• Korean Journal of Materials Research
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• v.20 no.1
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• pp.42-46
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• 2010

Phosphorus exhibits considerable segregation in steelmaking slag. In order to recover phosphorus from slag to $K_3PO_4$ via molten iron, a carbothermic reaction using microwave heating was suggested recently. The carbothermic reduction of phosphorus from slag to molten iron using microwave heating was carried out at 2073K. However, at this temperature the thermodynamic properties of both slag and molten iron cannot be determined experimentally. Therefore, the computational approach of the so-called CALPHAD method is very useful to understand the transfer of phosphorus from slag to metal and to enhance this reaction. In the present investigation, a theoretical study of the reduction behavior of phosphorus in slag was carried out at much lower temperatures using the recently developed thermodynamic database in the FactSage program. The calculated results showed reasonable accordance with the experimental data; namely, the thermodynamic database could be applied successfully to higher temperature reactions. The current study found that higher temperature and high $SiO_2$ concentration are favorable for the recovery of phosphorus from slag.

• Korean Journal of Metals and Materials
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• v.47 no.2
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• pp.107-113
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• 2009

Molten iron with 2 mass % carbon content was decarbonized at 1823 K~1923 K by bubbling $Ar+O_2$ gas through a submerged nozzle. The reaction rate was significantly influenced by the oxygen partial pressure and the gas flow rate. Little evolution of CO gas was observed in the initial 5 seconds of the oxidation; however, this was followed by a period of high evolution rate of CO gas. The partial pressure of CO gas decreased with further progress of the decarbonization. The overall reaction is decomposed to two elementary reactions: the decarbonization and the dissolution rate of oxygen. The assumptions were made that these reactions are at equilibrium and that the reaction rates are controlled by mass transfer rates within and around the gas bubble. The time variations of carbon and oxygen contents in the melt and the CO partial pressure in the off-gas under various bubbling conditions were well explained by the mathematical model. Based on the present model, it was explained that the decarbonization rate of molten iron was controlled by gas-phase mass transfer at the first stage of reaction, but the rate controlling step was transferred to liquid-phase mass transfer from one third of reaction time.

• Proceedings of the KWS Conference
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• 2009.11a
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• pp.95-95
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• 2009

Zinc coatings provide the most effective and economical way of protecting steel against corrosion. There are three types of galvanizing lines typically used in production line in galvanizing industries,Galvanize (GI) coating (Zn-0.1-0.3%Al), Galfan coating (Zn-5%Al), Galvalume(GL) coating (45%Zn-Al). In continuous Galvanizing lines, the immersed bath hardware (e.g. bearings, sink, stabilizer, and corrector rolls, and also support roll arms and snout tip) are subjected to corrosion and wear failure. Understanding the reaction of these materials with the molten Zn alloy is becomes scientific and commercial interest. To investigate the reaction with molten Zn alloys, static immersion test performed for 4, 8, 16, and 24 Hr. Two different baths used for the static immersion, which are molten Zn and molten Zn-55%Al. Microstructures characterization of each of the materials and intermetallic layer formed in the reaction zone was performed using optical microscope, SEM and EDS. The thickness of the reaction layer is examined using image analysis to determine the kinetics of the reaction. The phase dominated by two distinct phase which are eutectic carbide and matrix. The morphology of the intermetallic phase formed by molten Zn is discrete phase showing high dissolution of the material, and the intermetallic phase formed by Zn-55wt%Al is continuous. Aluminum reacts readily with the materials compare to Zinc, forming iron aluminide intermetallic layer ($Fe_2Al_5$) at the interface and leaving zinc behind.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 1998.04a
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• pp.292-299
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• 1998

Case hardening behavior of tool steel(SK5) was investigated after YAG laser irradiation. In the case of beam passes, martensite formed in the melt zone and in former pearlite regions of the austenization zone exhibited very high Vickers Hardness values. The molten depth and radius, micro structure, hardness were investigated as a function of defocusing distance, pulse width, and power density.

• Proceedings of the Korean Operations and Management Science Society Conference
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• 1996.04a
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• pp.566-569
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• 1996

Steel making using EAF (Electric Arc Furnace) consists of three major processes: molten steel making, slab casting and hot rolling. Orders from customers, which includes their requirements such as composition, order quantity with allowable range, width, thichness, and unit weight of coils etc, are grouped as charges for EAF to enhance the productivity of the furnace. This paper develops an efficient grouping algorithm for charges in the EAF by exploiting the order characteristics: the allowable ranges of furnace capacity, order quantity, and unit weight of coils. Numerical test shows that the proposed heuristic works very efficiently and the results are quite satisfactory.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 1998.03a
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• pp.53-58
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• 1998

Case hardening of tool steel(SK5) was investigated after YAG laser irradiation. In the case of beam passes, martensite formed in the melt zone and in former pearlite regions of the austenization zone exhibited very high Vickers Hardness values. The molten depth and radius, micro structure, hardness were investigated as a function of defocusing distance, pulse width, and power density.

• Journal of the Korean institute of surface engineering
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• v.33 no.5
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• pp.381-386
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• 2000

It was found that colloidal silica sprayed to the galvanized steel sheet apparently made the molten zinc layer solidified to be the randomly oriented fine grains. Its spraying effect was also little affected by steel temperature that had been considered as one of the major operating factors in this process. From the results of surface analysis, it is considered that aluminum dissolved in coating layer reduces silica to silicon by the oxidation-reduction reaction, and that the reduced silicon acts as a more effective nucleus in solidification reaction than phosphate salt, siica and alumina.

• International Journal of Fuzzy Logic and Intelligent Systems
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• v.2 no.2
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• pp.146-152
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• 2002

Mold level control has been a major control task for continuous casting plants. The system involves nonlinearities such as stick-slip friction in the sliding gate, time-delay, friction force variations between molten steel and the inner wall of mold, and nozzle logging/unclogging. These complex problems should be solved to control mold level for steel cast. In this paper, we propose a neural fuzzy mold level control technique for solving these complex problems and give experiment studies to show the mold level control in continuous casting process.

• Journal of Welding and Joining
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• v.12 no.4
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• pp.127-140
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• 1994

Resistance spot welding has been widely used in the sheet metal joining processes because of its high productivity and convenience. In the resistance spot welding processes the size of molten nugget is a criterion to assess weld quality. Many research have founded on measuring weld nugget size at the same time monitoring welding process parameters such as dynamic resistance and electrode movement. With increasing demand of energy saving, many efforts were made to employ aluminum alloys that are lighter than steel and have relatively equivalent strength to steel in the automobile industry. In this paper, spot weldability of aluminum alloys for various welding conditions were examined by series of experiments. One of the 6000 series (Mg-Si) aluminum alloy, 6383-T4 was chosen, which is currently considered as a substitute for the galvanized steel. Dynamic resistance, electrode movement and corresponding nugget size were observed and compared to the case of steel. Finally, resistance spot welding of dissimilar material (galvanized steel-aluminum alloy) was attempted.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.11
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• pp.3043-3047
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• 2009

Nitrogen solubility and nitride formation in liquid 304 Stainless steel has been measured by sampling method at various temperatures. Also values of thermodynamic functions are determined. Nitrogen solubility in molten 304 Stainless steel is increased with temperature and under the 1atm nitrogen atmosphere, titanium nitride is formed over 0.03wt%Ti in 304Stainless steel. Produced nitride is identified TiN by EDS analysis.