• Title/Summary/Keyword: mono ethanol amine

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A Study on the Growth Pattern of ZnO Particles in Chemical Solutions (용액상에서 합성된 ZnO 입자의 생성과정에 관한 연구)

  • Kim Hak-Soo;Kim Donghwan
    • Korean Journal of Materials Research
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    • v.15 no.10
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    • pp.678-682
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    • 2005
  • We studied the possibility of $Zn_4O(Ac)_2(OH)$ formation as a precursor for ZnO nano particles in sol-gel method. Four different additives such as tetra methyl ammonium hydroxide, mono ethanol amine (MEA), LiOH, and $H_2O$ were used for zinc acetate dissolved in 2-methoxy ethanol. ZnO particles of 5-6 nm in size were observed. Existence of $Zn_4O(Ac)_6$ was not verified. $Zn_4O(Ac)_2(OH)$ molecules were observed and they were believed to be the precursors of ZnO. A peak at 275nm in UV-Vis analysis was observed In the case of MEA and $H_2O$ but no ZnO particles were detected in transmission electron microscopy.

Process Improvement and Evaluation of 0.1 MW-scale Test Bed using Amine Solvent for Post-combustion CO2 Capture (0.1 MW급 연소후 습식아민 CO2 포집 Test Bed 공정개선효과 검증)

  • Park, Jong Min;Cho, Seong Pill;Lim, Ta Young;Lee, Young ill
    • KEPCO Journal on Electric Power and Energy
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    • v.2 no.1
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    • pp.103-108
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    • 2016
  • Carbon Capture and Storage technologies are recognized as key solution to meet greenhouse gas emission standards to avoid climate change. Although MEA (monoethanolamine) is an effective amine solvent in $CO_2$ capture process, the application is limited by high energy consumption, i.e., reduction of 10% of efficiency of coal-fired power plants. Therefore the development of new solvent and improvement of $CO_2$ capture process are positively necessary. In this study, improvement of $CO_2$ capture process was investigated and applied to Test Bed for reducing energy consumption. Previously reported technologies were examined and prospective methods were determined by simulation. Among the prospective methods, four applicable methods were selected for applying to 0.1 MW Test Bed, such as change of packing material in absorption column, installing the Intercooling System to absorption column, installing Rich Amine Heater and remodeling of Amines Heat Exchanger. After the improvement construction of 0.1 MW Test Bed, the effects of each suggested method were evaluated by experimental results.

Absorption Equilibrium of CO2 in the Sterical Hindered Amine, AMP Aqueous Solution (입체장애아민 AMP (2-amino 2-methyl 1-propanol) 수용액의 CO2 흡수평형)

  • Han, Keun-Hee;Lee, Jong-Seop;Min, Byoung-Moo
    • Korean Chemical Engineering Research
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    • v.45 no.2
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    • pp.197-202
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    • 2007
  • This research was basically carried out to extend the application of $CO_2$ absorption processes for flue-gas system, which are mainly applied to a reforming process in petro-chemical industries. In general, MEA absorbent has some problems in flue-gas treatment, such as, degradation, regeneration energy and absorption capacities. As we known, sterical hindered amine, typically AMP (2-amino 2-methyl 1-propanol), have a good potential to improve these problems. In this paper, the characteristics of $CO_2$ absorption in aqueous AMP solution were measured and compared with that of MEA. It has been found that the $CO_2$ absorption capacity in AMP is double than that of MEA in the low $CO_2$ partial pressure system such as flue-gas. Also, the equilibriums of $CO_2$-AMP system were partially suggested, which are essentially needed to design the absorption process.

Separation of Carbon Dioxide Using Pelletized Zeolite Adsorbent with Amine Impregration (아민 함침 성형 제올라이트 흡착제를 이용한 이산화탄소 분리)

  • Hong, Mi So;Pankaj, Sharma;Jung, Yun Ho;Park, Sung Youl;Park, So Jin;Baek, Il Hyun
    • Korean Chemical Engineering Research
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    • v.50 no.2
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    • pp.244-250
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    • 2012
  • In order to separate of carbon dioxide in the combustion exhaust gas, monoethanolamine (MEA) and piperazine (PZ) impregnated zeolite 13X adsorbents were used. A series of adsorbents were synthesized by impregnating 30, 50 and 70 wt% of MEA and PZ respectively on zeolite 13X pellet. XRD, FT-IR and BET were used to characterize the properties of impregnated pelletized zeolite 13X absorbents. In order to investigate the separation characteristics of carbon dioxide, zeolite pellet, MEA impregnated zeolite and PZ impregnated zeolite pellet were investigated at 25, 50 and $75^{\circ}C$. Amine impregnated pelletized zeolite absorbent has shown that adsorption decreases with increasing temperature. Finally, the carbon dioxide adsorption capacity when emission temperature of the combustion exhaust gas, PZ impregnated zeolite pellet was 1.8 times than zeolite pellet as well as 20 times than MEA impregnated zeolite pellet.

A Study on the Lipid Components in Oyster Mushroom (느타리버섯의 지방성분(脂肪成分)에 관한 연구(硏究))

  • Kwon, Yong-Ju;Uhm, Tai-Boong
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.13 no.2
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    • pp.175-180
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    • 1984
  • Lipids in oyster mushroom (Pleurotus florida) were extracted by the mixture of chloroform-methanol (2: 1, v/v) and fractionated into neutral lipids, glycolipids and phospholipids by silicic acid column chromatography. Components and fatty acid composition of each fraction were deter- mined by thin-layer and gas-liquid chromatographies. Fresh oyster mushroom contained 0.5% total lipid in which the contents if neutral lipids, glycolipids and phospholipids were 33.8%, 19.7% and 45. 6%, respectively, Triglycerides(38.2%), free fatty acids (20%) and free sterol (10%) were the major components among the neutral lipids. Diglycerides, monoglycerides, sterol esters and three unidentified neutral lipids were the minor components. Major components of glycolipids were steryl glycosides(35.9%) and esterified steryl glycosides (23.7%). Digalactosyl diglycerides, mono-galactosyl diglycerides and two unknown components were also present. Of the phospholipids, phosphatidyl cholines and serines (48.2%), and phosphatidyl ethanolamines(44.4%) were the major components. On the other hand, the major fatty acids of neutral lipids we.e linoleic, palmitoleic, oleic and palmitic acid. Linoleic and palmitic acid were the predominant fatty acids of both glycolipids and phospholipids.

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