• Title/Summary/Keyword: n-hexanal

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Analysis of n-Hexanal in Headspace Vapor over Cooked Brown Rice by Direct Vapor Injection Gas Chromatography (현미취반시 생성되는 n-hexanal의 가스크로마토그래피에 의한 분리및 정량)

  • Shin, Myung-Gon;Rhee, Joon-Shick;Kwon, Tai-Wan
    • Korean Journal of Food Science and Technology
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    • v.17 no.5
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    • pp.406-408
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    • 1985
  • n-Hexanal in headspace over the cooked brown rice stored at $5^{\circ}C$ and $35^{\circ}C$ for 0. 4, 8 and 12 months was determined by a modified direct vapor injection gas chromatographic method. The retention time of n-hexanal was 3.5 min and n-hexanal could be rapidly separated from other compounds at the operational conditions of gas chromatography. n-Hexanal contents of cooked brown rice also showed a standard deviation of less than 10% of the average.

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Effect of Lactic-Fermentation on the n-Hexanal Content of Peanut Milk (젖산발효가 땅콩유(乳)의 n-Hexanal 함량에 미치는 영향)

  • Lee, Chan
    • The Korean Journal of Food And Nutrition
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    • v.26 no.1
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    • pp.146-149
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    • 2013
  • This study was performed to identify the effect of lactic-fermentation of peanut milk on n-hexanal content. Changes in viable cell populations, pH and titratable acidity indicated that there was a synergistic interaction between Lactobacillus delbrueckii subsp. bulgaricus and Streptococcus salivarius subsp. thermophilus during fermentation. The analysis of headspace volatiles revealed that n-hexanal nearly disappeared due to fermentation. S. salivarius subsp. thermophilus was more effective than L. delbrueckii subsp. bulgaricus in reducing the n-hexanal content.

Effects of Cooking on the n-Hexanal Content of Peanut Milk

  • Lee, Chan
    • Preventive Nutrition and Food Science
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    • v.6 no.3
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    • pp.197-199
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    • 2001
  • The effects of cooking peanut kernels before grinding on the n-hexanal content of peanut milk was investigated. Analysis of headspace volatiles revealed that n-hexanal was greatly reduced by cooking peanut kernels before grinding. Total solids and protein content tended to decrease as cooking time was increased. The most satisfactory condition of cooking peanut kernels for preparing peanut milk was 10 min.

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The Changes in the Physicso-Chemical Properties of Peanut Milk by Processing Conditions (가공조건에 따른 땅콩유의 물리화학적 특성의 변화)

  • Lee, Chan
    • The Korean Journal of Food And Nutrition
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    • v.14 no.3
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    • pp.199-203
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    • 2001
  • 땅콩유 제조시 땅콩의 침지시에 NaHCO$_3$를 첨가하는것과 분쇄전에 땅콩을 열처리하는 것이 n-hexanal 함량에 미치는 영향을 조사하기 위하여 headspace gas chromatgraphy 방법을 이용하여 조사하였다. 분쇄전에 땅콩을 열처리한 경우에는 n-hexanal함량이 현저하게 감소됨을 알 수 있었으며 열처리 시간이 증가함에 따라 n-hexanal 함량도 감소하지만 땅콩유중의 충고형분과 단백질함량도 함께 감소하였다. 이상의 결과로볼 때 콩비린내의 원인물질 중의 하나인 hexanal 함량의 감소를 위해서는 두유의 경우처럼 분쇄전에 땅콩을 열처리하는 것은 필수적이지만 지나친 열처리는 땅콩유는 단백질함량을 감소시켜 영양가가 저하시키므로 땅콩을 10분간 가열하는 것이 가장 바람직한 가공조건이라고 판단된다.

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The Effect of Lactic-fermentation on the Quality of Peanut Milk (젖산발효가 땅콩유의 품질에 미치는 영향)

  • Lee, Chan
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.3
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    • pp.439-443
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    • 2001
  • The effect of fermentation of peanut milk with lactic acid bacteria on n-hexanal content was investigated. Changes in pH, titratable acidity and viable cell populations indicated that Streptococcus salivarius subsp. thermophilus was adapted better than Lactobacillus delbrueckii subsp. bulgaricus during fermentation. Analysis of headspace volatiles revealed that n-hexanal, which is one of the compounds responsible for undesirable green/beany flavor in peanut milk, completely disappeared as a result of fermentation. S. salivarius subsp. thermophilus was more effective than L. delbrueckii subsp,. bulgaricus in reducing the n-hexanal content. No significant difference was found in water sorption between fermented and unfermented peanut milk.

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Effect of Blanching and Germination of Soybeans on the Quality of Soymilk (대두의 데치기와 발아가 두유의 품질에 미치는 영향)

  • Ha, Sang-Do;Kim, Sung-Soo;Park, Choul-Soo;Kim, Byung-Mook
    • Korean Journal of Food Science and Technology
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    • v.23 no.4
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    • pp.485-489
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    • 1991
  • In order to study the effects of blanching and germination of soybean on the quality of soymilk, the soybeans were differently treated as follow; (1) blanched for 5 min at $100^{\circ}C$, (2) germinated for 2 days at $25^{\circ}C$, (3) germinated for 2 days and then blanched for 5 min at $100^{\circ}C$. The qualities of various soymilks prepared from the treated soybeans were compared with those of soymilk from the untreated soybeans. Blanching of soybeans decreased yields, solid materials, viscosity, total protein, soluble nitrogen, and total sugar of soymilk but no effect on its free sugar contents, specific gravity, and pH. The blanching, however, improved the sensory properties and decreased the n-hexanal contents of soymilk to about 1/2.4. Germination of soybeans improved the yields, physical, chemical, and sensory properties and decreased the n-hexanal contents of soymilk to about 1/5. The germination plus blanching of soybeans showed kind of combined effects of germination's and of blanching's, resulting in the decrease of n-hexanal to about 1/10 and improvement in sensory properties of soymilk.

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Shelf-life Prediction of Brown Rice in Laminated Pouch by n-Hexanal and Fatty Acids During Storage (현미의 포장 저장 중 지방산 조성 및 헥사날의 변화에 의한 저장성 예측)

  • Han, Jae-Gyoung;Kim, Kwan;Kang, Kil-Jin;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.28 no.5
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    • pp.897-903
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    • 1996
  • The shelf-life of brown rice in laminated film (4-layered) pouch was analyzed at various temperatures $(4^{\circ}C,\;20^{\circ}C,\;30^{\circ}C\;and\;$40^{\circ}C)$ using n-hexanal content and fatty acid composition as a measure of deterioration. The far acidity of brown rice during storage showed sensitive responses at the storage temperature, resulting in the activation energy of 14.07 kcal/mole and $Q_{10}$ value of 2.22. The fatty acids in the brown rice were myristic, palmitic, stearic, oleic, linoleic and linolenic acid, and oleic acid was the moot predominant. The higher the temperature and the longer the storage periods, the higher the fatty acid contents except linoleic acid. The n-hexanal activation energy was 18.36 kcal/mole, and $Q_{10}$ value was 2.84. Based on the storage conditions, the shelf-life of brown rice was 80 days by n-hexanal and 60 days by fat acidity at room temperature $(21^{\circ}C)$.

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Variation of Volatile Composition in the Leaf of Zanthoxylum schinifolium Siebold et Zucc. & Zanthoxylum piperitum DC (산초나무와 초피나무 잎의 정유성분 변이)

  • Cho, Min-Gu;Chang, Chin-Sung;Chae, Young-Am
    • Korean Journal of Medicinal Crop Science
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    • v.10 no.3
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    • pp.162-166
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    • 2002
  • (Z)-ocimene+limonene, $(E)-{\beta}-ocimene$ and citronellal showed seasonal variation in the leaves of Z. schinifolium. Especially estragole was detected at fruiting stage regardless of collection sites. Common variation components in the leaves of Z. piperitum at all collection sites were (Z)-3-hexenol, ${\alpha}-pinene$, limonene and citronellal. The compositions with monthly variation in Z. schinifolium at arboretum were ${\alpha}-pinene$, myrcene, (Z)-3-hexenyl acetate, ${\alpha}-phellandrene$, (Z)-ocimene+limonene, ${\beta}-phellandrene$, linalool, geranyl acetate while in Z. piperitum were hexanal, (Z)-3-hexenol, (E)-2-hexenal, hexanol, ${\alpha}-pinene$, (Z)-ocimene, limonene, citronellal, geranyl acetate, ${\beta}-caryophyllene$. Estragole was not detected in Z. schinifolium leaves at arboretum due to too young tree to bearing fruit on it.

An in vivo Study of Lipid Peroxidation in Rats under Conditions of Oxidative Stress and the Antioxidant Effects of Probucol

  • Kim, Songsuk
    • Nutritional Sciences
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    • v.6 no.2
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    • pp.94-99
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    • 2003
  • The purpose of this study was to investigate in vivo lipid peroxidation in rats under conditions of streptozotocin-induced oxidative stress and the antioxidant effects of probucol. In vivo lipid peroxidation was observed by measuring low molecular weight aldehydes and related carbonyl compounds in rat urine. Three groups of male Wistar rats weighing 165-190 g were used: normal (N), streptozotocin-induced oxidative stress (OS) and oxidative stress plus probucol treatment (P). following streptozotocin treatment of the rats, a variety of secondary lipid peroxidation products were increased. The levels of butanal, hexanal, hex-2-enal, kept-2-enal, octanal, non-2-enal, deca-2,4-dienal, 4-hydroxyhex-2-enal, 4-hydroxyno n-2-enal, malondi aldehyde(MDA), and unknown carbonyl compounds were significantly increased in the oxidative stress group compared to the control group. Treatment with probucol resulted in significant decreases in buoal, hexanal, hex-2-enal, octanal, deca-2,4-dienal, 4-hydroxyhex-2-enal, MDA and unknown carbonyl compounds. Hept-2-enal, hepta-2,4-dienal and non-2-enal appeared to have a tendency to decrease due to pobucol treatment.

Changes in Quality Characteristics of Brown Rice During Storage (저장중 현미의 품질 특성 변화)

  • 신명곤;민봉기;김동철
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.20 no.3
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    • pp.276-280
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    • 1991
  • The quality changes of brown rice during storage were determined by the method of quantitative analysis of n-hexanal, amylogram, texture and volume expansion. The qualities of stored brown rice were also analyzed with sensory evaluation of cooked milled rice obtained from brown rice, n-Hexanal content, peak viscosity and total setback of brown rice flour pastes increased substantially with the increased of storage period at 35$^{\circ}C$. Up to 10 months of storage at 35$^{\circ}C$, stale flavor obtained by a sensory method markedly increased, but stickiness decreased. The scores of overall preference were in good agreement with those of stale flavor (r=-0.98) and sticky texture (r=0.98). The correlation coefficient between stale flavor obtained by a sensory method and instrumetal analysis for stored brown rice was r=0.97.

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