• Title/Summary/Keyword: motion of molecules

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Probing and Control of Surface Polarization Phenomena in Molecular Films for Organic Electronics

  • Iwamoto, Mitsumasa
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.3-4
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    • 2007
  • Orientational ordering of polar molecules and excess charges at the interface are main origins of surface polarization. For organic electronics, probing and control of these two surface polarization phenomena are key issues. In this presentation, I report a novel electrical measurement that can directly probe orientational dipolar motion in surface monolayers by Maxwell-displacement-current, and also report a novel optical technique that allows carrier motions in organic materials by measuring the optical second harmonic signals activated by the electric field. Then I discuss how the control of dipolar motions and carrier motions are linked to organic electronics applications such as organic field effect transistors.

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A Study on Stress Intensity Factors and Dislocation Emission via Molecular Dynamics (분자수준 시뮬레이션을 이용한 응력확대계수 및 전위이동에 관한 연구)

  • Choe, Deok-Gi;Kim, Ji-Un
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.4 s.175
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    • pp.830-838
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    • 2000
  • The paper addresses an application of molecular dynamics technique for fracture mechanics. Molecular dynamics simulation is an atomistic approach, while typical numerical methods such as finite element methods are macroscopic. Using the potential functions, which express the energy of a molecular system, a virtual specimen with molecules is set up and the trajectory of every molecule can be calculated by Newton's equation of motion. Several three-dimensional models with various types of cracks are considered. The stress intensity factors, the sizes of plastic zone as well as the dislocation emission are sought to be compared with the analytical solutions, which result in good agreement.

Single-Molecule Methods for Investigating the Double-Stranded DNA Bendability

  • Yeou, Sanghun;Lee, Nam Ki
    • Molecules and Cells
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    • v.45 no.1
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    • pp.33-40
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    • 2022
  • The various DNA-protein interactions associated with the expression of genetic information involve double-stranded DNA (dsDNA) bending. Due to the importance of the formation of the dsDNA bending structure, dsDNA bending properties have long been investigated in the biophysics field. Conventionally, DNA bendability is characterized by innate averaging data from bulk experiments. The advent of single-molecule methods, such as atomic force microscopy, optical and magnetic tweezers, tethered particle motion, and single-molecule fluorescence resonance energy transfer measurement, has provided valuable tools to investigate not only the static structures but also the dynamic properties of bent dsDNA. Here, we reviewed the single-molecule methods that have been used for investigating dsDNA bendability and new findings related to dsDNA bending. Single-molecule approaches are promising tools for revealing the unknown properties of dsDNA related to its bending, particularly in cells.

A Study of the Insulation Characteristic in $CF_4$ Gas (시뮬레이션에 의한 $CF_4$ 기체의 전자수송특성)

  • Kim, Sang-Nam;Hwang, Cheong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.468-469
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    • 2007
  • In this paper, the electron transport characteristics in $CF_4$ has been analysed over the E/N range 1~300[Td] by a two-tenn approximation Boltzmann equation method and by a Monte Carlo simulation. The motion has been calculated to give swarm parameters for the electron drift velocity, longitudinal diffusion coefficient, the ratio of the diffusion coefficient to the mobility, electron ionization and attachment coefficients, effective ionization coefficient, mean energy, collision frequency and the electron energy distribution function. The swarm parameter from the swarm study are expected to serve as a critical test of current theories of low energy electron scattering by atoms and molecules, in particular, as well as crucial information for quantitative simulations of weakly ionized plasmas.

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Effect of Molecular Aggregation on the Photo-Induced Anisotropy in Amorphous Polymethacrylate Bearing an Aminonitroazobenzene Moiety

  • Kim, Beom Jun;Park, Su Yeong;Choe, Dong Hun
    • Bulletin of the Korean Chemical Society
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    • v.22 no.3
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    • pp.271-275
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    • 2001
  • We investigated H-type molecular aggregation in a simply spin-coated amorphous homopolymer film of polymethacrylate containing push-pull azobenzene moieties. It was found that the aggregate formation was strongly influenced by thermal treatment an d that the aggregate created in the polymer film could be easily disrupted by irradiation of a linearly polarized light. In the first writing cycle of aggregated polymer film, photo-induced birefringence showed a steep increase to the highest value followed by a gradual decrease to the certain asymptotic value under longer irradiation of a linearly polarized light. This unique behavior could be attributed to the cooperative motion and the disruption of the aggregated molecules under continuous irradiation of light.

A study on the manufacture and dielectric of the polyvinylidene fluoride thin films through vapor deposition method (진공증착법을 이용한 PVDF박막의 제작과 유전 특성에 관한 연구)

  • Park, S.H.;Im, U.C.;Cho, K.S.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1995.11a
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    • pp.420-422
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    • 1995
  • PVDF (polyvinylidene fluoride) has at least from known crystalline structure ( ; they are referred to as the $\alpha$, $\beta$, $\gamma$ and $\alpha_p$ phase or forms II, I, III and $IV_p$). In this study, the manufactured PVDF thin films through vapor deposition method had for II ( ; the substrate temperature at 30$^{\circ}C$). The dielectric behavior of poly(vinylidene fluoride) is affected by orientation and crystal modification. The very high value of the dielectric constant for high temperature conditioned film is believed to be due to the orientation effect. The loss peak caused by molecular motion of the molecules in crystalline regions.

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Electron Energy Distribution Function in $CF_4$ Gas used by MCS-BE Algorithm ($CF_4$ 기체의 MCS-BEq 알고리즘에 의한 전자에너지 분포함수)

  • Park, Jae-Sae;Kim, Sang-Nam;Kim, Il-Nam
    • Proceedings of the KIEE Conference
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    • 2002.06a
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    • pp.102-105
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    • 2002
  • In this paper, the electron transport characteristics in $CF_4$ has been analysed over the E/N range 1${\sim}$300 [Td] by a two-term approximation Boltzmann equation method and by a Monte Carlo simulation. The motion has been calculated to give swarm parameters for the electron drift velocity, longitudinal diffusion coefficient, the ratio of the diffusion coefficient to the mobility, electron ionization and attachment coefficients, effective ionization coefficient, mean energy, collision frequency and the electron energy distribution function. The swarm parameter from the swarm study are expected to serve as a critical test of current theories of low energy electron scattering by atoms and molecules, in particular, as well as crucial information for quantitative simulations of weakly ionized plasmas.

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The wake flow control behind a circular cylinder using ion wind (이온풍을 이용한 실린더 뒤의 후류 제어)

  • Hyun K T;Chun C H
    • Proceedings of the KSME Conference
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    • 2002.08a
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    • pp.459-462
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    • 2002
  • Many active and passive flow control methods have been studied since decades, but there are only few works about flow control methods using ion wind. This paper presents an experimental study on the wake control behind a circular cylinder using ion wind, a bulk motion of neutral molecules driven by locally ionized air of corona discharge. Experiments are done f3r different electrohydrodynamic numbers - the ratio of an electrical body farce to a fluid Inertial force - from 0 to 2 and for the Reynolds number ranging from $4{\times}10^3\;to\;8{\times}10^3$. Pressure distributions over a cylinder surface are measured and flow visualizations are carried out by smoke wire method. Flow visualizations confirm that ion wind affects significantly the wake structure behind a circular cylinder and pressure drag could be dramatically reduced by the superimposing ion wind.

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Percolation Approach to the Morphology of Rigid-Flexible Block Copolymer on Gas Permeability

  • 박호범;하성룡;이영무
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.69-70
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    • 1997
  • Polyimides and related polymers, when synthesized from aromatic monomers, have generally rigid chain structures resulting in a low gas permeability. The rigidity of polymer chains reduces the segmental motion of chains and works as a good barrier against gas transport. To overcome the limit of use as materials of gas separation membranes due to low gas permeability, block copolymers with the incorporation of flexible segments like siloxane linkage and ether linkage have been studied. These block copolymers have microphase-separated structures composed of microdomains of flexible poly(dimethylsiloxane) or polyether segments and of rigid polyimides segments. In case of rigid-flexible block copolymers, the characteristics of both phases for gas permeation are of great difference. The permeation of gas molecules occurs favorably through microdomains of flexible segments, whereas those of rigid segments hinder the permeation of gas molecules. Accordingly the increase of content of flexible segments in a rigid polymer matrix will increase the gas permeability of the membrane linearly. However, this prediction does not satisfy enough many experimental results and in particular the drastic increase of the permeability is observed in a certain volume fraction. It was proposed that the gas transport mechanism is dominated by diffusion rather than gas solubility in a certain content of flexible phase if solution-diffusion mechanism is adopted. However, the transition from solubility-dependent to diffusion-dependent cannot be explained by the understanding of mechanism itself. Therefore, we consider an effective chemical path which permeable phase can form in a microheterogenous medium, and percolation concept is introduced to describe the permeability transition at near threshold where for the first time a percolation path occurs. The volume fraction of both phases is defined as V$_{\alpha}$ and V$_{\beta}$ in block copolymers, and the volume of $\beta$ phase in the threshold forming geometrically a traversing channel is defined as V$_{\betac}$. The formation mechanism of shortest chemical channel is schematically depicted in Fig. 1.

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The Effects of Reciprocal Peer Questioning Strategy in Concept Learning on the Three States of Matter and Motion of Molecules (물질의 세 가지 상태 및 분자의 운동에 대한 개념 학습에서 상호동료 질문생성 전략의 효과)

  • Kim, Kyung-Sun;Kim, So-Yeon;Lee, Jung-Min;Noh, Tae-Hee
    • Journal of The Korean Association For Science Education
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    • v.27 no.5
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    • pp.394-403
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    • 2007
  • In this study, the effects of reciprocal peer questioning (RPQ) strategy upon students' concept learning were investigated. Ninety-two seventh graders at a co-ed middle school were assigned to control, reciprocal peer tutoring (RPT), and RPQ groups. The students were taught about 'three states of matter' and 'motion of molecules' for 12 class hours. Regardless of students' prior science achievement level, the RPQ group showed the highest scores among the three groups in the test of conceptual understanding, and the RPT group performed better than the control group. For high-level students, the scores of the RPQ group were significantly higher than those of the other groups in the test of the concept application, and those of the RPT group were higher than those of the control group. For low-level students, the scores of the RPT and RPQ groups in the concept application test were significantly higher than those of the control group, while those of the RPT and RPQ groups were not significantly different. These results indicated that verbal interaction by reciprocal tutoring helped students to understand chemical concept learning, and that using self-generated questions was more effective. Therefore, RPQ strategy is suggested to become one of the useful instructional methods to facilitate verbal interaction and concept learning in middle school science instructions.