• Macromolecular Research
• /
• v.15 no.2
• /
• pp.147-153
• /
• 2007

Hyperbranched polysiloxysilanes (HBPSs), with a variety of terminal functional groups (vinyl, epoxy, carboxyl and hydroxyl), were synthesized by the self-polymerization of an $AB_3$ type monomer of tris(dimethylvinylsiloxy) silane, with subsequent end-functionalizations, such as epoxidation and radical addition reaction, respectively. The ratio of the $\alpha-and$ $\beta-addition$ linkages in the HBPS polymerized by hydrosilylation of the $AB_3$ monomer was found to be approximately 1 to 3. The thermal stability and solubility were affected by the terminal functional groups.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2021.11a
• /
• pp.162-163
• /
• 2021

To prepare the waterborne silicone acrylic resin coatings, acrylic resin was prepared by a radical polymerization. Glass transition temperature(Tg) of the acrylic copolymer was fixed at 30℃ and the contents of tertiary amine monomer(DMAEMA), were varied to be 5, 10, 15 and 20 wt%, hydroxyl monomer, and carboxyl monomer were fixed 10 wt%, and 4 wt% respectively. γ-Glycidoxypropyltrimethoxysilane(GPTMS) containing epoxy group was used for curing agents. The eqivalent ratio of amine to epoxy was 1:1. The prepared coatings exhibited excellent adhesion to various substrates, and various physical properties of the coatings were satisfactory. The gloss retension and color difference were improved at low tertiary amine concentration. The coatings containing 10wt% tertiary amine concentration have especially good weather resistant properties.

• Membrane Journal
• /
• v.14 no.3
• /
• pp.207-217
• /
• 2004

In this study, we prepared nanofiltration membrane by applying the interfacial polymerization method as a way of manufacturing composite membranes. We have examined the effects of various preparation factors such as monomer concentration and composition, thermal curing condition, post treatment condition. In addition to preparation conditions, we also monitored the effects of operation conditions such as feed solution concentration and operation pressure on the permeation properties of the resulting nanofiltration membrane. We intended to increase the permeation rate of nanofiltration membrane by the enlargement of effective surface area using additives during interfacial polymerization step. With increasing the monomer concentration, membrane permeation rate are decreased with maintaining almost constant rejection. With respect to curing condition, with increasing the curing temperature both permeation rate and rejection are decreased. With increasing the ratio of MPD in amino monomer composition, permeation rate decreased drastically with high rejection. With increasing the feed solution concentration, both permeation rate and rejection decreased. Both permeation rates and rejection increased with increasing the operating pressure. Nanofiltration membrane have higher surface roughness with increasing additive concentration in the case of using MPD contained amine composition than using piperazine alone. Permeation rates are much lower than the nanofiltration membrane prepared by piperazine.

• Applied Chemistry for Engineering
• /
• v.28 no.4
• /
• pp.485-489
• /
• 2017

Polyethylene terephthalate (PET) has been widely applied in polymers and packaging industries to produce synthetic fibers, films, drink bottles or food containers. Therefore, it has become one of the major plastic wastes. In this article, glycolysis known as one of the main methods in PET chemical recycling was investigated using a glycol to break down the polymer into a monomer. Glycolysis of PET and ethylene glycol was performed in a micro-tubing reactor under various conditions. The effect of glycolysis conditions on the product distribution was investigated at experimental conditions of the EG/PET ratio of 1~4, the reaction time of 15~90 min and the reaction temperature of $250{\sim}325^{\circ}C$ with Mn and Cu catalysts. The highest yield of bis (2-hydroxyethyl) terephthalate monomer (BHET) was obtained as 89.46 wt% under the condition of the reaction temperature of $300^{\circ}C$ and the time of 30 min using 10 wt% $Cu/{\gamma}-Al_2O_3$ catalyst, with the PET and ethylene glycol ratio of 1 : 2.

• Journal of the Microelectronics and Packaging Society
• /
• v.23 no.3
• /
• pp.15-20
• /
• 2016

In an effort to overcome the weakness of aerogel, polymer aerogels have been prepared by copolymerizing the different types of monomers through sol-gel process. Polymerizing the successive phase of a high internal phase emulsion, which has interconnected porous structure, porous polymer aerogel can be manufactured. In this paper, we use the styrene/divinylbenzene chain as a basic monomer structure, and additionally use 2-ethylhexyl methacrylate (2-EHMA) or 2-ethylhexyl acrylate (2-EHA) as monomers for distinguishing the visible mechanical properties of synthesized polymer aerogel. We can observe the different tendency of polymer aerogels by kinds of monomer or ratio. Flexibility and microstructure can be changed by the types of monomer. EHA polymer aerogel shows high flexibility and thin microstructure, and EHMA polymer aerogel shows high hardness and thick microstructure. EHA/EHMA polymer aerogel shows the intermediate nature between them. By utilizing the mechanical properties of three types of polymer aerogels to adequate situation or environment, polymer aerogels could be used as drug agent, ion exchange resin, oil filter and insulator, and so on.

• Journal of the Korean Graphic Arts Communication Society
• /
• v.22 no.1
• /
• pp.83-94
• /
• 2004

PSR ink is used to insulation coating material that heat resistance is. The use purpose is used for bridge prevention, circuit protection, stabilization of insulation. Heat-cured resin was used mainly on the materials of PSR inks. But, UV-curing type resin in used. Also, because of recently environmental problem, ink is going to water type. Purpose of this study is to develop PSR ink that can develop in pure water. and experiment did that do from that find suitable oligomer and monomer and does brand ratio differ. Specially Knew that is extent water soluble UV resin develop possible is DPHA 10~50% that A/A1924 is 50~90wt %, monomer. As a result, when ratio of A/A1924 and DPHA low viscosity epoxy resin is 5:1.5:1.5, could get high sensibility pattern repeatability, tack and alkali-resistance.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.23 no.5
• /
• pp.621-627
• /
• 1999

This paper presents Raman scattering of liquid water to obtain the characteristics with variation of temperature. Very clear Stokes-Raman signals were observed, which shows H-O vibration stretching and H-O-H vibration bending. The obtained spectrum were processed by FFT filter to extract the noise and base. The spectral shape of the H-O stretching provided a various sensitive signature which allowed temperature to be determined by a curve-fitting technique. Those are Maximum Intensity, Maximum Wave Length, FWHM(Full Width at Half Maximum), PMCR(Polymer Monomer Concentration Ratio) and TSIR(Temperature Sensitive Intensity Ratio). TSIR method shows the highest accuracy of $0.1^{\circ}C$ in mean error and $0.32^{\circ}C$ In maximum error.

• Korean Journal of Materials Research
• /
• v.32 no.4
• /
• pp.193-199
• /
• 2022

In this study, lenses are fabricated using various nanomaterials as additives to a silicone polymer made with an optimum mixing ratio and short polymerization time. In addition, PVP is added at a ratio of 1 % to investigate the physical properties according to the degree of dispersion, and the compatibility with hydrophobic silicone and the possibility of application as a functional lens material are confirmed. The main materials are SIU as a silicone monomer, DMA, a hydrophilic copolymer, EGDMA as a crosslinking agent, and 2H2M as a photoinitiator. Holmium (III) oxide, Europium (III) oxide, aluminum oxide, and PVP are used. When Holmium (III) oxide and Europium (III) oxide are added based on the Ref sample, the characteristics of the lens tend to be similar overall, and the aluminum oxide shows a tendency slightly different from the previous two oxides. This material can be used as a silicone lens material with various nano oxides and polyvinylpyrrolidone (PVP) acting as a dispersant.

• Journal of the Korean Applied Science and Technology
• /
• v.28 no.1
• /
• pp.35-47
• /
• 2011

For the synthesis of water soluble acrylic modified epoxyester resin, fatty acid/epoxy ratio of 50/50 was used, and introduced maleic anhydride. Ratio of styrene/acrylic acid of acrylic monomers was fixed 85/15 and ratio of epoxyester/acrylic monomer was controlled 80/20, 75/25, 70/30, 65/35, and degree of neutralization were changed 65%, 80%, to 100%. As a result, 40% solids acrylic modified epoxyester resins were synthesized. Resins were evaluated water soluble stability, drying time, water resistant, storage stability and physical properties. And the white paints were prepared, and were evaluated viscosity, drying time, water resistance, adhesion, sagging, spray workability, gloss, salt spray resistance, skinning, whiteness and flash rust. As a result, the degree of neutralization of 100% and the ratio of epoxyester/acrylic monomer of 75/25 showed the best properties.

• Polymer(Korea)
• /
• v.34 no.3
• /
• pp.247-252
• /
• 2010

This paper investigates the effects of the monomer ratios on the typical properties of polymer-modified mortars that contain methyl methacrylate-based latexes. Basic data are also obtained to develop appropriate latexes for cement modifiers. Polymer-modified mortars that contain methyl methacrylate latexes copolymerized with butyl acrylate or ethyl acrylate are prepared for different polymer-cement ratios. They are then tested to obtain the tensile and tensile adhesive strengthes of polymer-modified mortar with methyl methacrylate-based latexes. From the test results, the tensile strength of MB7 polymer-modified mortar was higher than normal cement mortar by a maximum of 94% with a 20% polymer-cement ratio, which was almost twice higher than normal. The tensile adhesive strength of the MB polymer-modified mortar was higher for higher MMA monomer contents and polymer-cement ratios, and increased up to four times than that of normal cement mortar. The basic properties of the polymer-modified mortars are more affected by the polymer-cement ratio than by the monomer ratio, and are improved over unmodified mortar.