• 제목/요약/키워드: model investigation

검색결과 4,170건 처리시간 0.05초

The Adsorption and Desorption of $NH_3$ on Rutile $TiO_2(110)-1{\times}1$ Surfaces

  • 김보성;;;;김유권
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.265-265
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    • 2012
  • The adsorption of molecular $NH_3$ on rutile $TiO_2(110)-1{\times}1$ surfaces was investigated using a temperature-programmed desorption (TPD) technique combined with a molecular beam apparatus. A quantitative investigation into the TPD spectra of $NH_3$ was made for $NH_3$ adsorbed on two kinds of rutile $TiO_2(110)-1{\times}1$ surfaces with the oxygen vacancy ($V_O$) concentration of ~0% (p-$TiO_2(110)$) and ~5% (r-$TiO_2(110)$), respectively. On both surfaces, non-dissociative adsorption of $NH_3$ was inferred from a quantitative analysis on the amount of adsorbed $NH_3$ and those desorbed. With increasing coverage, the monolayer desorption feature shifted from 400 K toward lower temperatures until it saturates at 160 K, suggesting a repulsive nature in the interaction between $NH_3$ molecules. At the very low coverage regime, the desorption features were found to extend up to 430 K and 400 K on p-$TiO_2(110)$ and p-TiO(110), respectively. As a result, the saturation coverage of monolayer of $NH_3$ was higher on the p-$TiO_2(110)$ surface than on the p-TiO(110) by about 10%. The desorption energy ($E_d$) of $NH_3$ obtained by inversion of the Polanyi-Wigner equation indicated that the difference between the $E_d$'s of $NH_3$ (that is, $E_d(on\;p-TiO_2(110)$) - $E_d$(on p-TiO(110)) was 14 kJ/mol at ${\theta}(NH_3)=0$ and decreased to 0 as the coverage approached to a monolayer. The observed adsorption behavior of $NH_3$ was interpreted using an interaction model between $NH_3$ and surface defects on $TiO_2$ such as VO's and $Ti^{3+}$ interstitials.

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장기 저장 중 저장 온도와 습도에 따른 해품 콩의 콩나물 가공적성 연구 (Investigation of the processing characteristics of soybean sprouts after germination of HaePum during a long storage period with different temperature and humidity)

  • 이윤주;윤원병
    • Journal of Applied Biological Chemistry
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    • 제63권1호
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    • pp.1-8
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    • 2020
  • 나물용 콩인 해품의 저장 온도(5, 15 ℃ 그리고 실온)및 저장기간(0, 6, 12개월), 저장 습도(20, 40, 60, 80%) 에 따라 변화하는 해품 콩나물의 가공적성을 분석하였다. 콩나물의 발아세는 콩을 실온에서 저장 시 저장 기간이 증가함에 따라 발아세가 감소하였으며 저장 12개월이 되었을 때 0%이었다. 30 ℃, 80% 저장조건에서 4개월 저장된 콩을 이용 시 콩나물의 발아세는 4.94%로 가장 낮았다. 콩나물의 수율은 콩의 저장 온도와 저장기간이 증가함에 따라 유의미하게 감소하였으며(p <0.05), 콩의 저장 온도와 저장 습도에 따른 콩나물의 수율은 발아세의 경향과 동일하였다. 콩나물 자엽의 황색도와 조직감, 배축의 명도와 조직감 모두 저장 기간이 증가함에 따라 감소하였다. 콩의 고온(30 ℃), 고습(80%)의 저장조건에 의한 영향으로 콩나물 자엽의 조직감은 44.39±9.38 g/㎟으로 감소하였다. 콩나물의 유리아미노산 함량은 콩의 저장조건에 따라 뚜렷한 경향을 나타내지 않았으며 발아세의 결과와 유사하였다. 이는 콩의 저장 조건과 저장 기간이 콩나물의 품질인자에 영향을 미치기 때문에 저장 조건이 중요한 변수가 되는 것을 의미한다. 1차 반응속도 식과 Arrhenius식에 의해 계산된 콩나물 수율의 활성화 에너지(Ea)는 29.56 kJ/mol이었으며, 이를 이용하여 저장온도에 따른 수율의 예측이 가능하였다.

알긴산나트륨 및 첨가제를 함유한 서방성 매트릭스 정제 (Sustained Release Matrix Tablet Containing Sodium Alginate and Excipients)

  • 신성이;이범진;이태섭;허보욱;유승구
    • Journal of Pharmaceutical Investigation
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    • 제26권3호
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    • pp.187-192
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    • 1996
  • The matrix tablet containing sodium alginate and $CaHPO_4$ can release drugs in a controlled fashion from hydrogel with gelling and swelling due to their interaction as water penetrates the matrices of the tablet. The purpose of this study was to evaluate release characteristics of the matrix tablet varying the amount of sodium alginate, $CaHPO_4$ and other excipients such as chitosan, hydroxypropyl methylcellulose (HPMC) and $Eudragit^{\circledR}$ RS100 in the simulated gastric and intestinal fluid. The practically soluble ibuprofen was used as a model drug. The release profiles of matrix tablet in the gastric fluid as a function of sodium alginate/$CaHPO_4$ ratio was not pronounced because of low solubility of drug and stability of alginate matrices. However, release rate of drug from the matrix tablet in the intestinal fluid was largely changed when sodium alginate/$CaHPO_4$ ratio was increased, suggesting that the ratio of sodium alginate/$CaHPO_4$ was an important factor to control the gelling and swelling of the matrix tablet. The incorporation of other excipients into the matrix tablet also influenced the release rate of drug. The chitosan and HPMC decreased the release rate of drug. No release of drug was occurred when $Eudragit^{\circledR}$ RS100 was added into the tablet. The retarded release of matrix tablet when excipients were added resulted from the hindrance of swelling and gelling of the matrix tablet containing sodium alginate and $CaHPO_4$. The hardness and bulk density of the matrix tablet was not correlated with release rate of drug in the study. From these findings, the ratio of sodium alginate and $CaHPO_4$ in the matrix tablet in addition to incorporation of excipients could be very important to control the release rate of drug in dosage form design.

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인공리프 개구폭 변화에 따른 흐름특성 고찰 (Hydraulic Characteristics Investigation due to the Change of GapWidth between Artificial Reefs)

  • 김규한;심규태
    • 한국해안·해양공학회논문집
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    • 제28권6호
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    • pp.408-415
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    • 2016
  • 비교적 수심이 낮은 해안에 설치되는 소형어항 및 해안구조물 등은 연안흐름을 방해하여 표사이동의 평형상태를 붕괴시킬 수 있으며 구조물에 의한 회절파의 영향으로 파랑이 집중되어 국소적인 해안침식을 유발시킬 가능성이 크다. 이와 같은 해안침식을 제어하기 위한 대책으로는 다양한 저감공법이 제안되어 이용되고 있으나 이안제, 돌제 및 헤드랜드 등의 공법은 침식제어에 대한 직접적인 효과는 우수할 수도 있으나 해수면위로 구조물이 드러나기 때문에 경관이 우수한 해수욕장에서는 경관을 해치게 되어 적용하기 어려운 측면이 있다. 해안관광을 우선시하는 지역에서는 바다조망권을 훼손시키지 않고 2차적인 환경영향을 최소화 시키고자 하는 목적으로 광폭의 잠제인 인공리프를 채택하는 사례가 증가하고 있다. 한편 인공리프를 설치하고자 할 경우에는 인공리프의 길이와 인공리프 사이의 개구폭 및 해안선으로부터의 이안거리를 어떻게 결정하는지가 중요하다. 그러나 이러한 인공리프의 중요설계요소들에 대한 명확한 설계기준은 확립되어 있지 않다. 본 연구에서는 다양한 종류의 수리모형실험을 수행하고 인공리프 주변에서 발생되는 파랑 및 흐름장의 변화를 PIV기법 등을 이용한 정밀측정 및 해석을 수행하여 인공리프 길이와 이안거리 및 개구폭에 대한 기준을 제시하고자 하였다.

치과위생사 직무와 개인의 창의성에 의한 자기평가 연구 (A study on the self-evaluation of job performance and creativity of dental hygienists)

  • 홍선화;구경미
    • 한국치위생학회지
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    • 제10권6호
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    • pp.1037-1048
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    • 2010
  • Objectives : The awareness of health care need increasing attention from the public along with changing professional human-resources activity. As there are increasing social demand for the roles and professionalism of dental hygienists, the purpose of this study was to examine the job performance, creativity and organizational climate of dental hygienists by their own self-diagnostic evaluation in an attempt to help enhance their work ability. Methods : According to the data released as August 2008 by the Dental Association and public health centers in Gwangju, 735 dental hygienists worked at 425 dental clinics. The subjects in this study were 156 dental hygienists at 85 dental clinics who were selected by proportionate sampling method from among the dental hygienists. After an interview survey was conducted in person, the answer sheets from 132 respondents were analyzed except 24 incomplete ones. The questionnaire used in this study consisted of 49 items. A five-point Likert scale was used and SPSS 12.0 program was analyzed the data. Results : 1. As a result of checking the types of works, treatment cooperation(54%), and oral health education often(45%), They weren't responsible for preventive treatment(42%). 2. When they made a self-diagnostic evaluation of creativity and organizational climate, they put the highest value on their autonomy(2.21), followed by positive attitude(2.10). Out of seven organizational climate, challenging spirits(2.81) ranked highest, followed by reliability(2.66). 3. Major management eopmubyeol individual creativity compared with three business relationships and a positive attitude in the case of the high group received oral health education and care management services in a group doing the most was General office work and office assistance work in the medical assistance group that was doing business primarily. 4. In the relationship between self-assesment score and three performance duties, Positive difference was noted in the group with positive attitude and elevated autonomy in terms of performing oral health education. Conclusions : As a result, individual creativity and organization of the atmosphere, each detail, through analysis of the self-assessment model, developed guide on the investigation by doing a dental hygienist, a unique business promotion and Enlargement of the study suggested the need to be considered is.

절수에 의한 Mongolian gerbil 신장조직의 변화에 관한 형태학적 연구 (Morphological Study on the Changes in the Kidney of the Water-deprived Mongolian gerbil (Meriones unguiculatus))

  • 김무강;이근좌;정영길;송치원;이경열;박일권;이철호;이기훈;현병화;김길수
    • Applied Microscopy
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    • 제27권4호
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    • pp.433-452
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    • 1997
  • Mongolian gerbil (Meriones unguiculatus) has been as an animal model for studing the neurological diseases such as stroke and epilepsy because of the congenital incompleteries in Willis circle, as well as the investigation of water metabolism because of the long time-survival in the condition of water-deprived desert condition, compared with other species animals. In order to accomplish the this research, first of all another divided the laboratory animals 5 groups of which each group include the 5 animals. In this study were investigated the histological structure in the kidney, measured the plasma osmolalities at the time of sacrifice of indivisual animals, and the body weights every day during water-deprived. The results obtained in this study were summarized as followings: 1. The body weights and decreasing rates of the body weight in water-deprived mongolian gerbil groups were continuosly decreased. 2. The plasma osmolalities were increased from the 5th water-deprived day, after then the gradually increasing reached nearly its equilibrium state at the 10th water-deprived day. 3. The urine volumes were abruptly decreased from the 2th water-deprived day, after then the gradually decreasing patterns were reached nearly its equilibrium state at the 10th day, and stopped the 11th day. 4. In the light microscopical observation of the kidney, glomerular capillary loop thickening, mesangial matrix increasing, sclerosis, glomerular cystic atrophy, interstitial fibrosis, tubular dilatation, mononuclear interstitial inflammation, interstitial mineralization, and hyperplasia of the collecting duct epithelium in the cortex area, were observed from the 10th water deprived day, and the lesions were gradually severe changed as the time lapse. 5. In the electron microscopical findings of the kidney, the degenerative changes of endothelial cell, podocyte and mesangial cell in glomeruli were initially observed on the 10th water-deprived day as well as the degeneration of microvilli and intracellular organelle in the renal tubules.

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터널 덕트슬래브의 종방향 균열에 대한 원인 분석 사례 연구 (A Case Study on Cause Analysis for Longitudinal Crack of Duct Slab in Tunnel)

  • 박성우;박승수;황인백;차철준
    • 한국구조물진단유지관리공학회 논문집
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    • 제16권5호
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    • pp.19-28
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    • 2012
  • 본 연구에서는 반횡류식 터널 덕트슬래브 하면 중앙부에 발생한 종방향 균열의 발생 원인을 분석하였다. 분석을 수행하기 위하여 균열이 발생 부위에 대한 상세한 외관조사, 비파괴조사 및 덕트슬래브의 처짐 측량을 실시하였고, 그 결과와 수치해석결과와의 상관관계 분석을 수행하여 균열 발생 원인에 대한 상세한 분석을 실시하였다. 균열 발생 원인의 주요 인자로 단부구속조건, 철근의 위치, 온도의 변화 및 건조수축 등으로 분류하였고, 콘크리트 라이닝을 우선적으로 타설하고 덕트슬래브를 철근 커플러로 강결하여 수개월 후에 별도 타설한 시공여건에 따라 발생할 가능성이 있는 요소들을 고려하여 수치해석을 실시하였다. 특히, 건조수축에 대한 분석을 위하여 ACI209 및 콘크리트 구조설계기준의 예측식과 기존 연구의 실험결과를 비교하여 시공당시의 건조수축 발생량을 예측하였고 구조해석을 수행하여 건조수축이 균열발생의 주요한 원인 중에 하나라는 결과를 도출하였다. 이에 따라 기존에 수행한 도로터널의 안전진단 결과를 덕트슬래브의 시공 방법에 따라 분류하고 균열발생 패턴을 분석하여 덕트슬래브가 있는 터널의 시공방법의 개선에 대한 제언을 하였다.

서울지역의 미세먼지가 호흡기계 질환으로 인한 병원입원에 미치는 영향 (The Effect of PM10 on Respiratory-related Admission in Seoul)

  • 서주희;하은희;이보은;박혜숙;김호;홍윤철;이옥희
    • 한국대기환경학회지
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    • 제22권5호
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    • pp.564-573
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    • 2006
  • This study was performed to examine the effect of particulate matter less than 10 ${\mu}m$ in diameter($PM_{10}$) on respiratory-related admission in Seoul, 1999. Daily counts of respiratory-related admission were analyzed by generalized additive model with adjustment for effects of air temperature, humidity, and day of the week as confounders in a nonparametric approach. The results follow associations between $PM_{10}$ and asthma, acute upper respiratory disease, acute lower respiratory disease, pneumonia, and chronic respiratory disease. The relative risks were 1.30(95% CI=1.14$\sim$1.50) for pneumonia, 1.18(95% CI=1.01$\sim$1.37) for acute lower respiratory disease in less than 15 years, respectively. The relative risks were 1.85(95% CI=1.22$\sim$2.81) for acute lower respiratory disease, 1.28(95% CI=1.04$\sim$1.57) for asthma, 1.25(95% CI=1.01$\sim$1.54) for pneumonia and 1.19(95% CI=1.01$\sim$1.41) for acute upper respiratory disease in 15 to 64 years, respectively The relative risks were 1.54(95% CI=1.15$\sim$2.08) for asthma, 1.38(95% CI=1.06$\sim$l.80) for chronic respiratory disease in more than 65 years, respectively. The study showed that $PM_{10}$ was considerably affects daily counts of respiratory-related admission in Seoul, 1999 Statistically significant associations were mostly found in the adult group like If to 64 years. The highly relative risks come out in the elderly.

방사능(선)에 관한 차세대 인식도 및 교육방향에 대한 고찰 (And recognition of the next generation about the radioactivity A Study on the direction of education)

  • 서동우;김경연;김종은;배현학;손재호;전민규;정재은
    • 대한디지털의료영상학회논문지
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    • 제16권1호
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    • pp.43-47
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    • 2014
  • Sens of insecutity of the public and professionals about harmful effects of radiation is increasing in an accident at the Chernobyl and Fkushima nuclear power plant.Anxiety was amplified to lack of information about radiation majority of people. To target the middle and high school in the region of Daegu and Gyeongsangbuk-do, to investigate the radiation recognition of the next generation, it is intended to present a model of education for the safe use of radiation. The High School of the six metropolitan cities, city, town through the questionnaire and needs to be educational experience of radiation and use knowledge level of radiation, experience in daily life, understanding of man-made radiation and natural radiation, information channel on radiation, the radiation Distribute the total 800 parts of, to recover the 629 unit, was analyzed for 155 females 474 males. Many people 75.36% of the people, to 24.64% female subjects of this investigation, was constant, respectively from 13 to 18 years age. It is a large number and 30.37% of the respondents as "normal" level of knowledge of radiation, for the type of radiation, most knew. You have answer for risk experience of the medical radiation was higher, touching a lot of information via the broadcast medium in general, and the accuracy is low. I thought we wanted to be educated three or more twice a year, as an educator,about 71.37% and radiation-related understanding of knowledge and background in accordance with the diversification of information channels, the regional differences between urban and rural areas. But I considered the difference age (grade) for each is displayed, intended for junior high school students, the target surface and use the occurrence of radiation, high school students, the need for education about risk and application of radiation through this study.

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현실적 수학교육에 대한 고찰 - 초등학교의 알고리듬 학습을 중심으로 - (A Study of Realistic Mathematics Education - Focusing on the learning of algorithms in primary school -)

  • 정영옥
    • 대한수학교육학회지:수학교육학연구
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    • 제9권1호
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    • pp.81-109
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    • 1999
  • This study aims to reflect the basic principles and teaching-teaming principles of Realistic Mathematics Education in order to suppose an way in which mathematics as an activity is carried out in primary school. The development of what is known as RME started almost thirty years ago. It is founded by Freudenthal and his colleagues at the former IOWO. Freudenthal stressed the idea of matheamatics as a human activity. According to him, the key principles of RME are as follows: guided reinvention and progressive mathematisation, level theory, and didactical phenomenology. This means that children have guided opportunities to reinvent mathematics by doing it and so the focal point should not be on mathematics as a closed system but on the process of mathematisation. There are different levels in learning process. One should let children make the transition from one level to the next level in the progress of mathematisation in realistic contexts. Here, contexts means that domain of reality, which in some particular learning process is disclosed to the learner in order to be mathematised. And the word of 'realistic' is related not just with the real world, but is related to the emphasis that RME puts on offering the students problem situations which they can imagine. Under the background of these principles, RME supposes the following five instruction principles: phenomenological exploration, bridging by vertical instruments, pupils' own constructions and productions, interactivity, and interwining of learning strands. In order to reflect how to realize these principles in practice, the teaming process of algorithms is illustrated. In this process, children follow a learning route that takes its inspiration from the history of mathematics or from their own informal knowledge and strategies. Considering long division, the first levee is associated with real-life activities such as sharing sweets among children. Here, children use their own strategies to solve context problems. The second level is entered when the same sweet problems is presented and a model of the situation is created. Then it is focused on finding shortcomings. Finally, the schema of division becomes a subject of investigation. Comparing realistic mathematics education with constructivistic mathematics education, there interaction, reflective thinking, conflict situation are many similarities but there are alsodifferences. They share the characteristics such as mathematics as a human activity, active learner, etc. But in RME, it is focused on the delicate balance between the spontaneity of children and the authority of teachers, and the development of long-term loaming process which is structured but flexible. In this respect two forms of mathematics education are different. Here, we learn how to develop mathematics curriculum that respects the theory of children on reality and at the same time the theory of mathematics experts. In order to connect the informal mathematics of children and formal mathematics, we need more teachers as researchers and more researchers as observers who try to find the mathematical informal notions of children and anticipate routes of children's learning through thought-experiment continuously.

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