quality. Discharge capacity of prepared electrodes in nickel nitrate electrolyte was larger than that of the others bath. It was considered that the cell capacity was dependent on the surface roughness of active material.

• 한국결정성장학회지
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• 제27권5호
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• pp.268-273
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• 2017

In this study, nickel hydroxide crystalline powders were synthesized by continuous reaction in the taylor fluid flow using nickel chloride, nickel sulphate and sodium hydroxide as raw materials and compared with those prepared by a conventional batch type reaction. The crystallinity of nickel hydroxide prepared by the Taylor fluid flow reaction was higher than that of nickel hydroxide obtained by batch reaction. The particle size of nickel hydroxide decreased about 2.5 to 3.6 times, and the specific surface area was increased.

• 자원리싸이클링
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• 제2권4호
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• pp.23-26
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• 1993

This work is carried out to develop the recovery process of vanadium as vanadium pentoxide and nickel as nickel sulphate from the leaching solution of heavy oil fly ash. First, sodium chlorate solution was added to the leaching solution to oxidize vanadium ions. With adjusting pH of the solution and heating, vanadium ions(V) is hydrated and precipitated as red cake of $V_2O_5$ from the solution. After recovering vanadium, nickel is recovered as ammonium nickel sulfate with crystallization process. From this nickel salt, nickel sulfate which meets the specifications for the electroplating industry can be produced economically. More than 85% of vana-dium and nickel in the fly ash are recovered in this process.

• 자원리싸이클링
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• 제14권6호
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• pp.16-20
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• 2005

구리, 니켈 그리고 코발트를 함유한 용액으로부터 구리를 선택적으로 분리하기 위하여 $Na_{2}S$를 첨가하여 구리를 CuS로 침전시키는 연구를 행하였다. 구리의 침전율은 용액의 pH가 높을수록, 첨가한 $Na_{2}S$의 양이 많을수록,농도가 낮을수록, 반응온도와 반응시간이 증가할수록 증가하였다. pH 1, $20\%\;Na_{2}S$ 첨가량이 구리의 3 당량비, 온도 $25^{\circ}C$ 그리고 반응시간 30분에서 구리의 침전율은 $94.1\%$이었으며 니켈과 코발트도 각각 $4.3\%$와 $4.5\%$가 침전되었다. 즉 일부 니켈과 코발트 이온이 같이 공침되기 때문에 정량적으로 구리만을 침전, 분리하는 것은 가능하지 않았다.

• 한국표면공학회지
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• 제22권4호
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• pp.161-167
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• 1989

Effects of bath composition on electroless deposition of Ni-W-B from sulphate solution were invesrigated in terms of deposition kinetics, electro resistivity and composition of deposit film. The microstruigated and crystataine structure of the films were also studied using a scanning electron microscope and X-ray diffractometer. The deposition rate increased linearly with increasing the concentration of nickel sulphate in bath solution, wheras the rate decreasing with sodium citrate. The rate was also affected by sodium tungstate, which was maaximum at the concentration of 0.06 M/1 in sodium tungstate, The content of W in the deposit increased with increased with increasing the sodium citrate had on opposite effect on the composition of W and B in the deposit. The crystal change film from armorphous to cryatallicne nature by heat treatments was proved by the reduction of specific resistance and X-ray diffration.

• 한국초전도ㆍ저온공학회논문지
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• 제23권3호
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• pp.37-40
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• 2021

Nickel (Ni) is a kind of the rare earth resources. Since Ni-containing waste is drained after several plating operations in the factories, the effective recycling technique has been expected to be introduced. An actual magnetic separation technique using HTS bulk magnet generating the strong magnetic field has succeeded in collecting the paramagnetic slurry containing Ni-sulphate coarse crystals which were fabricated from the Ni-plating waste. The Ni compound in the collected slurry was identified as NiSO₄/6H₂O, showing slight differences in the particle size and magnetic susceptibility between the samples attracted and not-attract to the magnetic pole. This preferential extraction suggests us a novel recycling method of Ni resource because the compound is capable of recycling back to the plating processes as a raw material.

• Membrane and Water Treatment
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• 제1권3호
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• pp.171-179
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• 2010

The transport of selected salts of sulphuric acid (cobalt, copper, iron(II), manganese, nickel and zinc sulphate) through an anion-exchange membrane Neosepta-AFN was investigated in a counter-current continuous dialyzer at various salt concentrations and volumetric liquid flow rates. The basic transport characteristics - the rejection coefficient of salt and the permeability of the membrane - were calculated from measurements at steady state. The salt concentration in model mixtures was changed in the limits from 0.1 to 1.0 kmol $m^{-3}$ and the volumetric liquid flow rate of the inlet streams was in the limits from $8{\times}10^{-9}$ to $24{\times}10^{-9}m^3\;s^{-1}$. Under the experimental conditions given, the rejection coefficient of salts tested was in the range from 65% to 94%. The lowest values were obtained for iron(II) sulphate, while the highest for copper sulphate. The maximum rejection of salt was reached at the highest volumetric liquid flow rate and the highest salt concentration in the feed. The permeability ($P_A$) of the Neosepta-AFN membrane for the individual salts was in the range from $0.49{\times}10^{-7}m\;s^{-1}$ to $1.8{\times}10^{-7}m\;s^{-1}$ and it can be described by the following series: $P_{FeSO_4}$ < $P_{NiSO_4}$ < $P_{ZnSO_4}$ < $P_{CoSO_4}$ < $P_{MnSO_4}$ < $P_{CuSO_4}$. The permeability of the membrane was strongly affected by the salt concentration in the feed - it decreased with an increasing salt concentration.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 추계학술대회 초록집
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• pp.100-100
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• 2011

Nanomaterial architecture with highly ordered, vertically oriented $TiO_2$ nanotube arrays shows a good promise for diverse technological applications. As inspired from the literature reports that Nickel modification can improve the photocatalytic activity of $TiO_2$, it was planned to coat Ni into the $TiO_2$ matrix. In this study, first $TiO_2$ nanotubes(TiNTs) were prepared by anodization (60V,3min) in HF-free aqueous electrolyte on ultrasonically cleaned polished titanium sheet substrates ($1{\times}7cm^2$). The typical thickness of the sintered TiNT ($500^{\circ}C$for10min) was ~1 micronas confirmed from the FESEM study. In the next part, as-anodized and sintered TiNT/Ti photoanodes were used to coat Ni by AC electrodeposition from aqueous 0.1M nickel sulphate solution. During AC electrodeposition, conditions such as 1V DC offset voltage, 9V amplitude (peak-to-peak) and 750 Hz frequency were fixed constant and the deposition time was varied as 0.5 min, 1 min, 2 min and 10 min. The photoelectrochemical performance of pristine and Ni modified TiNT/Ti photoanodes was measured in 1N NaOH electrolyte under 1 SUN illumination in the potential range of -1V and 1.2V versus Ag/AgCl reference electrode. The photocurrent performance of TiNT/Ti photoanode decreased upon Ni modification and the results were confirmed after repeated experiments. This suggests us that Ni modification inhibits the photoelectrochemical performance of $TiO_2$ nanotubes.