• 제목/요약/키워드: modified epoxy

검색결과 253건 처리시간 0.023초

경화제 무첨가 에폭시 시멘트 모르터 및 콘크리트의 역학적 성질 (Mechanical Properties of Epoxy-Modified Mortars and Concretes without Hardener)

  • 조영국;소양섭
    • 콘크리트학회지
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    • 제8권3호
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    • pp.157-165
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    • 1996
  • 경화제 무첨가 에폭시 수지는 시멘트 모르터 및 콘크리트 중에 시멘트 수화에 의해 생성된 수산화물(예를 들어 $Ca(OH)_2$)의 존재하에서 경화할 수 있음에 착안하여, 본 연구는 경화제를 첨가하지 않은 에폭시 시멘트 모르터 및 콘크리트의 배합비 변화에 따른 역학적 성질을 파악하고 종래의 경화제 첨가 에폭시 시멘트 모르터 및 콘크리트와 비교하여 성능과 경제적인 면에서 우수한 경화제 무첨가 에폭시 시멘트 모르터 및 콘크리트를 개발하기 위하여 연구되었다. 연구 결과 종래의 경화제 첨가 에폭시 시멘트 모르터 및 콘크리트와 비교하여 10-20%의 낮은 폴리머 시멘트 비에서 우수한 역학적 성질을 가진 경화제 무첨가 에폭시 시멘트 모르터 및 콘크리트를 개발할 수 있다.

개질된 열가소성 고분자를 이용한 에폭시 수지 개발과 탄소섬유 복합재료에의 응용 (Development of epoxy resin with modified thermoplastic polymer and application to the carbon fiber composites)

  • 이광기;김민영;김원호;안병현;황병선
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2002년도 추계학술발표대회 논문집
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    • pp.237-240
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    • 2002
  • Amino terminated polyetherimide(ATPEI) has been synthesized by bisphthalic anhydride arid m-phenylenediamine, after that characterized by differential scanning calorimetry(DSC), thermogravimetric analyzer(TGA). Fourier transform (FT-IR) spectroscopy and gel permeation chromatography(GPC). ATPEI was blend to improve the toughness of bisphenol-A type epoxy resin which was cured by nadic methyl anhydride(NMA). The fracture toughness and the molphology of the toughened epoxy resin was evaluated. The toughness of ATPEI modified epoxy resin was higher than that of the PEI modified epoxy resin. In addtion, carbon fiber/ATPEI modified epoxy resin composites were fabricated and the mechanical properties of the resulted composites were investigated.

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에폭시 절연의 전기적 트리잉에 관한 표면 개질된 나노알루미나의 영향 (The Influence of Surface Modified Nano Alumina for Electrical Treeing in Epoxy Insulation)

  • 박재준
    • 전기학회논문지
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    • 제65권7호
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    • pp.1218-1224
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    • 2016
  • This paper presents the results of a study on the effect of surface modified alumina nanocomposites on electrical tree growth in epoxy insulation. Treeing experiments were conducted at a fixde AC voltage (500kV/mm, 10kV/60Hz)on unfilled epoxy sample as well as epoxy nanocomposites of 4 types with different loading and surface modified GDE gram. Time for tree growth as well as tree propagation length were studied. The results show that there is a significant improvement tree propagation time compare unfilled epoxy to epoxy nano alumina composites. Different tree propagation shapes as well as slower tree growth with 4 types nano alumina composites were observed.

팽창재 및 팽윤재를 병용한 에폭시수지 혼입 시멘트 모르타르의 강도특성 (Strength Properties of Epoxy-Modified Mortars with Expansive and Swelling Agents)

  • 함성민;김주영;김완기
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2014년도 춘계 학술논문 발표대회
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    • pp.288-289
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    • 2014
  • The purpose of this research is to examine strength properties of epoxy-modified mortar with expansive and swelling agent contents. The polymer-modified mortars (PMMs) using epoxy resin are prepared with various polymer-binder ratios, expansive and swelling agent contents. The PMMs using epoxy resin are tested for compressive, flexural and tensile strengths. As a result, the strength properties of the PMMs using epoxy resin are depending on the polymer-binder ratio rather than expansive and swelling agent content, and are remarkably improved over unmodified mortar (UMM).

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에폭시/유기적으로 변경된 층상실리케이트가 충진 된 나노콤포지트의 유전특성 (Dielectric Properties of Epoxy/Organically Modified Layered Silicate Nanocomposites)

  • 박재준
    • 한국전기전자재료학회논문지
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    • 제21권2호
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    • pp.188-193
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    • 2008
  • Epoxy/Organically Modified Layered Silicate Nanocomposites were prepared by dispersing synthetic layered silicate modified with alkyl ammonium ions. In the dispersing process, the organically modified layered silicate were mixed in epoxy resin with shearing, and aggregation of the silicate were removed by centrifugal separation after mixing epoxy resin and silicates. Micrographs taken by transmission electron microscopy(TEM) indicate that the nanocomposites have a mixed morphology including both parallel silicate layers and exfoliated silicate layers area, As the thermal properties, the glass transition temperature of the nanocomposites was shifted to a higher temperature($+6^{\circ}C$)than pure epoxy. Furthermore, dispersion of OMLS will prevented relative permittivity from increasing at a high temperature above the glass transition temperature.

에폭시수지와 아질산형 하이드로칼루마이트를 병용한 폴리머 시멘트 모르타르의 강도 및 방청성 (Strengths and Corrosion-Inhibition of Epoxy-Modified Mortars Contaning Nitrite-Type Hydrocalumite)

  • 김주영;김완기
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2013년도 춘계 학술논문 발표대회
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    • pp.53-55
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    • 2013
  • Nitrite-Type hydrocalumite (calumite) is a material that can provied a self-corrosion inhibition function to the reinforce concrete. In this study, bisphnol A·F type epoxy-midified mortars without hardner contaning calumite is prepared with various polimer-binder ratios, calumite contents and tow types of curing condition, and tested for flexural and compressive strength tensile strength and corrosion-inhibition. As a result, in the case of wet/dry curing condition, strengths of bisphnol A·F type epoxy-modified mortars without hardener contaning calumite is inclined to decrease with increasing of polymer-binder ratio and calumite content. However, dry cured specimens are slightly improved by using bisphnol A·F type epoxy resin. Finally, regardless of polymer-binder ratios and calumite contents, corrosion-inhibition of bisphnol A·F type epoxy-modified mortars without hardener containing calumite is superior than that of unmodified mortar.

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지환식 에폭시/표면개질된 마이크로-나노실리카 콤포지트의 유전특성 (Dielectric Properties for Surface Modified Micro-Nano Silica Composites of Cycloaliphatic Epoxy)

  • 박재준
    • 전기학회논문지
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    • 제65권11호
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    • pp.1840-1847
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    • 2016
  • The surface of nanosilica and microsilica was modified in order to develop a high voltage insulation material for outdoor application. The modified silicas were well dispersed in an aliphatic cyclic epoxy resin. Dielectric properties were studied for 8 kinds of specimens: 1 kind of neat epoxy, 3 kinds of epoxy/microsilica composites, and 4 kinds of epoxy/microsilica/nanosilica composites. Complex dielectric constants were measured in the range of 10-2~1.2 Hz at room temperature.

에폭시가 함유된 PVC졸 실란트의 물성 (Properties of Epoxy Modified PVC-sol Sealants)

  • 이승진;김현교;박환만;조원제;하창식
    • Elastomers and Composites
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    • 제34권3호
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    • pp.199-211
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    • 1999
  • 본 연구에서는 PVC졸 실란트에 요구되는 접착성 개선제에 대한 연구의 일환으로 에폭시가 2개(epoxy A)인 것과 4개인 것(epoxy B)을 각각 첨가하였을 때 PVC졸 실란트의 제반물성에 미치는 영향을 연구하였다. PVC졸은 디옥틸프탈레이트(DOP)로 PVC를 가소화시켜 제조된 것이다. 에폭시 수지 A의 경우는 에폭시 수지 함량이 증가할수록 PVC졸 실란트의 점도가 감소하였고, 첨가제 $CaCO_3$가 첨가된 에폭시 PVC졸 실란트의 점도는 에폭시 수지 종류에 관계없이 $CaCO_3$ 함량이 증가할수록 점도가 증가했다. $45^{\circ}C$ 열 수조상에서 점도 변화는 에폭시 수지 종류 또는 함량에 관계없이 점도가 감소하였는데 이는 에폭시가 PVC졸 실란트에 안정제의 역할을 한 것으로 판단되었고, $CaCO_3$가 함유된 경우는 그 함량이 증가할수록 점도가 증가한 것은 충진효과로 판단되었다. 에폭시가 첨가된 PVC졸 실란트의 열적 안정성은 다소 개선되었다. 인장 강도는 에폭시 수지 A의 함량이 낮은 경우는 인장 강도 및 신율이 증가하고, 높은 함량에서는 오히려 감소했다. 에폭시 수지 B의 경우는 에폭시 함량이 증가할수록 인장 강도와 신율은 증가하는 현상이 보였다. 충진제 함량이 많을수록 충진제 함량이 적은 PVC졸보다도 인장 강도는 낮은 현상을 보였다. 전기적 특성에서는 tan ${\delta}$의 값이 0.1정도($0.1{\pm}0.04$)이고 비유전율 ${\epsilon}_r$ 값은 0.5정도($0.5{\pm}0.04$)이므로 좋은 절연체로 판단되었다.

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목재 부산물인 목타르를 활용한 에폭시수지 혼입 PMM의 강도 및 경화특성 (Strenghts and Hardening Properties of Epoxy-modififed Mortars Using Wood-Tar of Wood By-Product)

  • 김주영;함성민;김완기
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2014년도 추계 학술논문 발표대회
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    • pp.21-22
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    • 2014
  • The purpose of this study is to ascertain strengths and hardening rate of epoxy-modified mortar with wood-tar contents. The polymer-modified mortars (PMMs) using epoxy resin with wood-tar are prepared with various polymer-binder ratios of 1, 3, 5% and wood-tar contents of 0, 5, 10, 15 and 20%. The PMMs using epoxy resin are tested for compressive, flexural and tensile strengths and hardening rate of epoxy resin. As a result, the strengths and hardening rate under polymer-binder ratio 1% and wood-tar content of 5% are more excellent than those of other specimens.

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Effect of Organically Modified Layered Silicate on Thermal, Mechanical, and Electrical Properties of Epoxy-Based Nanocomposites

  • Park, Jae-Jun;Kwon, Soon-Seok;Lee, Jae-Young
    • Transactions on Electrical and Electronic Materials
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    • 제12권4호
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    • pp.135-139
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    • 2011
  • In an effort to develop new electrical insulation materials, four different kinds of organically modified layered silicate were incorporated into an epoxy matrix to prepare nanocomposites for electrical insulation. Five wt% of organically modified layered silicates were processed in a planetary centrifugal mixer in an epoxy matrix, and the thermal, mechanical, and electrical properties of the cured epoxy/layered silicate were investigated. The morphology of the nanoscale silicate dispersed in the epoxy matrix was observed using transmission electron microscopy, and the interlayer distance was measured by wide-angle X-ray scattering diffraction analysis.