• Title/Summary/Keyword: near-ring

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Crystallographic Studies of $Ag^+$-and $Ca^{2+}$- Exchanged Zeolite A Reacting with Rubidium Vapor (루비듐 증기와 반응한 $Ag^+$ 이온과 $Ca^{2+}$ 이온으로 치환된 제올라이트 A의 결정학적 연구)

  • Han, Young-Wook;Song, Seong-Hwan;Kim, Yang
    • Journal of the Mineralogical Society of Korea
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    • v.4 no.1
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    • pp.22-31
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    • 1991
  • Three crystal structures of dehydrated $Ag^+$-and $Ca^{2+}$- exchanged zeolite $A(Ag_4Ca_4-A,\;Ag_^Ca_3-A,\;and\;Ag_8Ca_2-A)$ treated at 250${\circ}C$ with 0.1 Torr of Rb vapor have been determined by single-crystal x-ray diffraction techniques in the cubic space group Pm3m at 21(1)${\circ}C$ (a=12,271(1)${\AA}$, 12.255(1)${\AA}$, and 12.339(1)${\AA}$, respectively). Their structures were refined to the final error indices. R(weighted) of 0.072 with 130 reflections, 0.050 with 110 reflections, and 0.083 with 86 reflections, respectively, for which $I>3{\rho}(I)$. In each structure, Rb species are found at three different crystallographic sites:3$Rb^+$+ions per unit cell are located at 8-ring centers, ca. 5.6 to 6.4 $Rb^+$ ions are found opposite 6-rings on threefold axes in the large cavity, and ca. 2.5 to 3.0 $Rb^+$ ions are found on threefold axes in the sodalite unit. Also, Ag species are found at two different crystallographic stites: ca. 0.7 to 2.1 $Ag^+$ lie opposite 4-rings and ca. 2.2 to 4.8 Ag atoms are located near the center of the large cavity. In these structures, the numbers of Ag atoms per unit cell are 2.2, 2.4, and 4.8, respectively, and these may form hexasilver clusters at the centers of the large cavities. The $Rb^+$ ions, by blocking 8-rings, may have prevented silver from migrating out of the structure. Each hexasilver cluster is stabilized by coordination to up to 13 $Rb^+$ions. An excess absorption of about 0.8 Rb atom per unit cell indicates that the presence of a triangular symmetric $(Rb_3)2^{+}$ cation in sodalite cavity. At least one large-cavity six-ring $Rb^+$ ion must necessarily approach this cluster and may be viewed as a member of it to give $(Rb)_4^{3+}$, $(Rb)_5^{4+}$ or $(Rb)_6^{5+}$.

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Palaeomagnetism of Cretaceous Rocks in the Ǔisǒng Area, Kyǒngsang Basin, Korea (의성지역 백악기 암석에 대한 고자기 연구)

  • Kim, In-Soo;Lee, Hyun Koo;Yun, Hyesu;Kang, Hee-Cheol
    • Economic and Environmental Geology
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    • v.26 no.3
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    • pp.403-420
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    • 1993
  • The Cretaceous Kyongsang Basin is known to be composed of several tectonic blocks (or subbasins) with each distinct stratigraphic succession. The study area represents a major part of one of these blocks, i. e. the $\check{U}is\check{o}ng$ block. The area is charaterized by a suite of WNW-trending sinistral strike-slip faults as well as a number of ring faults. A total of 292 independently oriented core samples were drilled from 23 sites, covering virtually all the formations of the Cretaceous $Ky\check{o}ngsang$ Supergroup. Alternating field and thermal demagnetization experiments were conducted to reveal the primary magnetization. Due to the homoclinal nature of the strata in the area, it was not possible to make use of the conventional fold test It is, however, believed that the primary remanent components have been obtained from the majority of the formations, considering the similarity of the palaeomagnetic pole positions with those of contemporary strata of other blocks and the existence of antiparallel reversed remanence. It was found neither any significant difference in magnetic declination on each side of the strike-slip faults nor systematic change of magnetic declination with distance from the fault-line. This does not support such a block rotation hypothesis associated with the strike-slip faulting in the area as alleged by some authors. The samples from the outcrops on or near the fault-lines were severely overprinted by the recent magnetic fields regardless of age and lithology. Epithermal Au-Ag-Cu-Pb-Zn mineralizations are known along some fault lines in the area. It is interpreted that these two facts are closely related with fluid circulations along the fracture zones caused by fault activities. In regard to the age of the strata as deduced from the magnetostratigraphic consideration, the $Ch\check{o}mgok$ formation and the lower strata should be older than Barremian or 124 Ma. The age of volcanics of the $Yuch^{\prime}\check{o}n$ Group sampled in this study should be younger than Campanian or 83 Ma.

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Cure and Mechanical Behaviors of Cycloaliphatic/DGEBA Epoxy Blend System using Electron-Beam Technique (전자선 조사에 의한 고리지방족/DGEBA 에폭시 블렌드 시스템의 경화 및 기계적 특성)

  • 이재락;허건영;박수진
    • Polymer(Korea)
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    • v.27 no.3
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    • pp.210-216
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    • 2003
  • 4-Vinyl-1-cyclohexene diepoxide (VCE)/diglycidyl ether of bisphenol-A (DGEBA) epoxy blends with benzylquinoxalinium hexafluoroanti-monate were cured using an electron-beam technique. The effect of DGEBA content to VCE on cure behavior, thermal stabilities, and mechanical properties was investigated. The composition of VCE/DGEBA blend system vaned within 100:0, 80:20, 60:40, 40:60, 20:80, and 0:100 wt%. The cure behavior and thermal stability of the cured specimens was monited by near-infrared spectroscopy and thermogravimetric analysis, respectively. Also, the critical stress intensity factor ($_{4}$) test of the cured specimens was performed to study the mechanical interfacial properties. As a result, the decreases of short side-chain structure and chain scission were observed in NIR measurements as the DGEBA content increases, resulting in varying the hydroxyl and carbonyl groups. And, the initial decomposition temperature (IDT), temperature of maximum weight loss (T$\_$max/), and decomposition activation energy (E$\_$d/) as thermal stability factors were increased with increasing the DGEBA content. These results could be explained by mean of decreasing viscosity, stable aromatic ring structure, and grafted interpenetrating polymer network with increasing of DGEBA content. Also, the maximum $_{4}$ value showed at mixing ratio of 40:60 wt% in this blend system. in this blend system.

Optical Design of an Inspection Apparatus for Dynamic Visual Acuity (동체시력 검사기의 광학계 설계)

  • Lee, Dong-Hee;Kim, Hye-Dong
    • Journal of Korean Ophthalmic Optics Society
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    • v.9 no.2
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    • pp.473-480
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    • 2004
  • Recently, they are interested in the relation between night's vehicle accidents of drivers and the dynamic visual acuity at home and aboard. So, in this research, we tried to design an optical system of the inspection equipment to measure the dynamic visual acuity. A optotype standard did to Landolt's ring with 45mm of diameter and 9mm of gap to maintain the visual acuity of 1.0 in the 30m distance. An optical structure of the inspection equipment was composed of the sequence of an observer, a plus refraction lens system, a minus refraction lens system, and an optotype that was arranged to have characteristics that the size of the first virtual image of the optotype made by the minus refraction lens system grows bigger gradually according to the optotype movement to near distance from far distance, and also the first virtual image moves to the principle plane from the focal point of the plus refraction lens system as the size of the first virtual image arranged to the inside of focal distance of plus refraction lens system grows bigger gradually. As doing these processes, we completed the optical system of which characteristic is that the position of the final second virtual image moves to 3m from 50m as the size of the second virtual image made by the plus refraction lens system maintains to be regular.

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Growth Variation among the Different Populations of Sea Urchin, Pseudocentrotus depressus (분흥성게의 지역별 개체군 성장에 관한 연구)

  • CHUNG Sang-Chul;NATSUKARI Yutaka
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.28 no.4
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    • pp.421-427
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    • 1995
  • To know the variation in the growth of the sea urchin, Pseudocentrotus depressus according to their localities, three different populations including the culture populations, the released populations, and the wild populations were investigated using the cluster analysis. For this purpose, pigment banding pattern on the genital plate was used as an age character. The population composed of the same year class was born between September 25th and October 5th every year. The population of 9 to 10 months old had no $r_1,\;whereas\;r_1$, was observed in the population of either 1 year and 10 or 11 months old, and both $r_1,\;and\;r_2$ in the population of either 2 year and 9 or 10 months old. Therefore, $r_1,\;and\;r_2$ radius were regarded as an annual ring. Growth in the culture populations was much better than that In either the released or the wild populations. However, when the cultured populations composed of 8 to 12 mm in test diameter was released to the shove near a culture farm, its growth appeared to be similar to that of the wild Populations. The wide distribution patterns of test diameter measured from the same year class of both the cultured and the wild populations were probably due to either long spawning period or growth differences between individuals. Except Yamaguchi and Cheju populations, the move closely located populations showed the more similar growth pattern. However, the growth of Cheju population appeared to be similar to that of Aba, Mogi, Toishi rather than Kasiwazima although Cheju Island was more closely located with Kasiwazima than other localities. In addition, the population of Yamaguchi, located at the highest latitute, revealed the similar growth pattern to that of Nomozaki, located at the lowest latitute.

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Crystal Structures of Vacuum Dehydrated Fully $Cd^{2+}$-Exchanged Zeolite A and of Its iodine Sorption Complex (카드뮴 이온으로 완전히 치환한 제올라이트 A를 진공 탈수한 구조와 이것에 요오드를 흡착한 결정구조)

  • Jang, Se-Bok;Han, Young-Wook;Kim, Yang
    • Korean Journal of Crystallography
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    • v.4 no.2
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    • pp.54-62
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    • 1993
  • The crystal shnture of dehydrated fully Cd2+-exchanged zeolite A evacuated at 2 × 10-6 Torr and 650℃ (a:12.189(2) A) and of its iodine sorption corrplex (a:12.168(2)A) have been netsmlmn by single uystal x-ray diffraction techliques in the cubic space group hkTn at 21(1)℃. The strutures were refined to final error indices, Ri:0.057 and R2 =0.063 with 186 reflections and Rl:0.082 and R2:0.085 with 181 reflections, respectively, for which 1>3σ(In both structure, six lie at two distinguished threefold axes of unit cell ten the crystal structure of an iodine sorption complex of Cd6-A four Cd2+ ions are recessed 0.69(1) A into the large cavity to complex each with from the (111) plane of 0(3), whereas two Cd2+ ions recessed 0.68(1) A into the sodalite unit Awximately 4.0 l3ions per nit cell are sorbed. Each bridge between a Cd2+ ion and 8-ring oxygens ((I-I-I)= 117(1) ˚ and 0(1)-I(1)-I(2)=172(1)). The near linear I-I-0 angle and its interatomic distance (I-0=3.57(3) A) are indicative of a weak charge transfer interacticn between the frarrework oxygen and iodine. The existence of In3 inside the large cavity indicates that the If ions and H ions may be produced by reaction of In vapor with water molecules which maybe associated with Cd2+ ions in partially dehydrated Cd6-A In3- ions may be produced by the combination of I- and I2.

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Geotechnical Engineering Progress with the Incheon Bridge Project

  • Cho, Sung-Min
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.133-144
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    • 2009
  • Incheon Bridge, 18.4 km long sea-crossing bridge, will be opened to the traffic in October 2009 and this will be the new landmark of the gearing up north-east Asia as well as the largest & longest bridge of Korea. Incheon Bridge is the integrated set of several special featured bridges including a magnificent cable-stayed girder bridge which has a main span of 800 m width to cross the navigation channel in and out of the Port of Incheon. Incheon Bridge is making an epoch of long-span bridge designs thanks to the fully application of the AASHTO LRFD (load & resistance factor design) to both the superstructures and the substructures. A state-of-the-art of the geotechnologies which were applied to the Incheon Bridge construction project is introduced. The most Large-diameter drilled shafts were penetrated into the bedrock to support the colossal superstructures. The bearing capacity and deformational characteristics of the foundations were verified through the world's largest static pile load test. 8 full-scale pilot piles were tested in both offshore site and onshore area prior to the commencement of constructions. Compressible load beyond 30,000 tonf pressed a single 3 m diameter foundation pile by means of bi-directional loading method including the Osterberg cell techniques. Detailed site investigation to characterize the subsurface properties had been carried out. Geotextile tubes, tied sheet pile walls, and trestles were utilized to overcome the very large tidal difference between ebb and flow at the foreshore site. 44 circular-cell type dolphins surround the piers near the navigation channel to protect the bridge against the collision with aberrant vessels. Each dolphin structure consists of the flat sheet piled wall and infilled aggregates to absorb the collision impact. Geo-centrifugal tests were performed to evaluate the behavior of the dolphin in the seabed and to verify the numerical model for the design. Rip-rap embankments on the seabed are expected to prevent the scouring of the foundation. Prefabricated vertical drains, sand compaction piles, deep cement mixings, horizontal natural-fiber drains, and other subsidiary methods were used to improve the soft ground for the site of abutments, toll plazas, and access roads. Light-weight backfill using EPS blocks helps to reduce the earth pressure behind the abutment on the soft ground. Some kinds of reinforced earth like as MSE using geosynthetics were utilized for the ring wall of the abutment. Soil steel bridges made of corrugated steel plates and engineered backfills were constructed for the open-cut tunnel and the culvert. Diverse experiences of advanced designs and constructions from the Incheon Bridge project have been propagated by relevant engineers and it is strongly expected that significant achievements in geotechnical engineering through this project will contribute to the national development of the longspan bridge technologies remarkably.

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Organotitanium Chemistry (IV). The Molecular and Electronic Structure of $TiCl(OC_6H_5)_3{\cdot}C_6H_5OH\;and\;Ti(OC_6H_5)_4{\cdot}C_6H_5OH$ (유기티탄 화학 (제4보). $TiCl(OC_6H_5)_3{\cdot}C_6H_5OH\;및\;Ti(OC_6H_5)_4{\cdot}C_6H_5OH$의 분자 및 전자구조)

  • Lee Hoosung;Uh Young Sun;Sohn Youn Soo
    • Journal of the Korean Chemical Society
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    • v.19 no.2
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    • pp.92-97
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    • 1975
  • The molecular and electronic structures of $TiCl(OC_6H_5)_3{\cdot}C_6H_5OH\;and\;Ti(OC_6H_5)_4{\cdot}C_6H_5OH$ have been studied by employing cryoscopic and electronic spectroscopic methods. The cryoscopic data have shown that the dimeric tetraphenoxytitanium(Ⅳ) phenolate in solid undergoes complete dissociation into monomer in solution and also the chlorocomplex starts dissociation around the concentration of 8 m mole/l. Therefore, these two Ti-complexes are pentacoordinated in dilute solution and the local symmetry of the titanium ion in these complexes seems to be trigonalbipyramid. The electronic spectra of $TiCl(OC_6H_5)_3{\cdot}C_6H_5OH$ and $Ti(OC_6H_5)_4{\cdot}C_6H_5OH$ each show two band, systems, one vibration-structural band characteristic of the aromatic ring in the near UV and another visible band at 26.8 kK, 29.6 kK, respectively, which are assigned as a ligand to metal charge transfer band corresponding to $^1A_1''{\to}^1E'\;or\;^1E''$ transition.

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Reduced Electrical Coupling Effect and Miniaturized Antenna Using Quasi Möbius Strip with Via-Hole (Quasi Möbius Strip과 Via-Hole 구조를 응용한 선로결합 현상의 완화 및 소형화 설계)

  • Kim, Mi Jung;Park, Seong Gyoon;Ro, Soong Hwan
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.38B no.9
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    • pp.715-721
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    • 2013
  • Minimization techniques are adaptations of Helical structure, Meta material, multi-layer structure etc. But, Helical structure is not suited to minimization technique of RF circuit having single resonant frequency. Because it generate resonant frequency following as rotation of circumference. Meta material and multi layer structure have weakness of expenditure and complex structure. In addition, conventional three dimensional M$\ddot{o}$bius Strip and planar M$\ddot{o}$bius Strip are not two dimensional planar M$\ddot{o}$bius Strip that has weakness of electrical coupling effect. Therefore, in this paper, we proposed miniaturized and reduced electrical coupling effect antenna by adaptation of Quasi M$\ddot{o}$bius Strip that topology is same as three dimensional M$\ddot{o}$bius Strip with Via-Hole structure. According to the simulation result, physical circumferential length is 1/3 minimized compared with conventional ring antenna under the same resonant frequency. In addition, coupling effect is not nearly generates near to the resonant frequency, 2.4GHz.

A Basic Study on a Magnetic Fluid Driven Artificial Heart (자성유체에 의해 구동되는 인공심장에 관한 기초연구)

  • Kim, Dong-Wook;MITAMURA, Yoshinoro
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.5
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    • pp.940-947
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    • 2006
  • A variety of actuators fur an implantable artificial heart have been studied. They, all, however, share the disadvantages of a complicated energy conversion mechanism and of the need to use bearings. A ferrofluidic actuator directly drives magnetic fluids by applying a magnetic field to these fluids; it does not require bearings. In this study, the feasibility of a ferrofluidic actuator for an implantable artificial heart was studied. An way of two Poles of ring solenoids was mounted near the acrylic tube $({\phi}\;7.4mm)$. A rubber sack (volume : $2m{\ell}$ was connected to both ends of the acrylic tube. The sack were encased in a rigid chamber that had inlet and outlet ports. The acrylic tube and the rubber sack were filled with water encased in a rigid chamber magnetic fluid and the iron cylinder were immersed in the water. Two experiment method was conducted. 1) distance between stoppers were 72mm and 2) distance between stoppers were 104mm. A stroke volume was stability and $0.96m{\ell}$ was obtained in the experiment 1 and $1.92m{\ell}$ in the experiment 2. The energy efficiency of Experiment method 2 is about five times than Experiment method 2. A magnetic fluid-driven blood pump could be feasible if the magnetic fluid with high magnetization (3 times yester than the current value) is developed.

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