• Journal of Industrial and Engineering Chemistry
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• v.68
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• pp.1-5
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• 2018

In this study, we designed and synthesized novel thermal radical initiators of BTAP (1-phenyl-3,3-dipropyltriazene), BTACP (1-(phenyldiazenyl)pyrrolidine), BTACH (1-(phenyldiazenyl)piperidine), and BTACH7 (1-(phenyldiazenyl)azepane) based on a triazene moiety to provide a thermal initiator for radical polymerization. The synthetic method is valuable due to the simplicity. In addition, the synthesized thermal initiator did not affect the color of the polymer. Among the four initiators, the polymerization time for the BTACH of the 6-membered ring decreased by 67%, as opposed to the polymerization time without initiator. Conversion after polymerization was over 92%. DSC experiments also showed that the initiator with hexagonal rings had the lowest peak polymerization temperature of $160^{\circ}C$. Our study suggests a promising new initiator system that is effective for radical polymerization.

• Journal of Astronomy and Space Sciences
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• v.36 no.3
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• pp.105-113
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• 2019

Spectroscopic observations of barium star ${\zeta}$ Capricornus (HD204075) obtained at the 8.2 m telescope of the European Southern Observatory, with a spectral resolving power R = 80,000 and signal to noise ratio greater than 300, were used to refine the atmospheric parameters. We found new values for effective temperature ($T_{eff}=5,300{\pm}50K$), surface gravity ($log\;g=1.82{\pm}0.15$), micro-turbulent velocity ($v_{micro}=2.52{\pm}0.10km/s$), and iron abundance ($log\;N(Fe)=7.32{\pm}0.06$). Previously published abundances of chemical elements in the atmosphere of HD204075 were analyzed and no correlations of these abundances with the second ionization potentials of these elements were found. This excludes the possible influence of accretion of hydrogen and helium atoms from the interstellar or circumstellar environment to the atmosphere of this star. The accretion of nuclear processed matter from the evolved binary companion was primary cause of the abundance anomalies. The young age of HD204075 allows an estimation of the time-scale for the creation of the abundance anomalies arising from accretion of interstellar hydrogen and helium as is the case of stars with low magnetic fields; which we estimate should exceed $10^8$ years.

• The Bulletin of The Korean Astronomical Society
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• v.44 no.1
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• pp.83.3-83.3
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• 2019

New high-resolution spectra and multi-band photometric data of BS Cas were obtained at the Bohyunsan Optical Astronomy Observatory in 2018 and at the Jincheon Station of the Chungbuk National University Observatory in 2011, respectively. We measured the radial velocities (RVs) for both components, and the effective temperature of the more massive star was determined to be $6262{\pm}56K$. In addition, historical light curves showed strong time-dependant light variations at the total eclipse. These variations were modeled by a cool spot on the more massive component. Finally, the physical parameters of BS Cas by a simultaneous analysis of our RV curves with the photometric light curves were presented. Individual masses and radii of both components were deduced as $M_1= 0.59{\pm}0.07M_{\odot}$, $M_2=1.47{\pm}0.15M_{\odot}$, $R_1=0.94{\pm}0.03R_{\odot}$ and $R_2=1.47{\pm}0.05R_{\odot}$.

• Journal of The Geomorphological Association of Korea
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• v.25 no.1
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• pp.47-65
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• 2018

Frost shattering has traditionally been considered as one of the most effective process in rock weathering. Each slab specimens of five or six rhyolite, basalt and tuff was prepared and put in freeze-thaw cycles and repeated 300 times in the temperature of $-25^{\circ}C$ to $+30^{\circ}C$ and their weathering patterns and products were analyzed by surface observation, particle size, XRD and thin section. As the result, some changes were observed in weathering patterns and weathering products. Rock shattering was more active in waterlogging rather than atmospheric conditions, but there are many differences depending on the type of rock. Rhyolite is hardly weathered by 300 times freeze-thaw cycles and generates the least amount of weathering products. Weathering of Basalt is limited to the surface layer where water can be absorbed, and produces a few amount of platy-shape debris. Tuff are separated by blocky structure which the particles are aggregated along their edges rather than enlarged existing cracks/joins or generated new joints.

• Journal of Platform Technology
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• v.8 no.1
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• pp.3-9
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• 2020

In Korea, 63% of the nation's land is made up of forests, and the average temperature of the earth has been increasing. Forest service has been operating a proactive control system for preventing the spread of forest pests such as Pine wilt disease. but there were some hurdles in timely control due to weather, topography and manpower management difficulties. In this paper, we propose a model for building fast, accurate and efficient control system by categorizing the damage and dead wood automatically based on the images acquired using small unmanned aerial vehicles based on information and communication technology. In particular, the proposed model establishes an effective response system for government affairs through cooperation in the private sector. It can also create new jobs in the unmanned aerial vehicle business and service industries.

• Tribology and Lubricants
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• v.36 no.6
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• pp.350-358
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• 2020

Hot stamping is an effective and suitable process widely used in automotive applications, though critical issues such as the transfer of the coating materials and build-up of these materials on tool surfaces have been encountered. Past researches figured out the resultant wear phenomenon using pin-on-disc and drawing (for example, strip drawing and deep drawing) methods to mimic the process and analyzed the wear behavior with respect to the influencing factors such as surface coating, load, and roughness. Although the pin-on-disc is a conventional and widely-used method, it presented a methodological limitation when simulating the hot stamping process by forming a new blank each time, and hence, a drawing-based friction method has been proposed and developed. Each drawing method applies loads in a different way, resulting in a different wear behavior. Notably, the deep drawing process is most similar to the hot stamping process compared to other drawing methods. In this paper we present a review of the friction testing methods mimicking the hot stamping process and the associated wear behavior. This can be helpful in presenting a step-by-step approach and different perspectives on the wear behavior in the hot stamping process.

• Nuclear Engineering and Technology
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• v.54 no.2
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• pp.764-769
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• 2022

The United Arab Emirates is currently building and operating four units of the APR-1400 developed by a South Korean vendor, Korea Electric Power Corporation (KEPCO). This paper attempts to perform APR-1400 reactor core analysis by using the well-known two-step method. The two-step method was applied to the APR-1400 first cycle using the open-source nodal diffusion code, KOMODO. In this study, the group constants were generated using CASMO-4 fuel transport lattice code. The simulation was performed in Hot Zero Power (HZP) at steady-state and transient conditions. Some typical parameters necessary for the Nuclear Design Report (NDR) were evaluated in this paper, such as effective neutron multiplication factor, control rod worth, and critical boron concentration for steady-state analysis. Other parameters such as reactivity insertion, power, and fuel temperature changes during the Reactivity Insertion Accident (RIA) simulation were evaluated as well. The results from KOMODO were verified using PARCS and SIMULATE-3 nodal core simulators. It was found that KOMODO gives an excellent agreement.

• Membrane and Water Treatment
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• v.13 no.3
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• pp.129-137
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• 2022

In this study, the removal of Ciprofloxacin (CPX) from aqueous solutions was investigated by a new activated carbon adsorbent prepared from orange peel (ACOP) with chemical activation using ZnCl₂. The physicochemical properties of orange peel activated carbon were characterized by proximate and ultimate analysis, scanning electron microscopy, BET surface area determination and Fourier transformation infrared spectroscopic studies. According to Brunauer-Emmett-Teller isotherm and non-local-density functional theory, the cumulative surface area, pore volume and pore size of ACOP were determined as 1193 m² g^-1, 0.83 cc g^-1 and 12.7 Å, respectively. The effects of contact time, pH, temperature and ACOP dose on the batch adsorption of CPX were studied. Adsorption equilibrium data of CPX with ACOP were found to be compatible with both the Langmuir and Freundlich isotherms. CPX adsorption capacity of ACOP was calculated as 181.8 mg g^-1 using Langmuir isotherm. The CPX adsorption kinetics were found to be harmonious with the pseudo-second-order kinetic model. Conclusively, ACOP can be assessable as an effective adsorbent for the removal of ciprofloxacin (CPX) from aqueous solutions.

• Current Optics and Photonics
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• v.7 no.3
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• pp.273-282
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• 2023

This paper presents a new method for redistributing effectively the first orders of each lens element to achromatize and athermalize an optical system, by introducing a novel method for adjusting the slope of an achromatic and athermal line. This line is specified by connecting the housing, equivalent single lens, and aberration-corrected point on a glass map composed of available plastic and glass materials for molding. Thus, if a specific lens is replaced with the material characterized by the chromatic and thermal powers of an aberration-corrected point, we obtain an achromatic and athermal system. First, we identify two materials that yield the minimum and maximum slopes of the line from a housing coordinate, which specifies the slope range of the line spanning the available materials on a glass map. Next, redistributing the optical first orders (optical powers and paraxial ray heights) of lens elements by moving the achromatic and athermal line into the available slope range of materials yields a good achromatic and athermal design. Applying this concept to design a mobile-phone camera lens, we efficiently obtain an achromatic and athermal system with cost-effective material selection, over the specified temperature and waveband ranges.

• Journal of Ceramic Processing Research
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• v.13 no.spc2
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• pp.428-432
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• 2012

Polyamidimide (PAI)-colloidal silica (CS) nanohybrid films were synthesized by an advanced sol-gel process. The synthesized PAI-CS hybrid films have a uniform and stable chemical bonding and there is no interfacial defects observed by TEM. The thermal degradation ratio of PAI-CS (10 wt%) hybrid films is delayed by 100 ℃ compared with pure PAI sample determined by on set temperature range in TGA. The dielectric constant of PAI-CS (10 wt%) hybrid films decreases with increasing CS content up to about 5 wt% but increases at higher CS content, which is not explained simply by effective medium therories (EMT). The duration time of PAI-CS (10 wt%) hybrid coil is 38 sec, which is very longer than that of pure PAI coil sample. The PAI-CS (10 wt%) hybrid film has a higher breakdown voltage resistance than the pure PAI film at surge environment and exhibits superior heat resistance. The PAI-CS (10 wt%) sample shows the advanced and stable thermal emission properties in transformer module compared with the pure PAI sample. This result illustrates that the advanced thermal conductivity and expansion properties of PAI-CS sample in the case of appropriate sol-gel processes brings the stable thermal emission in transformer system. Therefore, new PAI-CS hybrid samples with such stable thermal emission properties are expected to be used as a high functional coating application in ET, IT and electric power products.