• Title/Summary/Keyword: morphology development

Search Result 1,079, Processing Time 0.026 seconds

Morphology Development in a Range of Nanometer to Micrometer in Sulfonated Poly(ethylene terephthalate) Ionomer

  • Lee, Chang-Hyung;Inoue, Takashi;Nah, Jae-Woon
    • Bulletin of the Korean Chemical Society
    • /
    • v.23 no.4
    • /
    • pp.580-586
    • /
    • 2002
  • We investigated the effect of ionic component on crystalline morphology development during isothermal annealing in a sodium neutralized sulfonated poly(ethylene terephthalate) ionomer (Ion-PET) by time-resolved small-angle x-ray scattering (TR-SAX S) using synchrotron radiation. At early stage in Ion-PET, SAXS intensity at a low annealing temperature (Ta = 120 $^{\circ}C)$ decreased monotonously with scattering angle for a while. Then SAXS profile showed a peak and the peak position progressively moved to wider angles with isothermal annealing time. Finally, the peak intensity decreased, shifting the peak angle to wider angle. It is revealed that ionic aggregates (multiplets structure) of several nm, calculated by Debye-Bueche plot, are formed at early stage. They seem to accelerate the crystallization rate and make fine crystallites without spherulite formation (supported by optical microscopy observation). From decrease of peak intensity in SAXS,it is suggested that new lamellae are inserted between the preformed lamellae so that the concentration of ionic multiplets in amorphous region decreases to lower the electron density difference between lamellar crystal and amorphous region. In addition, analysis on the annealing at a high temperature (Ta = 210 $^{\circ}C)$ by optical microscopy, light scattering and transmission electron microscopy shows a formation of spherulite, no ionic aggregates, the retarded crystallization rate and a high level of lamellar orientation.

Morphology of Halloysite Particles and Aggregates in the Weathering of Anorthosite (회장암 풍화과정에서 생성되는 할로이사이트 입자 및 집합체의 형태)

  • 정기영;김영호
    • Journal of the Mineralogical Society of Korea
    • /
    • v.9 no.2
    • /
    • pp.64-70
    • /
    • 1996
  • Early weathering products of anorthosite were investigated by using scanning electron microscopy in order to trace the development of halloysite particles and aggregates. Tiny short tubes or spheres precipitate on the plagioclase surface in the initial stage of weathering and form the compact globular aggregates. With continued growth, several globules are coalesced into wrinkled halloysite aggregates, and short tubes or spheres in globules grow into long tubes forming sheaf-like aggregates. Particle shape of halloysite varies with changing supersaturation degree of weathering solution, and determines the morphology of halloysite aggregates.

  • PDF

Comparison of Storage Stability, Volatile Compounds and Sensory Properties between Coarsely-and Finely-Marbled 1+ Grade Hanwoo Beef Loins

  • Cho, Soohyun;Lee, Wangyeol;Seol, Kuk-Hwan;Kim, Yunseok;Kang, Sun Moon;Seo, Hyunwoo;Jung, Younbok;Kim, Jinhyoung;Ba, Hoa Van
    • Food Science of Animal Resources
    • /
    • v.40 no.4
    • /
    • pp.497-511
    • /
    • 2020
  • This study aimed at comparing the storage stability, fatty acids profile, volatile flavor compounds and eating quality of Hanwoo beef longissimus thoracis (LT) muscles between two marbling morphological groups (fineness and coarseness). The 1+ grade Hanwoo LT muscles were measured for marbling fleck morphology at the 13th thoracic vertebrae location by using computerized image analysis. Results reveal that both marbling groups had similar proximate composition (protein, fat, moisture and collagen), color and technological quality traits (p>0.05). However, the coarse marbling group presented greater C18:2n6 and polyunsaturated fatty acids contents compared to the fine marbling group (p<0.05). Furthermore, the fine marbling group presented lower volatile basic nitrogen (VBN) and 2-thiobarbituric acid reactive substance (TBARS) contents compared to the coarse marbling group after 14 d storage (p<0.05). Also, higher amounts of C18:2n6 oxidation-derived volatile compounds such as hexanal and 3-ethyl-2-methyl-1,3-hexadiene, were found in the coarse marbling group. In term of sensory aspects, the finely-marbled group received higher scores of flavor and taste compared to the coarse marbling group (p<0.05). Overall, the marbling flecks morphology partially showed its effects on the storage stability, fatty acids profile and eating quality of the 1+ grade Hanwoo beef LT muscle.

Effects of Sperm Morphology on the Results of Conventional IVF and ICSI (정자의 형태가 IVF와 ICSI의 결과에 미치는 영향)

  • Kwon, Yoon-Jung;Kang, Hee-Gyoo;Kim, Soo-Kyung;Yang, Hyun-Won;Choi, Kyoo-Wan;Cha, Young-Beom;Lee, Seung-Jae;Park, Jong-Min
    • Clinical and Experimental Reproductive Medicine
    • /
    • v.22 no.3
    • /
    • pp.293-299
    • /
    • 1995
  • Objective: To investigate the effects of sperm morphology and their co-incubation with oocytes on the outcome of IVF and ICSI. Design: Strict morphology of washed sperm was assessed by Diff-Quick staining method before or after insemination. And the relationships between strict morphology and outcome (fertilization, embryo development and pregnancy) of IVF(with co-incubation) and ICSI (without co-incubation) were determined. Patients: Two-hundreds-and-sixty-three cycles of IVF and ninety-six cycles of ICSI were analyzed in order to clarify the influence of strict sperm morphology of spermatozoa on outcome of IVF and ICSI. These were divided into four groups. according to fertilization method and sperm morphology(Group 1: IVF, ${\geq}$12%, n:227; Group 2: IVF, <12%, n:36; Group 3: ICSI, ${\geq}$ 12%, n=48; Group 4: ICSI, <12%, n=48). Results: The fertilization rates of better morphology groups were higher than those of poor groups: Group 1(68.1%) > Group 2(62.1%), Group 3(78.1%) > Group 4(71.5%). There was no difference in embryo cleavage rates among four groups (>90%), Regarded with the good embryo rates, Group 1(56.8%) was significantly higher than Group 2(42.3%)(P<0.01), but there was no difference between Group 3(64.7%) and Group 4(61.2%). The pregnancy rates were also higher in better morphology groups as well as fertilization rates: Group 1(34.8%)> Group 2(16.7%)(p<0.05), Group 3(40.0%) > Group 4(23.0%)(p=0.08). Conclusion: Co-incubation with poor morphology sperm might adversely affect the quality of embryos. And strict sperm morphology may represent the ability to establish successful pregnancy. In short, the strict sperm morphology can be a good predictor of IVF and ICSI outcome.

  • PDF

Preliminary Study on the Development of a Platform for the Optimization of Beach Stabilization Measures against Beach Erosion II - Centering on the Development of Physics-Based Morphology Model for the Estimation of an Erosion Rate of Nourished Beach (해역별 최적 해빈 안정화 공법 선정 Platform 개발을 위한 기초연구 II - 양빈 된 해빈 침식률 산정을 위한 물리기반 해빈 지형모형 개발을 중심으로)

  • Cho, Yong Jun
    • Journal of Korean Society of Coastal and Ocean Engineers
    • /
    • v.31 no.5
    • /
    • pp.320-333
    • /
    • 2019
  • In this study, a physics-based 3D morphology model for the estimation of an erosion rate of nourished beach is newly proposed. As a hydrodynamic module, IHFOAM toolbox having its roots on the OpenFoam is used. On the other hand, the morphology model comprised a transport equation for suspended sediment, and Exner type equation derived from the viewpoint of sediment budget with the bed load being taken to accounted. In doing so, the incipient motion of sediment is determined based on the Shields Diagram, while the bottom suspended sediment concentration, the bed load transport rate is figured out using the bottom shearing stress directly calculated from the numerically simulated flow field rather than the conventional quadratic law and frictional coefficient. In order to verify the proposed morphology model, we numerically simulate the nonlinear shoaling, breaking over the uniform beach of 1/m slope, and its ensuing morphology change. Numerical results show that the partially skewed, and asymmetric bottom shearing stresses can be successfully simulated. It was shown that sediments suspended and eroded at the foreshore by wave breaking are gradually drifted toward a shore and accumulated in the process of up-rush, which eventually leads to the formation of swash bar. It is also worth mentioning that the breaker bar formed by the sediments dragged by the back-wash flow which commences at the pinnacle of up-rush as the back-wash flow gets weakened due to the increased depth was successfully duplicated in the numerical simulation.

Effects of ANTORIN R-10 on Ovarian Morphology, Follicular Development and Serum Estradiol Level in Immature Wistar Rats (미성숙 Wistar 랫트에서 ANTORIN R-10이 난소형태, 난포발육 및 혈중 호르몬 농도에 미치는 영향)

  • Kang, Eun-Ju;Yoo, Jae-Gyu;Song, Hye-Jin;Song, Seung-Hee;Rho, Gyu-Jin;Choe, Sang-Yong
    • Journal of Veterinary Clinics
    • /
    • v.24 no.4
    • /
    • pp.563-567
    • /
    • 2007
  • This study evaluated the effect of ANTORIN R-10(pFSH), a commercially available follicle stimulating hormone on ovarian morphology, on follicular development and serum estradiol levels in rats. Immature female Wistar S/T rats(27 day old; 80-100 g B.wt) maintained under controlled environmental conditions($22{\pm}2^{\circ}C$; 50% humidity; 12 h light/12 h dark cycle) with free access to standard laboratory feed and tap water were utilized. Animals were allowed to acclimatize to the new environment for at least 2 weeks before being included in the experiment. Rats were randomly allotted to 5 groups(Control, SL 0.1AU, SH 0.2AU, TL 0.1AU and TH 0.2AU). ANTORIN R-10 was subcutaneously injected twice daily for 3 days. Twenty hours after hormone treatment, blood was collected to estimate the serum estradiol $17-\beta$ concentration. Immediately, all rats were sacrificed and the ovarian morphology, ovary weight and number of follicles were recorded. Ovaries were fixed for histomorphological examination. Higher standard and treatment groups were significantly increased on ovary weight and the number of follicles more than 1mm compared with lower standard and treatment. However, no difference revealed between standard and treatment groups. ANTORIN R-10 was similar effects of follicles development and maturation compared with House standard FSH.

Developmental Morphology of Osmundea crispa (Ceramiales, Rhodophyta) from California

  • Nam Ki Wan;Choi Han Gil
    • Fisheries and Aquatic Sciences
    • /
    • v.2 no.1
    • /
    • pp.25-31
    • /
    • 1999
  • Developmental morphology of the red alga, Osmundea crispa (Hollenberg) Nam from California was studied on the basis of liquid-preserved and herbarium specimens. Vegetative axial segment of the species produces two pericentral cells and one trichoblast. Spermatangial filaments (branches) are derived from apical and epidermal cells in pocket-shaped apical pit with an ostiole-like upper opening. Procarp-bearing segment of female trichoblast produces five pericentral cells, of which the fifth functions as supporting cell of carpogonial branch. Tetrasporangial production occurs in random epidermal cells in apical pit of branchlets, and two presporangial cover cells show parallel arrangement to stichidial axis. As this vegetative and reproductive development is included in the generic delineation of Osmundea Stackhouse, O. crispa among the known Osmundea species is characterized by habit forming compact cushion-like clump with angular to terete thallus. It is also distinguished from O. hybrida (AP. de Candolle) Nam without the compressed thallus by the number of pericentral cells in procarp-bearing segment and shape of spermatangial pit. Taxonomic implication of the shape of spermatangial pit is also included.

  • PDF

Effect of gypsum content on the properties of PVC/Gypsum polymer blend material (PVC/Gypsum 복합체에서 Gypsum 의 영향)

  • N. V. Gian;Thai Hoan;Kim, M. Y.
    • Proceedings of the Korean Society For Composite Materials Conference
    • /
    • 2003.10a
    • /
    • pp.221-224
    • /
    • 2003
  • Polyvinyl chloride (PVC)/gypsum Polymer blend materials were prepared by melt blending of PVC with gypsum and additives. Effect of gypsum content on the properties of PVC/gypsum Polymer blend material was studied by investigating physico-mechanical properties, thermal properties and morphology development. It was found that the replacement of gypsum for methylene-butadiene-sarene (MBS) component in PVC/gypsum polymer blend material enhanced the tensile strength, but gradually decreased its impact strength. Besides, with the increase of gypsum content, the elongation at break of material gradually decreased. The Presence of the different gypsum contents made a shift of g1ass transition temperature and increased the thermal stability as well as the processing temperature range of polymer blends. The observation of morphology, the results of the physico-mechanical properties and thermal properties proved simultaneously that PVC/gypsum Polymer blend material with the gypsum content of 22.56 wt.% reached the optimum results among five kinds of PVC/gypsum Polymer blend materials investigated.

  • PDF

Preparation of Al-Sn Coating Bearings by RF Sputtering Method and Evaluation of Their Properties (RF 스퍼터링법에 의한 Al-Sn계 코팅베어링의 제작과 특성 평가)

  • 이찬식;이명훈
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.24 no.6
    • /
    • pp.139-146
    • /
    • 2000
  • The development of high performance materials is very important subject in order to enhance the properties of bearings whose role is to transfer energy harmoniously by reducing the problem of friction and wear down, etc. between the interacting solid surfaces in relative motion under high loads in comply with mechanical operating mechanism of engines. In this study, several (100-x)Al-xSn coating films (where x=85, 75, 65 atomic % at Al) on substrates which are abt. 2mm thickenss of Kelmet layer sintered back steel were prepared by using RF sputtering system. These coating films were observed the morphology by SEM(Scanning Electron Microscope) and investigated the crystal structure by XRD(X-ray Diffractor) for their properties. And friction coefficient of these films was measured by ball-on-disc tester for their tribological properties. From the experimental results, it was shown that high performance properties of bearing can be improved greatly by controlling the composition and morphology of material surface with effective use of the plasma-assisted sputtering process.

  • PDF

A study on the change of the fatigue life and the fracture morphology due to the carbon black on the Natural rubber for vibration-proof (철도차량 부쉬용 방진 천연고무의 카본블랙 강화제에 의한 피로수명과 파단 모폴로지 변화 연구)

  • Kim Jae-Hoon;Hur Hyun-Moo
    • Journal of the Korean Society for Railway
    • /
    • v.8 no.1
    • /
    • pp.21-26
    • /
    • 2005
  • The effects of carbon black on the fatigue lift and the fracture morphology and the carbon black dispersion of the carbon-black filled natural rubbers, for the vibration-proof, were investigated. Different kinds of carbon blacks resulted in different fatigue lift and fracture morphologies, which are classified by micro-scale and macro-scale fracture morphologies. These results be related to the size distribution of carbon black particles, the development of the carbon black agglomerate and the combine forces between the carbon black and the natural rubber.