• Title/Summary/Keyword: naphthalene trisulfonic acid

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Ion Chromatography of Anions with Indirect UV-Photometric Detection by using Naphthalene Trisulfonic Acid and Naphthalene Disulfonic Acid as an Eluent (Naphthalene Trisulfonic Acid 및 Naphthalene Disulfonic Acid을 이용한 음이온 간접자외선흡광검출 이온크로마토그래피)

  • Lee, Kwang-Pill;Cheon, Hwi-Kyung;Seo, Hyun-Kyung;Kwon, Se-Mog;Park, Keung-Shik;Tanaka, Kazuhiko;Ohta, Kazutoku
    • Analytical Science and Technology
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    • v.12 no.2
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    • pp.111-115
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    • 1999
  • Single column anion chromatography by indirect UV detection was applied to the determination of 7 common anions($H_2PO_4^-$, $Cl^-$, $NO_2^-$, $NO_3^-$, $I^-$, $SO_4^{2-}$, $SCN^-$). A low capacity silica-based anion-exchange column(TSK guardgel QAE-SW; ca. 0.3 meq./g; 4.6 mm i.d${\times}$150 mm) was used. In separating common anions, we compared naphthalene trisulfonic acid(NTS) and naphthalene disulfonic acid(NDS) to find more sensitive, selective and rapid separation method. And cations and anions can be separated simultaneously in 0.20 mM NTS-5% acetonitrile-water.

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Effects of Naphthalene Trisulfonic Acid on the Surface Properties of Electrodeposited Ni Layer (Naphthalene Trisulfonic Acid가 니켈 전착층의 표면 특성에 미치는 영향)

  • Lee Joo-Yul;Kim Man;Kwon Sik-Chol;Kim Jung-Hwan;Kim In-gon
    • Journal of the Korean institute of surface engineering
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    • v.39 no.1
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    • pp.13-17
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    • 2006
  • The effects of an organic additive, naphthalene trisulfonic acid (NTSA), contained in the nickel sulfamate bath on the surface properties of the electrodeposited nickel layer were investigated through electrochemical technique, x-ray diffraction analysis, and microscopic observation. The addition of NTSA facilitated the oxidation process of electrodeposited nickel layer during anodic scan and also increased the hardness and internal stress of the nickel film as the applied current density became higher. It seems that NTSA modulated the deposit structure during electrodeposition and so induced higher distribution of (110) orientation with respect to (200). With the increase of the NTSA in the bath, nickel layer was formed in small grain size, which resulted in enhanced surface evenness and brightness.