• 제목/요약/키워드: near-UV

검색결과 287건 처리시간 0.029초

에너지 절약 스마트윈도우용 전기변색 재료의 개발 (The Development of Electrochromic Materials for Energy Saving Smart Windows.)

  • 조봉희;김영호
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1994년도 하계학술대회 논문집 C
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    • pp.1308-1310
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    • 1994
  • The electrochromism of $WO_3$ and $V_2O_5$ thin films have been studied. The $WO_3$ thin film is found to be cathodic coloration material and the coloration efficiency of this film is close to $60 [cm^2/C]$ in the near infrared region. The $V_2O_5$ thin film exhibits cathodic coloration in tile near infrared and anodic coloration in the blue and near UV region. The cathodic coloration in the $450{\sim}1100 nm$ wavelength range is relatively weak with a maximum coloration efficiency of $6 [cm^2/C]$).

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Synthesis and Characterization of Red Light-Emitting Random Copolymers

  • Lee, Yeong-Beom;Shim, Hong-Ku
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.1418-1421
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    • 2009
  • A series of new light-emitting random copolymers with fully conjugated structure was prepared, for the first time through the well-known Gilch polymerization between 1,4-bis(chloromethyl)-2-ethylhexyloxy-5-methoxybenzene and 2,5-bis(bromomethyl)thiophene monomers in different ratios. The synthesized polymers (on thin film) showed the maximum wavelength of UV-visible absorbance and photoluminescence (PL) near 500 nm and near 600 nm, respectively. A single-layer light-emitting diode device, which has a simple ITO (indium-tin oxide)/polymer/Al configuration, was fabricated by spin-coating of polymers and then vacuum evaporation of Al metal. The threshold bias of PMEHPVTVs was in the range of 3.5-10 V. As in the PL spectra, the maximum wavelength of light emission near 600 nm was also shown in electroluminescence (EL) spectra of PMEHPVTVs when the operating voltage was about 7 - 14 V.

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근접장 마이크로파 현미경을 이용한 Copper(II)-phthalocyanine 박막의 특성 연구 (Characterization of thin film properties of Copper(II)-Phthalocyanine using a near-field scanning microwave microscope)

  • 박미화;이기진
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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    • pp.460-463
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    • 2003
  • We report the microwave reflection coefficient $S_{11}$ of copper(II)-phthalocyanine(CuPc) using a near-field microwave microscope(NSMM) in order to understand the intrinsic electromagnetic properties of organic materials. For a NSMM system, a high-quility microstip resonator coupled with a dielectric resonator was used. The reflection coefficient $S_{11}$ was changed by the preparation conditions of CuPc thin films. We compared the reflection coefficient with crystal phase, surface morphology, UV absorption spectra and x-ray diffraction results.

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식물생장(植物生長)에 미치는 자외선(紫外線)의 효과(效果) (The Assessment of Ultraviolet Radiation in Vegetable Growth)

  • 김형옥;문두길;이신찬;김용호;송필순
    • 한국환경농학회지
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    • 제3권1호
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    • pp.63-70
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    • 1984
  • 화학적(化學的) 광양측정방법(光量測定方法)을 리용(利用)하여 제주도(濟州島)의 해변(海邊)과 해발(海拔) 1,100m 고지(高地)에서 봄부터 가을사이의 태탕광선중(太湯光線中) 자외선(紫外線) 함양(含量)을 측정(測定)한 결과(結果), 여름과 초가을의 자외선(紫外線) 함풍(含豊)은 봄에 비해서 배(倍) 이상(以上)으로 나타났으며 고지대(高地帶)에서는 더 많은 자외선(紫外線) 함양(含量)이 측정(測定)되었다. 포장조건(圃場條件)에서 UV-B부분(部分)($280{\sim}320nm$) 자외선(紫外線)의 투과률(透過率)이 서로 다른 필름을 피복(被覆)하여 대두(大豆)의 생장발육(生長發育)을 조사(調査)했는데, 광선중(光線中) UV-B의 해작용(害作用)은 인정(認定)되지 않았다. 자외선(紫外線)이 식물(植物)의 광형태형성(光形態形成)에 미치는 효과(效果)를 구명(究明)하기 위하여 미형태형성(米形態形成)에 관여하는 식물(植物)의 광수용체(光受容體) 색소(色素)인 파이토크롬에 UV-B를 쪼이면서 파이토크롬의 변화(變化)를 추적(追跡)하였던바, 분자량(分子量) 124,000인 파이토크롬은 60% Pfr, 분자양(分子量)${\sim}120,000$은 50% Pfr의 광평형(光平衡) 상태(狀態)를 보였다. 광변환중(光變換中) quantum yield는 분자양(分子量) 124,000의 파이토크롬에서는 ${\phi}r=0.016$, ${\phi}fr=0.010$이었으며 분자량(分子量)${\sim}120,000$${\phi}r={\phi}fr=0.012$였다. 포장상웅(圃場狀熊)에서 공시(供試)된 대두(大豆)에 UV-B의 해작용(害作用)이 관찰(觀察)되지 않은 것은, UV-B가 파이토크롬을 변환(變換)시켜 파이토크롬이 관여하는 방어적(防禦的) 형태형성(形態形成) 및 발육(發育)을 촉진(促進)시키기 때문이라고 추론(推論)되었다.

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NEAR INFRARED TRANSFLECTANCE SPECTROSCOPY (NIRS) IN PHYTOCHEMISTRY

  • Huck, C.W.;W.Guggenbichler;Bonn, G.K.
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.3114-3114
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    • 2001
  • During the last years phytochemistry and phytopharmaceutical applications have developed rapidly and so there exists a high demand for faster and more efficient analysis techniques. Therefore we have established a near infrared transflectance spectroscopy (NIRS) method that allows a qualitative and quantitative determination of new polyphenolic pharmacological active leading compounds within a few seconds. As the NIR spectrometer has to be calibrated the compound of interest has at first to be characterized by using one or other a combination of chromatographic or electrophoretic separation techniques such as thin layer chromatography (TLC), high performance liquid chromatography (HPLC), capillary electrophoresis (CE), gas chromatography (GC) and capillary electrochromatography (CEC). Both structural elucidation and quantitative analysis of the phenolic compound is possible by direct coupling of the mentioned separation methods with a mass spectrometer (GC-MS, LC-MS/MS, CE-MS, CEC-MS) and a NMR spectrometer (LC-NMR). Furthermore the compound has to be isolated (NPLC, MPLC, prep. TLC, prep. HPLC) and its structure elucidated by spectroscopic techniques (UV, IR, HR-MS, NMR) and chemical synthesis. After that HPLC can be used to provide the reference data for the calibration step of the near infrared spectrometer. The NIRS calibration step is time consuming, which is compensated by short analysis times. After validation of the established NIRS method it is possible to determine the polyphenolic compound within seconds which allows to raise the efficiency in quality control and to reduce costs especially in the phytopharmaceutical industry.

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Near-infrared polarimetric study of near-Earth object 252P/LINEAR: An implication of scattered light from the evolved dust particles

  • Kwon, Yuna G.;Ishiguro, Masateru;Kwon, Jungmi;Kuroda, Daisuke;Im, Myungshin;Choi, Changsu;Tamura, Motohide;Nagayama, Takahiro;Kawai, Nobuyuki;Watanabe, Jun-Ichi
    • 천문학회보
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    • 제44권2호
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    • pp.44.2-44.2
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    • 2019
  • Comets, one of the least-altered leftovers from the nascent solar system, have probably preserved the primitive structure inside, whereas their surfaces become modified from the initial states after repetitive orbital revolutions around the Sun. Resurfacing makes the surface drier and more consolidated than the bulk nuclei, creating inert refractory dust layer ("dust mantle"). Near-infrared (NIR; 1.25-2.25 m) polarimetry is theoretically expected to maximize contrast of the porosity between inner fresh and evolved dust particles, by harboring more dust constituents in the single wavelength than the optical; thus, intensifies electromagnetic interaction in dust aggregates. Despite such an advantage, only a few studies have been made in this approach mainly due to the limited accessibility of available facilities. Herein, we present our new multi-band NIR polarimetric study of near-Earth object 252P/LINEAR over 12 days near perihelion, together with the results of optical (0.48-0.80m) imaging observations and backward dynamical simulation of the comet. Based on the results, we will characterize the dust properties of the comet and discuss the possible environmental (temperature and UV radiation) effects that could produce the observed phenomena.

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스핀코팅 및 저온열처리에 의한 자외선 발광특성을 갖는 산화아연 박막의 제조 (Preparation of ZnO Thin Films with UV Emission by Spin Coating and Low-temperature Heat-treatment)

  • 강보안;정주현
    • 한국안광학회지
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    • 제13권3호
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    • pp.73-77
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    • 2008
  • 목적: 본 논문은 저온열처리로 비결정 또는 결정 ZnO 박막의 UV emission 가능하다는 것이다. 방법: 화학적 용액법을 이용하여 소다-라임-실리카 유리 위에 100, 150, 200, 250 및 $300^{\circ}C$로 열처리하여 비정질 및 나노 결정질 ZnO 박막을 제조하였으며, 박막의 성장 특성 및 광학적 특성을 X-선 회절 분석법, 자외선-가시광선-근적외선 분광법 및 발광분석법을 통하여 분석하였다. 결과: $100^{\circ}C{\sim}200^{\circ}C$에서 60분간 열처리된 박막은 비정질 특성을 나타내고 있었으며, $250^{\circ}C$$300^{\circ}C$로 열처리된 박막에서는 ZnO 결정상이 나타났다. 비정질 ZnO 박막의 PL분석에 의하면 매우 강한 Near-band-edge emission이 나타났으며, Green emission은 거의 검출되지 않았다. 결론: 앞으로는 저온에서 ZnO 광전자소자를 쉽게 제조할 수 있을 것이다.

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The first UV fundamental plane and evidence of star formation in early-type galaxies

  • Jeong, Hyun-Jin;Yi, Suk-Young;Bureau, Martin;Davies, Roger L.
    • 한국우주과학회:학술대회논문집(한국우주과학회보)
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    • 한국우주과학회 2009년도 한국우주과학회보 제18권2호
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    • pp.36.2-36.2
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    • 2009
  • We present GALEX (Galaxy Evolution Explorer) far (FUV) and near (NUV) ultraviolet imaging of 34 nearby early-type galaxies from the SAURON representative sample of 48 E/S0 galaxies, all of which have ground-based optical imaging from the MDM Observatory. The surface brightness profiles of nine galaxies (~26 per cent) show regions with blue UV-optical colours suggesting recent star formation. Five of these (~15 per cent) show blue integrated UV-optical colours that set them aside in the NUV integrated colour-magnitude relation. These are objects with either exceptionally intense and localised NUV fluxes or blue UV-optical colours throughout. They also have other properties confirming they have had recent star formation, in particular Hbeta absorption higher than expected for a quiescent population and a higher CO detection rate. This suggests that residual star formation is more common in early-type galaxies than we are used to believe. NUV-blue galaxies are generally drawn from the lower stellar velocity dispersion (sigma_e <200 km/s) and thus lower dynamical mass part of the sample. We have also constructed the first UV Fundamental Planes and show that NUV blue galaxies bias the slopes and increase the scatters. If they are eliminated the fits get closer to expectations from the virial theorem. Although our analysis is based on a limited sample, it seems that a dominant fraction of the tilt and scatter of the UV Fundamental Planes is due to the presence of young stars in preferentially low-mass early-type galaxies.

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서울의 최근 자외선 복사의 변화 2004~2010 (Recent Variations of UV Irradiance at Seoul 2004~2010)

  • 김준;박상서;조나영;김우경;조희구
    • 대기
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    • 제21권4호
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    • pp.429-438
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    • 2011
  • The climatology of surface UV radiation for Seoul, presented in Cho et al. (1998; 2001), has been updated using measurement of surface erythemal ultraviolet (EUV) and total ultraviolet (TUV) irradiance (wavelength 286.5~363.0 nm) by a Brewer Spectrophotometer (MK-IV) for the period 2004~2010. The analysis was also carried out together with the broadband total (global) solar irradiance (TR ; 305~2800 nm) and cloud amount to compare with the UV variations, measured by Seoul meteorological station of Korean Meteorological Agency located near the present study site. Under all-sky conditions, the day-to-day variability of EUV exhibits annual mean of 98% in increase and 31% in decrease. It has been also shown that the EUV variability is 17 times as high as the total ozone in positive change, whereas this is 6 times higher in negative change. Thus, the day to day variability is dominantly caused rather by the daily synoptic situations than by the ozone variability. Annual mean value of daily EUV and TUV shows $1.62kJm^{-2}$ and $0.63MJm^{-2}$ respectively, whereas mean value of TR is $12.4MJm^{-2}$ ($143.1Wm^{-2}$). The yearly maximum in noon-time UV Index (UVI) varies between 9 and 11 depending on time of year. The highest UVI shows 11 on 20 July, 2008 during the period 2004~2010, but for the period 1994~2000, the index of 12 was recorded on 13 July, 1994 (Cho et al., 2001). A 40% of daily maximum UVI belongs to "low (UVI < 2)", whereas the UVI less than 5% of the maximum show "very high (8 < UVI < 10)". On average, the maximum UVI exceeded 8 on 9 days per year. The values of Tropospheric Emission Monitoring Internet Service (TEMIS) EUV and UVI under cloud-free conditions are 1.8 times and 1.5 times, respectively, higher than the all-sky measurements by the Brewer. The trend analysis in fractional deviation of monthly UV from the reference value shows a decrease of -0.83% and -0.90% $decade^{-1}$ in the EUV and TUV, respectively, whereas the TR trend is near zero (+0.11% $decade^{-1}$). The trend is statistically significant except for TR trend (p = 0.279). It is possible that the recent UV decrease is mainly associated with increase in total ozone, but the trend in TR can be attributed to the other parameters such as clouds except the ozone. Certainly, the cloud effects suggest that the reason for the differences between UV and TR trends can be explained. In order to estimate cloud effects, the EUV, TUV and TR irradiances have been also evaluated for clear skies (cloud cover < 25%) and cloudy skies (cloud cover ${\geq}$ 75%). Annual mean values show that EUV, TUV and TR are $2.15kJm^{-2}$, $0.83MJm^{-2}$, and $17.9MJm^{-2}$ for clear skies, and $1.24kJm^{-2}$, $0.46MJm^{-2}$, and $7.2MJm^{-2}$ for cloudy skies, respectively. As results, the transmission of radiation through clouds under cloudy-sky conditions is observed to be 58%, 55% and 40% for EUV, TUV and TR, respectively. Consequently, it is clear that the cloud effects on EUV and TUV are 18% and 15%, respectively lower than the effects on TR under cloudy-sky conditions. Clouds under all-sky conditions (average of cloud cover is 5 tenths) reduced the EUV and TUV to about 25% of the clear-sky (cloud cover < 25%) values, whereas for TR, this was 31%. As a result, it is noted that the UV radiation is attenuated less than TR by clouds under all weather conditions.

아세틸화가 Glycinin의 구조에 미치는 영향 (Effect of Acetylation on Conformation of Glycinin)

  • 김강성;이준식
    • 한국식품과학회지
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    • 제21권5호
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    • pp.714-720
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    • 1989
  • 콩의 주요 저장 단백질인 glycinin의 라이신 잔기를 적당량의 acetic anhydride를 이용하여 28, 65, 85, 95%로 아세틸화시켰다. 아세틸화에 의한 구조적 변화를 solvent perturbant 방법으로 측정한 결과 자연상태의 단백질에 있어서는 타이로신 잔기의 약 40% 미만이 단백질 표면에 노출되어 있었으나 85% 아세틸화 glycinin에 있어서는 70% 이상이 표면에 노출되어 용매에 대해 접근이 용이하게 되었다. 이와 같은 현상은 second derivative spectroscopy에 의해 서로 동일하게 나타났으며, 따라서 아세틸화에 의해 타이로신과 같은 소수성 아미노산이 단백질 표면으로 이동하여 단백질 구조가 변형되었음을 알 수 있었다. 한편 near UV circular dichriosim의 결과 자연상태의 glycinin과 아세틸화가 일어난 glycinin 모두 유사한 모양의 spectra를 나타내었으나 95% 아세틸화 glycinin의 경우에는 tryptophan의 영향이 두드러졌다. Specific viscosity의 경우 아세틸화가 일어날수록 급격히 증가하였는데 이는 아세틸화에 의해 구형의 glycinin이 변형되어 분자의 부피가 커졌을 뿐 아니라 subunit의 분리에 의해 입자수가 증가했기 때문이다.

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