• Analytical Science and Technology
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• v.18 no.1
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• pp.89-95
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• 2005

Studies on the electrochemical reduction of 7-acetoxy-4-bromomethyl-coumarin (ABMC), 7-acetoxymethyl coumarin (AMC), and coumarin in 0.1 M tetraethyl ammonium perchlorate acetonitrile solution were carried out with direct current, differential pulse polarography, cyclic voltammetry, and controlled potential coulometry. The electrochemical reduction of ABMC was proceeded through three irreversible steps coupled with the chemical reactions. The solution color was changed to yellow when the carbonyl group was reduced during second step and the color change was independent with bromo group of ABMC. Fluorescent intensity was highest when the electrochemical reduction was controlled at near the overpotential of supporting electrolyte (-2.3 volts).

• Analytical Science and Technology
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• v.10 no.6
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• pp.403-407
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• 1997

Separation factor for $^6Li$ and $^7Li$ have been determined using ion exchange resin having 1,7,13-trioxa-4,10,16-triazacyclooctadecane($N_3O_3$) as an anchor group. The lighter isotope, $^6Li$ is concentrated in the solution phase, while the heavior isotope, $^7Li$ is enriched in the resin phase. By Ccolumnl chromatography[0.9cm(I.D)${\times}$20cm(height)] using 2.0M ammonium chloride solution as an eluent, single separation factor, ${\alpha}$, 1.009. i.e.$(^7Li/^6Li)_{resin}$/$(^7Li/^6Li)_{solution}$ was obtained by the Glueckauf theory from the elution curve and isotope ratios.

• Textile Coloration and Finishing
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• v.22 no.3
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• pp.207-213
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• 2010

Natural dyeing of Sangju silk for graveclothes with mulberry extract solution was studied. The anthocyanidin dye in the extracted mulberry solution was markedly influenced by pH condition, which resulted in the changed maximum light absorption from a $\lambda$max of 525nm in acidic condition to 380nm in alkaline condition possibly due to the irreversible transformation of anthocyanidin to cyanidin form of the dye. The color fastness properties to both light and washing were good when the fabrics were dyed at $80^{\circ}C$ with the mulberry-extracted solution upto twice extraction.

• Structural Engineering and Mechanics
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• v.62 no.1
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• pp.65-77
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• 2017

The free vibration analysis of fluid conveying Timoshenko pipeline with different boundary conditions using Differential Transform Method (DTM) and Adomian Decomposition Method (ADM) has not been investigated by any of the studies in open literature so far. Natural frequencies, modes and critical fluid velocity of the pipelines on different supports are analyzed based on Timoshenko model by using DTM and ADM in this study. At first, the governing differential equations of motion of fluid conveying Timoshenko pipeline in free vibration are derived. Parameter for the nondimensionalized multiplication factor for the fluid velocity is incorporated into the equations of motion in order to investigate its effects on the natural frequencies. For solution, the terms are found directly from the analytical solution of the differential equation that describes the deformations of the cross-section according to Timoshenko beam theory. After the analytical solution, the efficient and easy mathematical techniques called DTM and ADM are used to solve the governing differential equations of the motion, respectively. The calculated natural frequencies of fluid conveying Timoshenko pipelines with various combinations of boundary conditions using DTM and ADM are tabulated in several tables and figures and are compared with the results of Analytical Method (ANM) where a very good agreement is observed. Finally, the critical fluid velocities are calculated for different boundary conditions and the first five mode shapes are presented in graphs.

• Korean Management Science Review
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• v.33 no.1
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• pp.101-117
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• 2016

In 2000s, incidence of natural disaster is increasing continuously. Therefore, the necessity of research on the effective disaster response is emphasized. Korea is not safe from natural disaster. Natural disasters like torrential downpours, typhoons have occurred more frequently than before. In addition disasters like droughts and MERS has also occurred. Therefore, needs for effective systems and algorithms to respond disaster are increased. This study covers the vehicle routing problem for effective logistics in disaster situations caused by natural disasters. The emergency vehicle route problem has different property from the general vehicle route problem. It has the property of the importance of deadline, the uncertain and dynamic demand information, and the uncertainty in information transfer. In this study, a solution that focused on the importance of deadline. In this study, the heuristic solution using the genetic algorithm are suggested. Finally the simulation experiment which reflects the actual environment are conducted to verify the performance of the solution.

• Structural Engineering and Mechanics
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• v.72 no.2
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• pp.229-244
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• 2019

Weak form integral equations are developed to investigate the flapwise bending vibration of the rotating beams. Rayleigh and Eringen nonlocal elasticity theories are used to investigate the rotatory inertia and Size-dependency effects on the flapwise bending vibration of the rotating cantilever beams, respectively. Through repetitive integrations, the governing partial differential equations are converted into weak form integral equations. The novelty of the presented approach is the approximation of the mode shape function by a power series which converts the equations into solvable one. Substitution of the power series into weak form integral equations results in a system of linear algebraic equations. The natural frequencies are determined by calculation of the non-trivial solution for resulting system of equations. Accuracy of the proposed method is verified through several numerical examples, in which the influence of the geometry properties, rotatory inertia, rotational speed, taper ratio and size-dependency are investigated on the natural frequencies of the rotating beam. Application of the weak form integral equations has made the solution simpler and shorter in the mathematical process. Presented relations can be used to obtain a close-form solution for quick calculation of the first five natural frequencies of the beams with flapwise vibration and non-local effects. The analysis results are compared with those obtained from other available published references.

• Bulletin of the Korean Chemical Society
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• v.30 no.3
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• pp.556-560
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• 2009

Aggregation behavior of three kinds of benzindocarbocyanine dyes in aqueous methanol solution was studied by UV-Vis absorption spectrum. The results indicated that the three dyes all existed monomer-dimer equilibrium in aqueous methanol solution (concentration range $10^{−5}\;to\;10^{−6}$ M) at 25.0$\sim$41.0 ${^{\circ}C}$ for Dye 1, 28.0$\sim$49.0 ${^{\circ}C}$ for Dye 2 and 26.0$\sim$47.0 ${^{\circ}C}$ for Dye 3. The fundamental property of the three dyes as the dimeric association constant KD, the dimeric free energy ${\Delta$}G_D, the dimeric entropy ${\Delta$}S_D, and the dimeric enthalpy ${\Delta$}H_D were determined. The ${\Delta$}H_D of three dyes: Dye 1, Dye 2 and Dye 3 was -42.5, -15.1 and -18.9 kJ/mol, respectively. The experimental observations were the subject of a theoretical study including the ground-state geometries which were fully optimized using DFT at B3LYP/6-31G level. The effect of dye molecule structure on ${\Delta$}H_D was discussed by theoretical calculations.

• Membrane and Water Treatment
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• v.4 no.4
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• pp.223-236
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• 2013

The paper presents an experimental set-up for osmotic membrane distillation, which can be operated continuously for several weeks. NaCl solutions were used as an osmotic solution. The influence of osmotic solution concentration on the obtained permeate flux is presented. The experimental set-up was equipped with a system for the regeneration of dilute brine. The regeneration was carried out using a method of natural evaporation to the air surrounding the installation. The evaporation area was created by the Białecki rings, assembled in the form of tower. The obtained evaporation rate was sufficient to maintain a constant NaCl concentration (over 300 g/L), for air with the relative humidity in the range of 30-80%. Accurel PP S6/2 hydrophobic polypropylene membranes were used in the study. The membranes exhibited 100% rejection for 600 h of the process duration.

• Journal of the Korean Society of Food Science and Nutrition
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• v.28 no.2
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• pp.417-422
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• 1999

Algin and chitosan are known as biodegradable natural polymers. PVA is useful for the production of water soluble packaging, paper, textile sizes. PVA/Algin and PVA/chitosan films were prepared by solution blends method in the weight ratio of chitosan, algin for the purpose of useful biodegradable films. Thermal and mechanical properties of blend films such as DSC, impact strength, tensile strength and morphology by SEM were determined. As a result, The ratio of 10.0wt% PVA/chitosan films were similar to PVA at thermal and mechanical properties. PVA/Algin films were found that phase separation was occured as more than 25wt% increasing the blend ratio of algin. PVA/Algin films were observed to be less partially compatibility than 10wt% increasing the blend ratio of algin by DSC, mechanical properties and SEM. Blend films were completely degraded pH 4.0 better than 7.0, 10.0 in the buffer solution. Also, they were rapidly degraded in the enzyme( glucosidase) solution better than pH solution by enzymolysis.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.31 no.2
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• pp.69-72
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• 2021

The reaction of ammonium ferric sulfate with sodium borohydride in laponite sol yields nanoiron colloidal solution. This solution in air forms transparent yellow brown solution. The resulting solution reacts with bidentate chelating ligands. The reaction products are characterized by UV-Vis absorption spectroscopy and X-ray diffraction. All compounds show metal to ligand charge transfer band in the region of 400~650 nm in UV-Vis absorption spectra. This indicates the formation of iron-ligand complex by air oxidation of nanoiron. Also, XRD patterns exhibit that the iron-ligand complex is intercalated in the interlayer of laponite.