• Title/Summary/Keyword: nano-composite material

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Separation of Low Molecular Weight of Dye from Aqueous Solution Using the Prepared Nano-composite Hollow Fiber Membranes (중공사형 나노복합막 제조를 이용한 수용액으로부터 저분자량의 염료 분리 연구)

  • Park, Cheol Oh;Lee, Sung Jae;Rhim, Ji Won
    • Membrane Journal
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    • v.28 no.3
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    • pp.180-186
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    • 2018
  • The nano-composite membranes were prepared onto the polyvinylidene fluoride (PVDF) hollow fiber membranes through twice dip-coating known layer-by-layer method. For the first coating, poly(vinylsulfonic acid, sodium salt)(PVSA) and Poly(styrene sulfonic acid)(PSSA) were used with varying the concentration and ionic strength (IS) and the poly(ethyleneimine)(PEI) as the second coating material was fixed at 10,000 ppm and IS = 0.3. To characterize the prepared nano-composite membranes, the permeabilities and rejection ratio were measured for each 100 ppm NaCl, $CaSO_4$, $MgCl_2$, and 25 ppm MO aqueous solution. The rejections were increased as the concentrations of coating materials increased. And it was confirmed that the salt rejections for PSSA as the coating material were higher than for PVSA. Typically, the permeability, 1.848 LMH and the rejection for MO 76.3% were obtained at the coating conditions of PSSA 30,000 ppm and I.S = 1.0.

The Study of Plate Powder Coated Nano Sized ZnO Synthesis and Effect of Sensory Texture Improvement (나노 ZnO 입자가 코팅된 판상 분체의 합성과 사용감 증진 효과에 대한 연구)

  • Jin-Hwa , Lee;Ju-Yeol, Han;Sang-Gil, Lee;Hyeong-Bae, Pyo;Dong-Kyu, Lee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.2
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    • pp.173-180
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    • 2004
  • Nano sized ZnO particle as 20-30nm applies for material, pigments, rubber additives, gas sensors, varistors, fluorescent substance as well as new material such as photo-catalyst, sensitizer, fluorescent material. ZnO with a particle size in the range 20-30nm has provided to be an excellent UV blocking material in the cosmetics industry, which can be used in sunscreen product to enhance the sun protection factor and natural makeup effect. But pure ZnO particles application limits for getting worse wearing feeling. We make high-functional inorganic-composite that coated with nano-ZnO on the plate-type particle such as sericite, boron nitride and bismuthoxychloride. In this experiment, we synthesized composite powder using hydrothermal precipitation method. The starting material was ZnCl$_2$ Precipitation materials were used hexamethylenetetramine(HMT) and urea. We make an experiment with changing as synthesis factors that are concentrations of starting material, precipitation materials, nuclear formation material, reaction time, and reaction temperature. We analyzed composite powder's shape, crystallization and UV-blocking ability with FE-SEM, XRD, FT-IR, TGA-DTA, In vitro SPF test. The user test was conducted by product's formulator. In the results of this study, nanometer sized ZnD was coated regardless of the type of plate-powder at fixed condition range. When the coated plate-powders were applied in pressed powder product, the glaze of powder itself decreased, but natural make-up effect, spreadability, and adhesionability were increased.

Computational mathematical modeling of the nonlinear vibration characteristics of AFG truncated conical nano pipe based on the nonlocal strain gradient theory

  • Zhang, Ruihua;Cao, Yiqing
    • Steel and Composite Structures
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    • v.42 no.5
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    • pp.599-615
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    • 2022
  • In the present paper, the numerical dynamic analysis of a functionally graded nano-scale nonuniform tube was investigated according to the high-order beam theory coupled with the nonlocal gradient strain theory. The supposed cross-section is changed along the pipe length, and the material distribution, which combines both metal and ceramics, is smoothly changed in the pipe length direction, which is called axially functionally graded (AFG) pipe. Moreover, the porosity voids are dispersed in the cross-section and the radial pattern that the existence of both material distribution along the tube length and porosity voids make a two-dimensional functionally graded (2D-FG) truncated conical pipe. On the basis of the Hamilton principle, the governing equations and the associated boundary conditions equations are derived, and then a numerical approach is applied to solve the obtained equations.

SWCNT/Nafion Composite Development for Improvement of Mechanical Properties of IPMC (IPMC의 기계적 특성향상을 위한 SWCNT/Nafion 복합체 개발)

  • Kwon, Hui-June;Lee, Heon-Sang;Lee, Jung-Hwa;Jun, Chan-Bong;Kang, Jung-Ho
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.10 no.1
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    • pp.47-53
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    • 2011
  • From recent research, it has revealed that Electroacitve polymer(EAP) has a physical limitation. Carbon nanotube(CNT) is known as the promising material which has excellent electro-mechanical characteristics and is mostly defect-free. It is expected that a successful synthesis of CNT and Nafion known as a primary material for IPMC would make a great improvement on its electro-mechanic feature. In this paper, we suggest the method of synthesis of CNT with Nafion which improves electro-mechanical characteristic. Using mechanical dispersion with Nafion and Isopropyl Alcohol(IPA), we disperse Single-walled carbon nanotubes(SWCNT). For a uniformly layer of CNT, we used a spray gun on a hot plate by a simplified method. In the result, we fabricated a disperse SWCNT/Nafion composite uniformly.

Investigating nonlinear forced vibration behavior of multi-phase nanocomposite annular sector plates using Jacobi elliptic functions

  • Mirjavadi, Seyed Sajad;Forsat, Masoud;Barati, Mohammad Reza;Hamouda, A.M.S.
    • Steel and Composite Structures
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    • v.36 no.1
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    • pp.87-101
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    • 2020
  • A multi-scale epoxy/CNT/fiberglass annular sector plate is studied in this paper in the view of determining nonlinear forced vibration characteristics. A 3D Mori-Tanaka model is employed for evaluating multi-scale material properties. Thus, all of glass fibers are assumed to have uni-direction alignment and CNTs have random diffusion. The geometry of annular sector plate can be described based on the open angle and the value of inner/outer radius. In order to solve governing equations and derive exact forced vibration curves for the multi-scale annular sector, Jacobi elliptic functions are used. Obtained results demonstrate the significance of CNT distribution, geometric nonlinearity, applied force, fiberglass volume, open angle and fiber directions on forced vibration characteristics of multi-scale annular sector plates.

The Role of Nano-particles on the Material Properties of Epoxy/Fe2O3 Nano-composites (Epoxy/Fe2O3 나노 복합재의 물성치에 미치는 나노 입자의 역할)

  • Park, Joo-Hyuk;Kim, Jung-Yub
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.30 no.5
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    • pp.88-93
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    • 2002
  • The objective of this study is to obtain fundamental understandings involving the manufacturing process of nano-composite via resin transfer molding and explore the role of nano sized $Fe_2O_3$ particles in the epoxy/$Fe_2O_3$ nano-composites. To achieve this goal, following investigations have been conducted: Define the optimum dispersion technique of nano-particles, identify the effect of the nano-particles to the resin viscosity, characterize the key mechanical properties versus particle loading amounts, and explore the usefulness and quality improvement in nano-composites. These efforts will be useful for designers to quantify application payoffs and define a technology development roadmap for manufacturing nano-composites, and will help an engineering design and manufacturing nano-composites more efficiently by providing the design methodology.

Thermal, electrical and mechanical buckling loads of sandwich nano-beams made of FG-CNTRC resting on Pasternak's foundation based on higher order shear deformation theory

  • Arani, Ali Ghorbanpour;Pourjamshidian, Mahmoud;Arefi, Mohammad;Arani, M.R. Ghorbanpour
    • Structural Engineering and Mechanics
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    • v.69 no.4
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    • pp.439-455
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    • 2019
  • This research deals with thermo-electro-mechanical buckling analysis of the sandwich nano-beams with face-sheets made of functionally graded carbon nano-tubes reinforcement composite (FG-CNTRC) based on the nonlocal strain gradient elasticity theory (NSGET) considering various higher-order shear deformation beam theories (HSDBT). The sandwich nano-beam with FG-CNTRC face-sheets is subjected to thermal and electrical loads while is resting on Pasternak's foundation. It is assumed that the material properties of the face-sheets change continuously along the thickness direction according to different patterns for CNTs distribution. In order to include coupling of strain and electrical field in equation of motion, the nonlocal non-classical nano-beam model contains piezoelectric effect. The governing equations of motion are derived using Hamilton principle based on HSDBTs and NSGET. The differential quadrature method (DQM) is used to calculate the mechanical buckling loads of sandwich nano-beam as well as critical voltage and temperature rising. After verification with validated reference, comprehensive numerical results are presented to investigate the influence of important parameters such as various HSDBTs, length scale parameter (strain gradient parameter), the nonlocal parameter, the CNTs volume fraction, Pasternak's foundation coefficients, various boundary conditions, the CNTs efficiency parameter and geometric dimensions on the buckling behaviors of FG sandwich nano-beam. The numerical results indicate that, the amounts of the mechanical critical load calculated by PSDBT and TSDBT approximately have same values as well as ESDBT and ASDBT. Also, it is worthy noted that buckling load calculated by aforementioned theories is nearly smaller than buckling load estimated by FSDBT. Also, similar aforementioned structure is used to building the nano/micro oscillators.

Improvement of Mechanical Properties of IPMC through Developing a Degree of Dispersion of SWCNT/Nafion Composite (SWCNT/Nafion 복합체의 분산능 향상을 통한 IPMC의 기계적 특성 향상)

  • Kwon, Hui-June;Kim, Ha-Na;Kang, Jung-Ho
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.10 no.5
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    • pp.131-136
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    • 2011
  • Many researchers are recently studying about Electroactive polymer(EAP). But it has a physical limitation, because of property of material. Carbon nanotube(CNT) is known as the promising material which has excellent electro-mechanical characteristics and is mostly defect-free. It is expected that a successful synthesis of CNT and Nafion known as a primary material for IPMC would make a great improvement on its electro-mechanic feature. This study focuses on the method of synthesis of CNT with Nafion which improves electro-mechanical characteristic. To come up with mechanical dispersion with Nafion and Isopropyl Alcohol(IPA), we dispersed Single-walled carbon nanotubes(SWCNTs). For a uniformly layer of CNT, we used a spray gun on a hot plate by a simplified method. We fabricated a disperse SWCNT/Nafion composite uniformly. Through the use of the E-beam evaporator to form an uniform electrode layer, we consummated the IPMC actuator. This result shows improving 1.5 times mechanical properties about driving force in IPMC.

A Study on Physical Characteristics of Silica Aerogel/Polymer Composite Materials (실리카 에어로겔/고분자 복합재의 물리적 특성에 관한 연구)

  • Park, Kyoungwoo;Lee, Yeon;Yoon, Jong-Kuk;Koo, Kyung-Wan
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.9
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    • pp.1318-1323
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    • 2013
  • Thermal insulation material was prepared by cross-linking chemical reaction of silica aerogel and epoxy resin, which has a high porous and vacant properties. The structural, mechanical, and thermal properties were analyzed in order to verify its application for industrial and electrical applications. The thermal conductivities were changed from 115 mW/mK to 75 mW/mK by reducing the contents of nano-porous silica areogel powders. The compressive loading is also decreased by increasing the contents of silica aerogels by 20 wt% in aerogel/epoxy composites. It is concluded that the formulated composite materials can be applied to building materials, electronics parts, and heavy industries.