• Title/Summary/Keyword: natural polymer

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Skin Permeation Characteristics of Antihyperlipoproteinemic Agent using Natural Polymer Bases in Rats (천연고분자 기재에 의한 수용성 항고지단백혈증제의 흰쥐 피부투과 특성)

  • Kong, Seung-Dae;Hwang, Sung-Kwy;Jung, Duck-Chae
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.2
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    • pp.126-131
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    • 2000
  • Transdermal therapeutic system(TTS) is often used as the method of drug dosage into the epidermic skin. Natural polymer were selected as ointment material of TTS. We investigated the permeation of natural polymer ointment containing drug in rat skin using horizontal membrane cell model. Permeation properties of materials were investigated for water-soluble drug such as oxiniacic acid in vitro. These results showed that skin permeation rate of drug across the composite was mainly dependent on the property of ointment base and drug. Proper selection of the polymeric materials which resemble and enhance properties of the delivering drug was found to be important in controlling the skin permeation rate. This result suggests a possible use of natural polymer ointment base as TTS of antihyperlipoproteinemic agent.

New Photoreactive Materials Having Chalcone Units: Synthesis and Photoalignment of Nematic Liquid Crystals

  • Lee, Won-Joo;Lim, Ji-Chul;Paek, Sang-Hyon;Kigook Song;Chang, Ji-Young
    • Macromolecular Research
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    • v.9 no.6
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    • pp.339-344
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    • 2001
  • In order to investigate the photoalignment mechanism of nematic liquid crystals on a polymer film, a new photoreactive polymer having chalcone groups as side chains was synthesized. Linearly polarized UV light causes preferential photoreactions of the chalcone unit along the polarization direction and thus induces the anisotrpy in the polymer alignment layer resulting in homogeneous LC alignment perpendicular to the polarization direction. The sequential investigations of photoalignment generated by the preferential E/Z isomerization and (2+2) cycloaddition reactions show that either photoreaction can solely induce the LC alignment in the direction perpendicular to UV polarization.

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Application of poly(vinyl acetate) and poly(1,4-butylene adipate) hydrophobic surface coatings on cementitious mortar specimens

  • Sanal, Irem;Yalcin, Bestenur;Yalcin, Ibrahim Ertugrul;Arda, Lutfi
    • Advances in concrete construction
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    • v.11 no.4
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    • pp.323-333
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    • 2021
  • The main objective of this study is to characterize and evaluate the hydrophobic performance of polymer-based water-repellent coatings on cementitious mortar surfaces. Different concentrations of poly(vinyl acetate) (PVAc) and poly(1,4-butylene adipate) (PBA) were prepared in the laboratory and their applicability and performance was tested experimentally by water absorption test and analysis of surface contact angles of cementitious mortar specimens. According to the results of this study, it can be stated that incorporation of nano polymer particles on the surface of cementitious mortar specimens can enhance contact angles and reduce water absorption by increasing hydrophobicity. However, a dosage limit exists for polymer materials in coating, and observed hydrophobic improvements decreases when polymer dosage reached beyond the limit. Additionally, it is observed that water absorption of polymer coated cementitious mortars is closely related with the results of surface contact angle.

Effects of Reactive Compatibilizers on the Morphology and Properties of Natural Rubber/SiO2 Composites

  • Lee, Min Young;Park, Jin Young;Song, Ki Chan;Kim, Su Kyung
    • Elastomers and Composites
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    • v.51 no.2
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    • pp.106-112
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    • 2016
  • Maleimidopropyltriethoxysilane grafted natural rubber (MISNR) was prepared by reaction of maleic anhydride grafted natural rubber and 3-aminopropyl triethoxysilane. MISNR was used as the compatibilizer of natural rubber/silica composites. The composites were prepared by two-step mixing procedures. The final mixtures were cured with optimum cure condition, which was established by a rheometer. Effects of the amounts of compatibilizer in the composites on the cure characteristics, morphology, thermal stability, and physical and mechanical behaviors were investigated. The composites having MISNR had shown cure characteristics and physical and mechanical properties superior to those without MISNR. Silica particles in the former appeared to be more uniform and reduced in size compared with the latter. The effects of the types of silica were also evaluated.

Strength and Durability Properties of Recycled Polymer Concrete Using Unsaturated Polyester Resin and Recycled Aggregates (불포화폴리에스터 수지와 재생골재를 이용한 재생 폴리머 콘크리트의 강도 및 내구 특성)

  • Kim, Young-Ik;Sung, Chan-Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.51 no.6
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    • pp.97-103
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    • 2009
  • This study was performed to evaluate the strength and durability properties of recycled polymer concrete using unsaturated polyester resin and recycled aggregates. Unsaturated polyester resin, natural and recycled aggregates and fly ash were used. The mix proportions were determined to satisfy the requirement for the workability and slump according to aggregate sizes (5-10 and 5-25 mm) and unit binder contents (10% and 12%). Tests for the compressive and flexural strength, freezing and thawing and durability for 20% sulfuric solution were performed. The compressive and flexural strength of recycled polymer concrete were in the range of 85~97 MPa and 17.9~20.8 MPa, respectively. The strengths of recycled polymer concrete using recycled aggregate have similar or slightly decreased compared to polymer concrete using natural aggregate. After 300 cycles of freezing and thawing, weight decrease ratio and durability factor of recycled polymer concrete were in the range of 0.13~1.42% and 94~99, respectively.

Development and Characterization of Asymmetric Swelling-Induced Wrinkles on Natural Rubber Surface

  • Lee, Gi-Bbeum;Sathi, Shibulal Gopi;Kim, Min Jung;Park, Changsin;Huh, Yang Il;Nah, Changwoon
    • Elastomers and Composites
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    • v.51 no.4
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    • pp.342-349
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    • 2016
  • Characteristics of the swelling-induced wrinkles on the surfaces of natural rubber (NR) film were investigated. The wrinkle structure was generated by swelling of NR film pre-stretched and firmly bonded onto an aluminum substrate in hexane. A novel experimental method was adopted to replicate the swelling-induced wrinkles on the NR film using an epoxy-hardener system. To get insight into the wrinkle parameters; the wrinkle length (L), wrinkle distance (D), wrinkle height (H) and the angle between two consecutive wrinkles (${\theta}$), the cross-sections of the replicas obtained from saturated swollen NR film were examined using an optical microscopy (OM). From the OM images, the wrinkling parameters were measured as a function of the thickness of NR film from 0.42 to 1.76 mm. Also, it was evaluated that the effects of swelling time on the wrinkling parameters. The length (L), distance (D) and height (H) of wrinkles increased as the thickness of the NR film and the swelling time increased. However, the angle between the wrinkles (${\theta}$) showed a sharp decrease up to a swelling time of 200 minutes and slightly decreased afterwards.

Dynamic Mechanical Properties of Natural Fiber/Polymer Biocomposites: The Effect of Fiber Treatment with Electron Beam

  • Han, Young-Hee;Han, Seong-Ok;Cho, Dong-Hwan;Kim, Hyung-Il
    • Macromolecular Research
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    • v.16 no.3
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    • pp.253-260
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    • 2008
  • Environmentally friendly biocomposites were made using plant-based natural fibers, such as henequen and kenaf. The natural fiber reinforced polypropylene (PP) and unsaturated polyester (UP) biocomposites were examined in terms of the reinforcing effect of natural fibers on thermoplastic and thermosetting polymers. Kenaf (KE) and henequen (HQ) fibers were treated with an electron beam (EB) of 10 and 200 kGy doses, respectively, or with a 5 wt% NaOH solution. Four types of biocomposites (KE/PP, HQ/PP, KE/UP and HQ/UP) were fabricated by compression molding and each biocomposite was characterized by dynamic mechanical analysis and thermogravimetric analysis. The kenaf fiber had the larger reinforcing effect on the dynamic mechanical properties of both PP and UP biocomposites than the henequen fiber. The highest storage modulus was obtained from the biocomposite with the combination of UP matrix and 200 kGy EB treated kenaf fibers.

Compressive Strength of Natural Fiber Reinforced Polymer Composites (천연섬유강화 폴리머 복합재료의 압축강도 특성)

  • Song, Jun-Hee;Mun, Sang-Don;Kim, Yoo-Young;Kim, Hong-Gun
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.19 no.1
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    • pp.140-144
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    • 2010
  • In recent years there has been a growing interest for the use of natural fibers in composite applications due to their low cost, environmental friendliness, and good mechanical properties. The purpose of this study is to determine the characteristic of bending strength on bamboo fiber reinforced polymer composites. The parameters of RTM process depend on the weight ratio of bamboo fiber and resin, the number of bamboo ply and amount of hardening agent. Besides the existence of pore in composites according to vacuum time investigated a effect on mechanical properties of reinforced polymer composites. Test result shows that compressive strength was a maximum(approximately 1,840kgf/$cm^2$) value when weight ratio of resin was 12%.