• Title/Summary/Keyword: natural exposure

Search Result 841, Processing Time 0.037 seconds

Characterization of the UV Oxidation of Raw Natural Rubber Thin Film Using Image and FT-IR Analysis

  • Kim, Ik-Sik;Lee, Bok-Won;Sohn, Kyung-Suk;Yoon, Joohoe;Lee, Jung-Hun
    • Elastomers and Composites
    • /
    • v.51 no.1
    • /
    • pp.1-9
    • /
    • 2016
  • Characterization of the UV oxidation for raw natural rubber (NR) was investigated in controlled conditions through image and FT-IR analysis. The UV oxidation was performed on a thin film of natural rubber coated on a KBr window at 254 nm and room temperature to exclude the thermal oxidation. Before or after exposure to UV light, image of the NR thin film was observed at a right or tilted angle. FT-IR absorption spectra were measured in transmission mode with the UV irradiation time. The UV oxidation of NR was examined by the changes of absorption peaks at 3425, 1717, 1084, 1477, 1377, and $833cm^{-1}$ which were assigned to hydroxyl group (-OH), carbonyl group (-C=O), carbon-oxygen bond (-C-O), methylene group $(-CH_2-)$, methyl group $(-CH_3)$, and cis-methine group $(cis-CCH_3=CH-)$, respectively. During the initial exposure period, the results indicated that the appearance of carbonyl group was directly related to the reduction of cis-methine group containing carbon-carbon double bond (-C=C-). Most of aldehydes or ketones from carbon-carbon double bonds were formed very fast by chain scission. A lot of long wide cracks with one orientation at regular intervals which resulted in consecutive chain scission were observed by image analysis. During all exposure periods, on the other hand, it was considered that the continuous increment of hydroxyl and carbonyl group was closely related to the decrement of methylene and methyl group in the allylic position. Therefore, two possible mechanisms for the UV oxidation of NR were suggested.

Calculation of Man-made Radiation Exposure Rate from NaI Spectrum (NaI 스펙트럼으로부터 인공방사선 조사선량의 계산)

  • Lee, M.S.
    • Journal of Radiation Protection and Research
    • /
    • v.26 no.2
    • /
    • pp.113-117
    • /
    • 2001
  • The energy band method for NaI spectrum calculates only the exposure rate due to natural radiation because it calculates exposure rate using energy spectrum of $1300{\sim}3000keV$. However, the total energy method includes in its calculation the exposure rate due to man-made radiation because it uses the energy spectrum of $150{\sim}3400keV$. Therefore, the resulting difference of extracting the exposure rate calculated by the energy band method from the exposure rate calculated by the total energy method is apparently the exposure rate due to man-made radiation. In this study, we measured the NaI spectrum during the period of significant changes of the exposure rate in the area without a man-made radiation. As the results, we found the exposure rates calculated by those two methods are equal within the statistical variation of ${\pm}0.3{\mu}R\;h^{-1}$. Consequently, if the difference between the exposure rates calculated by the two methods exists, it may be due to the man-made radiation exposure rate.

  • PDF

Risk Assessment of Human Exposure to Methidathion during Harvest of Cucumber in Green House

  • Byoun Ji-Youn;Choi Hoon;Moon Joon-Kwan;Park Hee-Won;Liu Kwang-Hyeon;Ihm Yang-Bin;Park Byeoung-Soo;Kim Jeong-Han
    • Toxicological Research
    • /
    • v.21 no.4
    • /
    • pp.297-301
    • /
    • 2005
  • Farmers are generally expressed to pesticides through mixing loding, application activity and harvesting of crop after application of pesticides. The present work investigated the exposure and risk of furathiocarb to workers when harvesting of cucumber was carried out in green house after application of furathiocarb EC. Glove was used for the hand exposure assessment, socks for foot and dermal patches for the other parts of body. Personal air monitor equipped with a XAD-2 resin was used for the respiratory exposure assessment. During the harvest of cucumber in green house, the initial rate of potential dermal exposure (Day 1) for methidathion was 1.3 mg/hr. The major exposure parts were hand $(78\~83\%),\;thigh\;(5\~7\%)$ and arms $(6\~9\%)$ during 3 days' harvest. No exposure was detected from the respiratory monitoring. For risk assessment, the potential dermal exposure (PDE), the absorbable quantity of exposure (AQE) and the margin of safety (MOS) and margin of exposure (MOE) were calculated. In risk assessment of harvester exposure for 7days, all MOS was > 1 and MOE was > 100 indicating that possibility of risk was little.

Comparison of scopolamine-induced cognitive impairment responses in three different ICR stocks

  • Yoon, Woo Bin;Choi, Hyeon Jun;Kim, Ji Eun;Park, Ji Won;Kang, Mi Ju;Bae, Su Ji;Lee, Young Ju;Choi, You Sang;Kim, Kil Soo;Jung, Young-Suk;Cho, Joon-Yong;Hwang, Dae Youn;Song, Hyun Keun
    • Laboraroty Animal Research
    • /
    • v.34 no.4
    • /
    • pp.317-328
    • /
    • 2018
  • Cognitive impairment responses are important research topics in the study of degenerative brain diseases as well as in understanding of human mental activities. To compare response to scopolamine (SPL)-induced cognitive impairment, we measured altered parameters for learning and memory ability, inflammatory response, oxidative stress, cholinergic dysfunction and neuronal cell damages, in Korl:ICR stock and two commercial breeder stocks (A:ICR and B:ICR) after relevant SPL exposure. In the water maze test, Korl:ICR showed no significant difference in SPL-induced learning and memory impairment compared to the two different ICRs, although escape latency was increased after SPL exposure. Although behavioral assessment using the manual avoidance test revealed reduced latency in all ICR mice after SPL treatment as compared to Vehicle, no differences were observed between the three ICR stocks. To determine cholinergic dysfunction induction by SPL exposure, activity of acetylcholinesterase (AChE) assessed in the three ICR stocks revealed no difference of acetylcholinesterase activity. Furthermore, low levels of superoxide dismutase (SOD) activity and high levels of inflammatory cytokines in SPL-treated group were maintained in all three ICR stocks, although some variations were observed between the SPL-treated groups. Neuronal cell damages induced by SPL showed similar response in all three ICR stocks, as assessed by terminal deoxynucleotidyl transferase dUTP nick end labeling (TUNEL) assay, Nissl staining analysis and expression analyses of apoptosis-related proteins. Thus, the results of this study provide strong evidence that Korl:ICR is similar to the other two ICR. Stocks in response to learning and memory capacity.

Development of Natural Hazard Risk Map using Insured Claim Payouts and Its Application (보험 손실액을 활용한 자연재해 위험 지도 개발 및 적용방안 연구)

  • Kim, Ji-Myong;Park, Young Jun
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2015.05a
    • /
    • pp.257-258
    • /
    • 2015
  • The amount of damages caused by natural hazards is consistently growing due to the unusual weather and extreme events. At the same time, property damage by natural hazards is rapidly increasing as well. Hence, we need systematic anti-disaster activities and consulting that can react to such a situation. To address these needs, we investigated and analyzed insured claim payouts from natural hazards by administrative area, and calculate the risk index utilizing GIS. According to the index, this map is identifying the areas of greatest natural hazard risk. The ranking of natural disaster vulnerability based on the risk index, and risk grades were divided into five based on the ranking. This map integrates the natural hazard losses to assist in comprehensive and effective loss prevention activities using analysis of regional loss claims from natural hazards. Moreover, this map can be as utilized as loss mitigation and prevention activities to verify the distribution of exposure and hazards.

  • PDF

Study on the Maintenance of Gloss and Durability test of Glossing Exposure Concrete (광택노출콘크리트의 광택유지성 및 내구성 평가)

  • Ha, Jae-Dam;Kim, Ki-Soo;Choi, Long;Chung, Tai-Wung;Lee, Hyun-Hee;Shin, Sung-Woo
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 1999.10a
    • /
    • pp.147-150
    • /
    • 1999
  • Glossing Exposure Concrete is a high quality architectural concrete, i.e., appearance of natural stone and a marbling effect concrete to achieve high quality glassy reflective surface for outer wall of the building. In this study to obtain the conservation and durability of gloss of the "glossing exposure concrete" we developed a from practice and the best mix proportion and derived the optimistic removal time of form to bring out the durable glassy reflective surface and durable concrete. Hereby with the "glossing exposure concrete" obtained, we investigate the accelerate carbonation and accelerate durability test to evaluate the durability factor of this type of concrete.is type of concrete.

  • PDF

Critical Issues on Health Risk of Asbestos (석면과 건강에 대한 이슈)

  • Yoon, Chung-Sik
    • Journal of Environmental Health Sciences
    • /
    • v.35 no.5
    • /
    • pp.426-432
    • /
    • 2009
  • Asbestos is a commercial term of natural occurring silicated minerals and forms long, thin fibers. Chrysotile, the serpentine asbestos, accounts for most use in commercial use. Asbestos is well known health hazard material and it is proved that inhalation of asbestos fibers leads to increased risk of developing several diseases such as lung cancer, mesothelioma, asbestosis. In these days, people most at risk for exposure are maintenance and construction workers and general citizens who are working on and close to the work area at which asbestos containing material is disturbing. Non asbestiform, though its chemical composition is same with regulated asbestos, is known to be less hazardous than asbestiform. Exposure guideline, 0.01 f/ml, is not safe level in terms of health risk. It is reasonable to take preventable action when asbestos is suspicious. In Korea, it is necessary to clarify the concept between hazard and risk, to differentiate asbestiform from non asbestiform, to make regulations for compensation for asbestos related patients, to manage future exposure for general citizens.