• Title/Summary/Keyword: mixture gas

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Synthesis of transparent diamond-like carbon film on the glass by radio-frequency plasma enhanced chemical vapor deposition (RF-PECVD법에 의한 투명 다이아몬드상 탄소 박막 합성)

  • Kim, Tae-Gyu;Shin, Yeong-Ho;Cho, Hyun;Kim, Jin-Kon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.4
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    • pp.190-193
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    • 2012
  • Transparent diamond-like carbon (DLC) films were synthesized on glass using radio frequency plasma enhanced chemical vapor deposition method from the gas mixture of $CH_4$, $SiH_4$ and Ar. The pressure, the rf-power, $CH_4/SiH_4/Ar$ ratio, and the deposition time were 0.1Torr, 100W, 20 : 1 : 1, and 20 min, respectively. The optical transmittances of DLC-deposited glass and uncoated glass were compared with each other in the visible light regions. The DLC-deposited glass showed transmittance of approximately 83 % and 95 % as compared to the uncoated glass for the wavelength of 380 nm and 500 nm, respectively. The hardness and roughness of DLC-coated glass have been measured by nanoindentation and AFM, respectively. The DLC-coated glass showed a little less or similar optical transmittance compared to the uncoated glass, while the hardness of DLC-coated glass was 2.5 times higher than that of the uncoated glass. The deposited DLC film had the very smooth surface and was thicker than 150 nm after deposition for 20 min.

A Study on Asphalt Paving Filler Development from Industrial By-products and its Characteristics in Construction Site (산업부산물을 활용한 아스팔트 포장용 채움재 개발 및 현장시공 성능평가 연구)

  • Cho, Do-Young;Park, Keun-Bae;Woo, Yang-Yi;Moon, Bo-Kyung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.227-234
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    • 2016
  • In this study, asphalt paving filler, which satisfies the KS standards, were prepared from industrial by-products, such as fly ash generated from thermal power plants, cogeneration ash generated from cogeneration plants, and desulfurized gypsum generated from the flue-gas desulfurization process. The properties of the prepared mixed filler and the existing limestone filler were compared through laboratory tests for preparing asphalt mixture using each filler. In addition, asphalt pavement field tests were conducted using the limestone filler and mixed filler. The dynamic stability, Marshall stability, tensile strength ratio, saturation, porosity, and flow value of the asphalt mixtures used in the field test were evaluated, as was done in the laboratory test. The laboratory and field construction test results revealed outstanding tensile strength ratio, Marshall stability and dynamic stability when using the prepared filler than for the existing limestone filler. Through optimization of the mixing design, the possibility of developing fillers, which the characteristics of the existing limestone filler, was confirmed.

The Predicted Normal Value of Volume of Isoflow on Smokers and Nonsmokers (흡연자와 비흡연자에서 등기류용량(Volume of Isoflow)의 추정정상치에 관한 연구)

  • Park, Jung-Gook;Jung, Tae-Hoon
    • Tuberculosis and Respiratory Diseases
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    • v.39 no.2
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    • pp.141-149
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    • 1992
  • In order to establish predicted normal values of volume of isoflow($V_{iso}\dot{V}$), $V_{iso}\dot{V}$ were measured in a total 234 healthy adults, consisting of 78 male nonsmokers, 108 male smokers and 48 female nonsmokers. The volumes of isoflow were determined through analysis of maximal expiratory flow volume curves recorded with a mixture of 80% helium and 20% oxygen(He-$O_2$ gas) following one(1VC) and three vital capacity(3VC) maneuver and with room air. Based upon the correlation of the observed values of the parameters to age and physical characteristics, the following regression formulars for the prediction of the parameters, using age in year(A) as a variable, were obtained. 1VC method ($V_{iso}\dot{V}_1$) Male smoker : 0.614A+2.347 Male nonsmoker : 0.370A-2.792 Female nonsmoker : 0.588A-2.459 3VC method ($V_{iso}\dot{V}_3$) Male smoker : 0.467A+1.696 Male nonsmoker : 0.288A-1.538 Female nonsmoker : 0.367A-0.114.

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Preparation of Porous Anti-Insect Repellent Powder Using Spray Drying of Medicinal Herbal Extracts Anti-Insect Repellent Silica Sol (분무건조법을 이용한 한약추출물 해충기피 실리카 졸의 다공성 방충입자의 제조)

  • Park, Hee Young;Hwang, KiSeob;Kim, Jung-Hyeon;Lee, Jun-Young
    • Applied Chemistry for Engineering
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    • v.26 no.5
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    • pp.549-556
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    • 2015
  • Anti-insect repellent silica sol from mixture with silica and anti-insect repellent solution extracted from medicinal herbs was prepared. The micron size porous sphere powder with anti-insect repellent solution was prepared by the spray drying method. The characteristic of anti-insect repellent powder using spray drying method was analyzed by FE-SEM, PSA, TGA with the concentration of anti-insect repellent sol (anti-insect repellent solution and silica) and conditions of spray drier. The average particle size of 4, 7 wt% and 10 wt% of anti-insect repellent sol concentration were 8.3, $9.5{\mu}m$ and $11.7{\mu}m$, respectively. The particle size is increasing with high concentration of anti-insect repellent sol. Other hands, particle size as the temperature of inlet nozzle and velocity of sol injection were nearly same at high velocity of gas injection. Also, Anti-insect repellent impregnation in porous sphere powder were confirmed by TGA methode and its thermal property was stable up to $200^{\circ}C$. We expect that anti-insect repellent powder is applied for plastic compound and process of film manufacture.

Effect of Intake Pressure on Emissions and Performance in Low Temperature Combustion Operation of a Diesel Engine (디젤 저온연소 운전 영역에서 흡기압이 엔진 성능에 주는 영향)

  • Lee, Sun-Youp;Chang, Jae-Hoon;Lee, Yong-Gyu;Oh, Seung-Mook;Kim, Yong-Rae;Kim, Duk-Sang
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.1
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    • pp.88-94
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    • 2012
  • One of the effective ways to reduce both $NO_x$ and PM at the same time in a diesel CI engine is to operate the engine in low temperature combustion (LTC) regimes. In general, two strategies are used to realize the LTC operation-dilution controlled LTC and late injection LTC - and in this study, the former approach was used. In the dilution controlled regime, LTC is achieved by supplying a large amount of EGR to the cylinder. The significant EGR gas increases the heat capacity of in-cylinder charge mixture while decreasing oxygen concentration of the charge, activating low temperature oxidation reaction and lowering PM and $NO_x$ emissions. However, use of high EGR levels also deteriorates combustion efficiency and engine power output. Therefore, it is widely considered to use increased intake pressure as a way to resolve this issue. In this study, the effects of intake pressure variations on performance and emission characteristics of a single cylinder diesel engine operated in LTC regimes were examined. LTC operation was achieved in less than 8% $O_2$ concentration and thus a simultaneous reduction of both PM and $NO_x$ emission was confirmed. As intake pressure increased, combustion efficiency was improved so that THC and CO emissions were decreased. A shift of the peak Soot location was also observed to lower $O_2$ concentration while $NO_x$ levels were kept nearly zero. In addition, an elevation of intake pressure enhanced engine power output as well as indicated thermal efficiency in LTC regimes. All these results suggested that LTC operation range can be extended and emissions can be further reduced by adjusting intake pressure.

The screening of the mutagenicity and desmutagenicity for cooked pork meats according to cooking conditions (조리 조건을 달리한 가열조리된 육류(돼지고기)의 변이원성 검색과 제어에 관한 연구)

  • 정경숙;구성자
    • Korean journal of food and cookery science
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    • v.18 no.6
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    • pp.716-722
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    • 2002
  • Meat(beef, pork, chicken, duck) were cooked by three kinds of instruments (gas grill. electric grill, microwave oven) and extracted with 80% methanol. These methanol extracts were performed the Ames test, employing S. typhimurium tester strain TA100 (in vitro) and micronucleus test (in vivo). The methanol extract of cooked pork showed high mutagenicity in 5.0mg/plate without S9 mix and induced a higher mutagenicity with S9 mix than without S9 mix at 5 mg/plate. In all kinds of cookery methods, pork extracts showed high mutagenicity according to increase of cookery temperature (200$\^{C}$, 260$\^{C}$ and 320$\^{C}$). The methanol extract of cooked pork by electric grill (at 260$\^{C}$, for 5 min) showed high mutagenicity in all kinds of cookery instruments on the Ames test and micronucleus test. In all kinds of meat, the methanol extract of cooked pork showed a higher mutagenicity than the others and chicken showed a lower. The extract after pork soaked in ginger juice showed lower mutagenicity and micronucleus formation than the other vegetable juice.

Development of Biofilter for Reducing Offensive Odor from Pig House (돈사 악취 저감을 위한 바이오필터 개발)

  • Lee, Seung-Joo;Lim, Song-Soo;Chang, Dong-Il;Chang, Hong-Hee
    • Korean Journal of Environmental Agriculture
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    • v.24 no.4
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    • pp.386-390
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    • 2005
  • This study was conducted to develop the biofilter fur reducing ammonia $(NH_3)$ and hydrogen sulfide $(H_2S)$ gas emission from a pig house. A biofilter was designed and constructed by a type of squeeze air into the column type of air flow upward. Its column size was ${\Phi}260{\times}360mm$. It was used pressure drop gauge, turbo blower, air temperature, velocity sensor and control program that was programed by LabWindows CVI 5.5. Mixing materials were consisted with composted pine tree bark and perlite with 7:3 ratio (volume). The biofilter media inoculated with ammonia (Rhodococcus equi A3) and hydrogen sulfide (Alcaligenes sp. S5-5.2) oxidizing microorganisms was installed in a commercial pig house to analyzed the effectiveness of biogas removal for 10 days. Removal rates of ammonia and hydrogen sulfide gases were 90.8% and 81.5%, respectively. This result suggests that the pine compost-perlite mixture biofilter is effective and economic for reducing ammonia ana hydrogen sulfide gases.

Evaluation of Distribution Characteristics for Petroleum Hydrocarbon in Groundwater by TPH Fraction Analysis (석유계 총 탄화수소(Total Petroleum Hydrocarbons, TPH) 분획분석법을 이용한 지하수 중 유류오염물질 분포특성 평가)

  • Kim, Deok Hyun;Park, Sunhwa;Choi, Min-Young;Kim, Moonsu;Yoon, Jong Hyun;Lee, Gyeong-Mi;Jeon, Sang-Ho;Song, Dahee;Kim, Young;Chung, Hyen Mi;Kim, Hyun-Koo
    • Journal of Soil and Groundwater Environment
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    • v.23 no.5
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    • pp.26-36
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    • 2018
  • Total petroleum hydrocarbon (TPH) is a mixture of various oil substances composed of alkane, alkene, cycloalkane, and aromatic hydrocarbons (benzene, toluene, ethylbenzene, xylene, etc.). In this study, we investigated 92 groundwater wells around 36 gas stations to evaluate distribution characteristics of petroleum hydrocarbons. Groundwater in the wells was sampled and monitored twice a year. The fraction analysis method of TPH was developed based on TNRCC 1006. The test results indicated aliphatic and aromatic fractions accounted for 28.6 and 73.8%, respectively. The detection frequencies of TPH in the monitoring wells ranged in 21.6 - 24.2%. The average concentration of TPH was 0.11 mg/L with the concentration range of 0.25~0.99 mg/L. In the result of TPH fraction analysis, in aliphatic fractions were 19% (C6-C8 : 0.2%, C8-C10 : 0.4%, C10-C12 : 0.4%, C12-C16 : 0.5%, C16-C22 : 1.0%, C22-C36 : 16.6%), and aromatic fractions were 81% (C6-C8 : 1.1%, C8-C10 : 0%, C10-C12 : 2.9%, C12-C16 : 0.3%, C16-C22 : 4%, C22-C36 : 66.8%). Fractions of C22-C36 were detected in about 83% of the monitoring wells, suggesting non-degradable characteristics of hydrocarbons with high carbon content.

Deposition Characteristics of Ti-Si-N Films Deposited by Radio Frequency Reactive Sputtering of Various Ratio of Ti/Si Targets in an $N_2$/Ar Ambient (Ti/Si의 조성비율이 다른 타겟을 이용한 sputtered Ti-Si-N 박막의 증착특성 연구)

  • Park, Sang-Gi;Kang, Bong-Joo;Yang, Hee-Jeong;Lee, Won-Hee;Lee, Eun-Goo;Kim, Hee-Jae;Lee, Jae-Gap
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.580-584
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    • 2001
  • We have investigated the deposition characteristics of Ti-Si-N films obtained by rf magnetron sputtering with ratios of Ti/Si targets in an $Ar/N_2$ gas mixture. The growth rate and stoichiometry dependence of the Ti-Si-N films on the ratio of Ti/Si and $N_2$ flow rate ratio were found to be due to the different nitriding rate of Ti and Si targets. Additionally, their different sputtering yield of nitrified Ti and Si make a reason as well. Lowering Si content in the film favored the formation of crystalline TiN, leading to the low resistivity. Increasing N content led to the Ti-Si-N films having a higher density and compressive stress, suggesting that the N content in the film is one of the most important factors determining the diffusion barrier characteristics. In the current work, the optimum process conditions for the formation of efficient diffusion barrier of Ti-Si-N film has successfully obtained by manipulating the Ti/Si ratio of target and $N_2$ flow rate ratio.

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Gemological Characteristics of Rubies and Sapphires from Tanzania (탄자니아산 루비 및 사파이어의 보석광물학적 특성)

  • Park Hee-Yul;Sung Kyu-Youl
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.4 s.46
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    • pp.313-323
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    • 2005
  • XRD, XRF, EPMA, FT-IR, and SEM-CL studies were carried out in order to characterize gemological features of corundum from Tanzania. Fluorescence reaction of the Tanzanian corundum to short and long wave ultraviolet rays was weakly detected. Inclusions in Tanzanian corundum are divided into five types, Type I is fluid-rich inclusion, Type II is gas-rich inclusion, Type III is liquid $CO_{2}$ inclusion, Type IV is solid-rich inclusion, and Type V is a mixture of fluid and solid inclusion and daughter minerals. SEM-CL images show twin structure with growth texture, microphenocryst of spinel solid inclusions, massive and growth texture. Ruby and sapphire from Tanzania are distinctly distinguished by concentrations of Fe and Cr, and plotted in the particular field at $Al_{2}O_{3}/100-Cr_{2}O_{3}-Fe_{2}O_{3}$ diagram. According to FT-IR analysis, all corundum specimens from Tanzania showed the similar patterns, and absorption peaks of $455.09\~459.23\;cm^{-1},\;603.15\~611.71\;cm^{-1},\;1509.00\~1655.05\;cm^{-1}\;and\;3436.41\~3468.87\;cm^{-1}$. These distinctive characteristics mentioned above can be used to identify the locality and source of corundum stones from Tanzania.