• Title/Summary/Keyword: natural uranium

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A Sequential Separation Procedure for the Determination of Uranium, Thorium and Their Isotopes in Geological Materials (지질시료 중의 U과 Th 분석 및 자연방사성동위원소 측정을 위한 화학적 분리)

  • Kim, Jung Suk;Choi, Kwang Soon
    • Analytical Science and Technology
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    • v.10 no.5
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    • pp.307-314
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    • 1997
  • Inductively coupled plasma atomic emission spectrometry(ICP/AES) was used for the determination of uranium and thorium in geological materials. Samples were predecomposed by mixed acid digestion technique. The separation of the uranium and thorium was achieved by systematic solvent extraction with TTA(thenoyltrifluoroacetone) and TOA (tri-n-octylamine) and back extraction into HCl. The results for standard rock sample, NIST SRM 278, showed a good agreement with those certified from NIST as well as found values by other non-destructive techniques. Additional purification for extracted portions was carried out by anion exchange chromatography for measurement of several natural radioisotopes of uranium and thorium by alpha spectrometry.

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Study of the Changes in Composition of Ammonium Diuranate with Progress of Precipitation, and Study of the Properties of Ammonium Diuranate and its Subsequent Products Produced from both Uranyl Nitrate and Uranyl Fluoride Solutions

  • Manna, Subhankar;Kumar, Raj;Satpati, Santosh K.;Roy, Saswati B.;Joshi, Jyeshtharaj B.
    • Nuclear Engineering and Technology
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    • v.49 no.3
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    • pp.541-548
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    • 2017
  • Uranium metal used for fabrication of fuel for research reactors in India is generally produced by magnesio-thermic reduction of $UF_4$. Performance of magnesio-thermic reaction and recovery and quality of uranium largely depends on properties of $UF_4$. As ammonium diuranate (ADU) is first product in powder form in the process flow-sheet, properties of $UF_4$ depend on properties of ADU. ADU is generally produced from uranyl nitrate solution (UNS) for natural uranium metal production and from uranyl fluoride solution (UFS) for low enriched uranium metal production. In present paper, ADU has been produced via both the routes. Variation of uranium recovery and crystal structure and composition of ADU with progress in precipitation reaction has been studied with special attention on first appearance of the precipitate Further, ADU produced by two routes have been calcined to $UO_3$, then reduced to $UO_2$ and hydroflorinated to $UF_4$. Effect of two different process routes of ADU precipitation on the characteristics of ADU, $UO_3$, $UO_2$ and $UF_4$ were studied here.

Nuclear Characteristics of a New(PWR-PHWR) Fuel Cycle (PWR-PHWR 핵연료 주기의 핵적 특성)

  • Jae Woong Song;Chang Hyun Chung
    • Nuclear Engineering and Technology
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    • v.17 no.3
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    • pp.185-192
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    • 1985
  • The fissile content of PWR spent fuel is higher than that of natural uranium which is normal fuel for CANDU type reactor. Investigated are the concepts of PWR spent fuel utilization in CANDU type reactor to diversify uranium resource and partially to solve storage problems of PWR spent fuel being gradually accumulated. Nuclear characteristics of uranium-plutonium mixed oxide fuel loaded in CANDU type reactor are analysed using the WIMS/D computer code. In this study, analyses are solely carried out upon the current CANDU type reactor design without changingany reactivity control devices.

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Physiological and Ecological Studies of the Vegetation on Ore Deposits (금속광물상에 나타나는 식물에 관한 생리생태학적 연구 3. 괴산 우라늄광지대 식물의 방사선생태학적 징상)

  • Chang, Nam Kee;Chang Soo Mok
    • The Korean Journal of Ecology
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    • v.5 no.4
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    • pp.137-142
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    • 1982
  • From 1975 to 1981, the survey was carried out to find out radioecological effects of uranium ore deposits on natural vegetation in Koisan, Korea. The symptoms of spotty and mosaic chlorosis, and necrosis were observed in flowering plants in the areas of uranium ore deposits at Deok-Peung-Ri A, B, and C in Koisan. Although 13 species were found to be chlorosis and necrosis, foliages observed are small and very rare. The features of these symptoms closely resemble those occured by the effects of heavy meetals. The amount of transparent radiation throughout the depth of soils from uranium radiation sources decreases exponentially. The mean contents in leaves of spotty and mosaik chlorotic plants, and soils were 1.36~1.53 and 5.3~7.4 ppm, respectively.

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Distribution Characteristics of Uranium and Radon Concentrations of Groundwater in Gwangju Area (광주지역 지하수 중 우라늄과 라돈의 함량 분포 특성)

  • Seo, Heejeong;Min, Kyoungwoo;Park, Jiyoung;Park, Juhyun;Hwang, Hoyeon;Park, Seil;Kim, Seonjeong;Jeong, Sukkyung;Bae, Seokjin;Kim, Seongjun
    • Journal of Environmental Health Sciences
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    • v.48 no.2
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    • pp.86-95
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    • 2022
  • Background: As high concentrations of uranium and radon have been detected in some areas in Korea, it is considered necessary to investigate natural radioactive materials in the Gwangju area. Objectives: This study aimed to identify the hydrochemical characteristics of groundwater in Gwangju and investigate the distribution characteristics of uranium and radon, which are naturally radioactive substances. Methods: To determine the uranium and radon concentrations in groundwater according to the geology of the Gwangju area, we measured 62 groundwater wells. A geological distribution map of uranium and radon content was prepared for this study. Results: The groundwater type, defined using a Piper diagram, was mainly Ca-HCO3. The concentration of uranium in the groundwater ranged from 0 to 29.3 ㎍/L, with a mean of 3.3 ㎍/L and a median of 0.9 ㎍/L. The median concentration of uranium in groundwater was highest in alluvium, granitic gneiss, and biotite granite (classified by geological unit), in that order. The concentration of radon in the groundwater ranged from 4.8 to 313.2 Bq/L, with a mean of 75.6 Bq/L and a median of 59.6 Bq/L. The median concentration of radon in groundwater was highest in biotite granite, alluvium, and granitic gneiss, in that order. As a result of the correlation analysis of groundwater in the study area, there was no significant correlation between uranium and radon. Conclusions: In this study area, uranium was shown to be far below the concentrations allowed by drinking water quality standards, but radon concentrations exceeded drinking water quality monitoring standards in 11% of the samples. It was judged that appropriate measures, such as the installation of radon reduction facilities, will be required after a thorough review of high-concentration radon detection sites of in the research area.

Conceptual Design of a Cover System for the Degmay Uranium Tailings Site (Degmay 우라늄광산 폐기물 부지 복원을 위한 복토층 개념설계)

  • Saidov, Vaysidin;Kessel, David S.;Kim, Chang-Lak
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.2
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    • pp.189-200
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    • 2016
  • The Republic of Tajikistan has ten former uranium mining sites. The total volume of all tailings is approximately 55 million tonnes, and the covered area is more than 200 hectares. The safe management of legacy uranium mining and tailing sites has become an issue of concern. Depending on the performance requirements and site-specific conditions (location in an arid, semiarid or humid region), a cover system for uranium tailings sites could be constructed using several material layers using both natural and man-made materials. The purpose of this study is to find a feasible cost-effective cover system design for the Degmay uranium tailings site which could provide a long period (100 years) of protection. The HELP computer code was used in the evaluation of potential Degmay cover system designs. As a result of this study, a cover system with 70 cm thick percolation layer, 30 cm thick drainage layer, geomembrane liner and 60 cm thick barrier soil layer is recommended because it minimizes cover thickness and would be the most cost-effective design.