• Title/Summary/Keyword: mixture phenomena

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The Study on Phase Transition Pressure of Donor doped Pb(Zr0.52Ti0.48)O3 Ceramics with Diamond Anvil Cell (다이아몬드 엔빌 셀을 이용한 Donor doped Pb(Zr0.52Ti0.48)O3 세라믹스의 상전이 압력 연구)

  • Cho, Kyung-Ho;Ko, Young-Ho;Seo, Chang-Eui;Kim, Kwang-Joo
    • Journal of the Korean Ceramic Society
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    • v.48 no.5
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    • pp.471-478
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    • 2011
  • Investigations of crystal structure and phase transition of $Pb(Zr_{0.52}Ti_{0.48})O_3$ ceramics doped with A-site substitution impurity (La, Nd) or B-site substitution impurity (Sb, Nb) at 2 mol% concentration were carried out. X-ray diffraction patterns of impurities doped $Pb(Zr_{0.52}Ti_{0.48})O_3$ ceramics have been measured at pressures up to ~5 GPa with diamond anvil cell and synchrotron radiation. The patterns were obtained at room temperature using methanol-ethanol mixture as pressure-transmitting media. In order to refine the crystal structure, Rietveld analysis has been performed. The structures of impurities doped $Pb(Zr_{0.52}Ti_{0.48})O_3$ ceramics are tetragonal in space group P4mm at ambient pressure and are transformed into a cubic phase in space group Pm$\bar{3}$m as the pressure increases. In this study, when A-site substitution donor $La^{3+}$ or $Nd^{3+}$ ion was added to $Pb(Zr_{0.52}Ti_{0.48})O_3$ ceramics, the phase transition phenomena showed up at the pressure of 2.5~4.6 GPa, but when B-site substitution donor $Nb^{5+}$ or $Sb^{5+}$ ion was added to it, the phase transition appeared at relatively lower pressure of 1.7~2.6 GPa.

V-t Characteristics and 50% Flash-over Voltage of $SF_{6}-N_{2}$ Mixtures for Lightening Impulse Voltage ($SF_{6}-N_{2}$ 혼합가스에서 뇌충격전압에 의한 50[50%] Flash over 전압 및 V-t 특성)

  • 김정달;송원표;김동의
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.7 no.1
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    • pp.21-29
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    • 1993
  • In this paper, we studied the 50% flashover voltage of lightening impulse which affect the most serious damages on the insulation of the electric power network system. Also its V -t characteristics and corona process phenomena of pure $SF_6, N_2, SF_6-N_2$mixtures under the circumstances of nonuniform field gap are researched. Comparing the characteristics of pure $SF_6$ with that of $SF_6, N_2$mixtures, we discussed that breakdown processes and $SF_6, N_2$ mixture's application to economics.As a results, 50% flashover voltage of $SF_6$ 50% - $N_2$ 50% for impulse voltage is higher then that of 80% of pure SF6, measured data and calculated data by equal area law are almost equal from the points of view of V-t characteristics. Therefore, it has been known that $SF_6$ 50% - $N_2$ 50% mixtures can be used as an economic constitution gas of pure $SF_6$, it is verified that corona processes from Lichtenberg figure.

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Properties of Ultra High Performance Fiber Reinforced Cementitious Composites Mixed with Limestone Powder (석회석 미분말을 혼입한 초고성능 섬유보강 시멘트복합재의 특성)

  • Han, Sang-Mook;Wu, Xiang-Guo
    • Journal of the Korean Society of Hazard Mitigation
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    • v.8 no.2
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    • pp.23-30
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    • 2008
  • UHPC has high performance, high strength and excellent mechanical properties. Moreover UHPC(Ultra High Performance Cementitious Composite) has advantage to reduce cross section under the same load compared with other kinds of concrete. But silica fume which is imported from foreign country has a abundant portion in UHPC mixture in comparison with normal concrete. This is one of the main reason to raise the construction cost. Superior mechanical properties of UHPC due to the optimum filling composition can be changed by replacing the very fine ingredient. The purpose of this research is to grasp the characteristic of UHPC which silica fume and silica flour is replaced with limestone powder. This experiment can be divided into three classes according to the kinds of replacement. The compressive strength and flow of all types were measured and microstructure and hydration phenomena for comparing RPC were analyzed by SEM, XRD, NMR method. As a result, the replacement can be considered to be effective by for the decrease of the UHPC structure construction cost and improvement of the fresh UHPC.

Analysis of the clinker formed in circulating fluidized bed boiler (유동층 보일러에 생성된 크링커에 대한 분석)

  • Kim, Kyeong-Sook;Park, Hyun-Joo;Lee, Tae-Won;Jeong, Nyeon-Ho
    • Analytical Science and Technology
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    • v.13 no.1
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    • pp.5-11
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    • 2000
  • During the commissioning period in Tonghae thermal power plant which is the largest circulating fluidized bed boiler in the nation, a considerable amount of clinker was formed at FBAC and seal pot. Various attempts, for example, concentration analysis, surface phenomena, thermal characterization, and crystal structure of ash, bed sand, limestone, clinker, and mixture of each gradients have been studied to identify the causes of clinker formed in circulating fluidized bed boiler. As the results, the characterization of black particles in which separated from the clinker is more similar to that of bed sand, on the other hand, white particles are more similar to ash. In addition, the sintering temperature of sand is over $1,200^{\circ}C$ and this temperature was decreased as limestone is added to bed material. The cause of clinker was proved that ash was sticked to molten or sintered sand or limestone in the area of high temperature in the circulating system.

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Synthesis of Zeolite from the Mixtures of Aluminosilicate Gel and Activated Carbon (알루미노 실리케이트 겔과 활성탄 혼합물상에서의 제올라이트 합성)

  • Park, Jeong-Hwan;Suh, Jeong-Kwon;Jeong, Soon-Yong;Lee, Jung-Min;Doh, Myung-Ki
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.615-618
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    • 1998
  • The zeolite crystals were synthesized by hydrogel process into the pore of activated carbon. The effect of activated carbon in the course of the crystallization of zeolite was investigated. The phenomena of impregnation of zeolite crystals into the pore of the activated carbon were also examined. The results show that in case of the addition of 5% of activated carbon to the aluminosilicate gel including the mole composition of zeolite A, zeolite A was purely synthesized without the existence of other type of zeolite. However, in case of the addition of 20% of activated carbon, zeolite X was purely synthesized. In the pore mouth and internal of activated carbon, zeolite crystals having the size under $1{\mu}m$ was observed. From the results of the pore size and particle size distributions, it was confirmed that the synthetic sample was the composite material impregnated by the zeolite crystals into the pore of activated carbon, not the simple mixture of zeolite and activated carbon.

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Effect of Gas Sparging on Sonochemical Oxidation in a 300 kHz Sonoreactor (300 kHz 조건에서의 초음파화학적 산화반응에 대한 연속식 가스 주입 효과)

  • Seo, Jieun;Son, Younggyu
    • Journal of Korean Society on Water Environment
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    • v.34 no.6
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    • pp.642-649
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    • 2018
  • The effect of gas sparging on sonochemical oxidation was investigated in a 300 kHz sonoreactor under various liquid height/volume conditions ($5{\sim}30{\lambda}$, 3.4 ~ 9.0 L), determined by the wavelength of the applied frequency. The electrical input power was maintained constant for all cases . Sonochemical activity drastically decreased from $15{\lambda}$ and the liquid height of $10{\lambda}$ was suggested as the optimal height for 300 kHz without gas sparging. In our previous research, the sonochemical activity observed was five-times higher when air sparging was applied for 36 kHz. On the other hand, no enhancement was obtained at 10, 15, 25 and $30{\lambda}$ using air sparging (1, 3, and 6 L/min) for 300 kHz in this study $20{\lambda}$ and optimization of gas sparging was conducted at $20{\lambda}$ using various gases including air, Ar, $O_2$, $N_2$, and mixtures of Ar and $O_2$. It was found that gas sparging using pure Ar or pure $O_2$ resulted in lower sonochemical activity compared to that of air sparging due to the imbalance between the intensity of cavitation phenomena and the generation of oxidizing radical species. Consequently, the gas mixture of $Ar:O_2$ = 80 % : 20 % (DO saturation ${\approx}100%$) was suggested as an optimal gas sparging condition.

A New Approach for Detection of Gear Defects using a Discrete Wavelet Transform and Fast Empirical Mode Decomposition

  • TAYACHI, Hana;GABZILI, Hanen;LACHIRI, Zied
    • International Journal of Computer Science & Network Security
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    • v.22 no.2
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    • pp.123-130
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    • 2022
  • During the past decades, detection of gear defects remains as a major problem, especially when the gears are subject to non-stationary phenomena. The idea of this paper is to mixture a multilevel wavelet transform with a fast EMD decomposition in order to early detect gear defects. The sensitivity of a kurtosis is used as an indicator of gears defect burn. When the gear is damaged, the appearance of a crack on the gear tooth disrupts the signal. This is due to the presence of periodic pulses. Nevertheless, the existence of background noise induced by the random excitation can have an impact on the values of these temporal indicators. The denoising of these signals by multilevel wavelet transform improves the sensitivity of these indicators and increases the reliability of the investigation. Finally, a defect diagnosis result can be obtained after the fast transformation of the EMD. The proposed approach consists in applying a multi-resolution wavelet analysis with variable decomposition levels related to the severity of gear faults, then a fast EMD is used to early detect faults. The proposed mixed methods are evaluated on vibratory signals from the test bench, CETIM. The obtained results have shown the occurrence of a teeth defect on gear on the 5th and 8th day. This result agrees with the report of the appraisal made on this gear system.

Experimental Study on the Development of Electromagnetic Pulse Shielding Inorganic Paint Using Carbon Materials (탄소 재료를 사용한 전자파 차폐 무기계 도료 개발에 관한 실험적 연구)

  • Kyong-Pil Jang;Tae-Hyeob Song
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.3
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    • pp.234-243
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    • 2023
  • The electromagnetic pulse(EMP) is a general term for high-output electromagnetic waves, and is classified into EMP generated from nuclear weapons, non-nuclear EMP, and EMP generated by natural phenomena. Electromagnetic pulses are means that can cause fatal damage to all electronic devices with electromagnetic elements, such as communication devices, mobile phones, computers, TVs, and means of transportation. In this study, the electromagnetic pulse(EMP) shielding effectiveness evaluation of paints according to the type and amount of carbon material was conducted to develop EMP shielding inorganic paint using carbon materials. In order to analyze the improvement of compatibility and dispersibility between materials, experiments were conducted two times with about 27 types of mixture proportions, and the electromagnetic pulse shielding effectiveness was evaluated by the electrical resistance measurement method. As a result of applying the EMP shielding paint developed through this study to shielding concrete, it was confirmed that the shielding performance was improved from about 25 dB to a maximum of 40 dB.

Interfacial Phenomena of Dodecyl Ether Sulfates Containing Various Ethylene Oxide(EO) and Isopropylene Oxide(PO) (EO, PO가 부가된 도데실 에테르 황산화물의 계면성)

  • Yoo, Young-Chang;Kim, Sang-Chun;Kim, Tae-Young;Ju, Myung-Jong;Nam, Ki-Dae
    • Applied Chemistry for Engineering
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    • v.7 no.2
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    • pp.299-307
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    • 1996
  • The surface tension of PO added sodium poly(oxyethylene(EO), oxyisopropylene(PO)) dodecyl ether sulfate firstly were slightly lower than EO added sulfate in the concentration range of $10^{-6}{\sim}10^{-3}mol/{\ell}$. And they had lower critical micelle concentration ($10^{-4}{\sim}9{\times}10^{-5}mol/{\ell}$) than general anionic surfactants. The adsorptivity ($2.2{\times}10^{-10}mol/cm^2$) of sodium $(PO)_{10}(EO)_5$ dodecyl ether(compound of PO addition firstly) calculated by Gibbs' adsorption isotherm were higher than that of sodium $(EO)_{10}(PO)_5$, dodecyl ether(compound of EO addition firstly), but were lower than that of sodium dodecyl sulfate (${\Gamma}=3.2{\times}10^{-10}mol/cm^2$). These could be understood that the adsorption areas of compounds were very large because of their high molecular weight. Moreover, PO compounds showed better properties than EO compounds in foamability, emulsifying power for organics (n-hexane, benzene), detergency for the lard, tallow oil mixture and dispersability for iron oxide. It was interpreted in terms of surface properties of the PO compounds. These showed that the interfacial activity become higher when hydrophilic and hydrophobic portion existed in aggoromerated state respectively. The test results of emulsifying power for organics (n-hexane, benzene) showed better for benzene than n-hexane. Eight kinds of sodium (EO, PO) dodecyl ether derivatives showed irregular dispersibilities for polar iron oxide in water dispersed media.

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A Study on Gathering Behaviour of Fish in the Artificial Sea-floor Area (인공해저에 대한 어류의 위집기구에 관한 연구)

  • 홍성완
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.36 no.2
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    • pp.96-104
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    • 2000
  • By using the offshore type submersible platform, Artificial sea floor anchored at a depth of forty meters several experimental studies have been conducted successfully during 1996. The facility consists of an artificial sea floor that floats at 7 meters below the surface, a machinery hut that projects above the surface at the center of the structure and a balance weight beneath the structure. The facility can be surfaced easily by using a water discharging pump in the water tank which is located at the center of it. To find out the behavioral character and the gathering factor of fishes around the artificial sea floor, investigations were carried out during the daytime and nighttime by direct observation and by echo-sounder. Around the testing reefs and artificial sea floor, six kinds of fishes were found by diving observation and the dominants were Scomber japonicus, Sebastes thompsoni and Oplegnathus fascitus. As Scomber japonicus was distributed around the artificial sea floor in dense small school, they were not seen elsewhere in the survey area. The artificial sea floor was concluded to act as a schooling ground far Scomber japonicus, Sebastes thompsoni and Oplegnathus fascitus. were close to the testing reefs(within 10m) in the daytime, and were thought to settle on the testing reefs at nighttime, To examine the distribution of 7shes around the artificial sea floor, an acoustic survey over a 1$\times$1km area, 0-50m in depth during the all day. Around the artificial sea floor many thin scattering fish echo(TS-54.5~ -51.5dB) and dense fish echo(TS-41~-38dB) were mainly distributed. Many scattering fish echoes, which were thought to be a mixture of small squid, pelegic crustacea and ethers, were distributed over the whole survey area. A dense fish school stayed beneath the artificial sea floor for a short duration. These phenomena were concluded to show an attraction and detention function of the artificial sea floor.

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