• Title/Summary/Keyword: mixed resin

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Removal of Copper from the Solution Containing Copper, Nickel, Cobalt and Iron (구리, 니켈, 코발트, 철 혼합용액(混合溶液)으로부터 구리의 제거(除去))

  • Park, Kyung Ho;Nam, Chul Woo;Kim, Hyun Ho;Barik, Smruti Prakash
    • Resources Recycling
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    • v.22 no.6
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    • pp.48-54
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    • 2013
  • The methods to separate and remove copper in the mixed solution ((399 ppm Cu, 208 ppm Fe, 15.3 g/L Ni, 2.1 g/L Co) with nickel, cobalt and iron were investigated. With hydroxide precipitation method, copper and iron ions were completely precipitated and removed from the solution at pH 7 while some nickel and cobalt also were precipitated. 99.75% copper could be precipitated and removed as copper sulfide from the solution with adding $Na_2S$ (1.25 w/v concentration) of 2 times equivalent of Cu at pH 1. Copper was selectively absorbed on TP 207 ion exchange resin at equilibrium pH 2.0 and could be eluted from copper-loaded resin using 5% $H_2SO_4$.

An Experimental Study on the Ion Reaction and the Electrochemical Rebar-Corrosion in Aqueous Solution Mixed with Sulfate and Chloride Ion-Reactive Material (황산, 염소이온 반응 소재 혼입 수용액에서의 이온반응성 및 전기화학적 철근 부식에 관한 실험적 연구)

  • Ryu, Hwa-Sung;Shin, Sang-Heon;Kang, Tae-Won;Lim, Chang-Gil;Kim, Hong-Tae
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.1
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    • pp.31-38
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    • 2019
  • In this study, amine derivatives and ion exchange resins were selected to actively control penetration ions ($SO{_4}^{2-}$, $Cl^-$) as the element technology of repair materials for concrete structures in drainage environments. Ions ($SO{_4}^{2-}$, $Cl^-$) adsorption performance and corrosion resistance of calcium hydroxide solution with amine derivative and ion exchange resin were confirmed by ion chromatography and potentiostat analysis. As a result of the experiment, it was confirmed that the amine derivative is excellent in the adsorption of chlorine ion and the ion exchange resin is excellent in the adsorption of sulfate ion. It has been confirmed that corrosion resistance can be increased by proper combination of two materials in the calcium hydroxide solution containing sulfate ion and chloride ion simulating sewage environment.

Fabrication of the Alnico Bonded Magnets for Measuring Instruments and its Magnetic Properties (계측기용 알니코 본드자석의 제조 및 자기 특성연구)

  • Kim, Jung Sik
    • Korean Journal of Metals and Materials
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    • v.49 no.1
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    • pp.85-91
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    • 2011
  • Alnico magnets can be used as magnetic bearings for the precise electric power measuring instruments such as watt-hour meters because they have high remanence ($B_r$), relatively high maximum energy product ($(BH)_{max}$), and excellent temperature stability. In this study, Alnico composite magnets were fabricated by appropriately mixing alnico alloy powders with epoxy resin and binder. The Alnico powders mixed with epoxy resin and a hardening agent with a mixing ratio of 96:4 were pressed and then cured to be a toroid-type ring magnet with an outer diameter (${\Phi}_{out}$) of 15 mm, an inner diameter (${\Phi}_{in}$) of 6.5 mm and a thickness (t) of 2.5 mm, respectively. The magnetic properties of the Alnico ring magnets were varied with the mixing ratio of Alnico powders that possess different average particle sizes. The Alnico ring magnet prepared by mixing 5 wt% of $50{\mu}m$ (small size) powder, 15~20 wt% of $150{\mu}m$ (medium size) powder, and 75~80 wt% of $300{\mu}m$ (large size) powder showed the best magnetic properties (remanent induction, coercive force, maximum energy product, and surface flux density). In addition, measurements of temperature and moisture characteristics for the Alnico ring magnets showed that the surface flux densities of the N and S poles decreased little and the repulsive distance between the magnets decreased as small as 0.05 mm after 10 days.

Study on Mechanical and Electrical Properties of Expanded Graphite/Carbon fiber hybrid Conductive Polymer Composites (팽창흑연/탄소섬유 혼합 보강 전도성 고분자 복합재료의 특성 평가)

  • Oh, Kyung-Seok;Heo, Seong-Il;Yun, Jin-Chul;Han, Kyung-Seop
    • Composites Research
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    • v.20 no.6
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    • pp.1-7
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    • 2007
  • Expanded graphite/carbon fiber hybrid conductive polymer composites were fabricated by the preform molding technique. The conductive fillers were mechanically mixed with a phenol resin to provide an electrical property to composites. The conductive filler loading was fixed at 60wt.% to accomplish a high electrical conductivity. Expanded graphites were excellent in forming a conductive networking by direct contacts between them while it was hard to get the high flexural strength over 40MPa with using only expanded graphite and phenol resin. In this study, carbon fibers were added in composites to compensate the weakened flexural strength. The effect of carbon fibers on the mechanical and electrical properties was examined according to the weight ratio of carbon fiber. As the carbon fiber ratio increased, the flexural strength increased until the carbon fiber ratio of 24wt.%, and then decreased afterward. The electrical conductivity gradually decreased as the increase of the carbon fiber ratio. This was attributed to the non-conducting regions generated among the carbon fibers and the reduction of the direct contact areas between expanded graphites.

Study on the Strength Characteristics of PP and ABS According to the Ratio of Recycled Resin (재사용 수지 비율에 따른 PP, ABS의 강도 특성에 관한 연구)

  • Jun-Han Lee;Jong-Sun Kim
    • Design & Manufacturing
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    • v.18 no.2
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    • pp.57-63
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    • 2024
  • In this study, the recyclability of commonly used PP (polypropylene) and ABS (acrylonitrile butadiene styrene) was evaluated by molding test specimens from mixture of virgin and shredded material, followed by measuring their strength properties, Experiments were conducted o two type of PP (transparent and non-transparent) and two types of ABS (white and yellow). Test specimens for each resin were prepared with shredded material ratios ranging from 10% to 50% in 10% increments. Changes in tensile strength, elastic modulus, and elastic limit were analyzed based on the mixing ratio of the shredded material. The experimental results demonstrated that the strength properties of all the resins remained consistent within a certain range, even with increasing proportions of shredded material. For transparent PP, the tensile strength ranged from 30.87± MPa, the elastic modulus from 1.23±0.04 GPa, and the elastic limit from 19.17±0.44%. Non-transparent PP exhibited a tensile strength ranging from 27.71±0.58 MPa, an elastic modulus from 1.03±0.06 GPa, and an elastic limit from 17.35±0.41%. For ABS, white ABS had a tensile strength of 39.42±0.28 MPa, an elastic modulus of 1.94±0.01 GPa, and an elastic limit of 36.76±0.25%. Yellow ABS showed a tensile strength of 39.25±0.78 MPa, an elastic modulus of 1.94±0.01 GPa, and an elastic limit of 37.14±0.23%, with values remaining consistent within this range. Based on these results, it was confirmed that the mechanical properties of the resins used in this study do not change significantly when mixed with recycled shredded material, indicating excellent mechanical recyclability.

Performance of Membrane Capacitive Deionization Process Using Polyvinylidene Fluoride Heterogeneous Ion Exchange Membranes Part II : Performance Study of Membrane Capacitive Deionization Process (폴리비닐플루오라이드 불균질 이온교환막을 이용한 막 결합형 축전식 탈염공정의 탈염성능 Part II : 불균질 이온교환막의 탈염성능)

  • Park, Cheol Oh;Rhim, Ji Won
    • Membrane Journal
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    • v.27 no.3
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    • pp.240-247
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    • 2017
  • In this study, the heterogeneous ion exchange membranes prepared by the combination of the carbon electrode and mixed the cation and anion exchange polymers and polyvinylidene fluoride as the basic polymer together were made to recognize the efficiency of the salt removal for the application of the membrane capacitive deionization process. The mixing weight ratio of the solvent, basic polymer and ion exchange resin was 7 : 2 : 1 and this mixed solution was directly cast on the electrode. As for the operating conditions of the adsorption voltage and time, feed flow rate, desorption voltage and time of the feed solution NaCl 100 mg/L, the salt removal efficiencies (SRE) were measured. Apart from this NaCl, the $CaCl_2$ and $MgSO_4$ solutions were investigated in terms of SRE as well. Typically, SRE for NaCl 100 mg/L solution under the conditions of adsorption voltage/time, 1.5 V/3 min, desorption voltage/time -0.1 V/3 min, was shown 98%. And for the $CaCl_2$ and $MgSO_4$ solutions, the SREs of 70 and 59% were measured under the conditions of adsorption voltage/time, 1.2 V/3 min, desorption voltage/time -0.5 V/5 min, respectively.

Current status of the types of dental filling and preventive materials among children in mixed dentition (혼합치열기 어린이의 치아우식 예방 및 충전 재료 현황에 관한 조사)

  • Oh, Ae-Young;Choi, Youn-Hee;Jin, Hye-Jung;Park, Ji-Hye;Kim, Young-Suk;Kwon, Ho-Jang;Song, Keun-Bae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.4
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    • pp.1483-1491
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    • 2010
  • The purpose of this study was to examine current status of the types of dental filling materials and preventive materials among Korean children in mixed dentition. Seven elementary schools were randomly selected from four metropolitan regions in South Korea. The total of 711 children aged 9-10 years old were examined with their parents’ informed consents. Oral examination was conducted by one trained dentist. The mean number of dfs was $7.9{\pm}8.0$ ($ds=1.3{\pm}2.5,\;fs=6.6{\pm}7.6$) and DMFS was $1.4{\pm}2.2$ ($DS=0.2{\pm}0.8,\;FS=1.1{\pm}2.1$). The average of filled surfaces using amalgam, composites, sealants, and others were $2.8{\pm}3.9,\;1.6{\pm}2.8,\;2.9{\pm}3.2$, and $4.5{\pm}7.0$, respectively. The use of dental filling material according to region, the amalgam was the highest in Daegu and the resin was the highest in Pusan. In permanent teeth, about 70% of total filling surfaces had sealant and about 20% was resin fillings, and the proportion of amalgam filling surfaces was less than 10%.

Effects of Treatment Methods of Fire-retardant and Layup of Treated Veneers on the Performances of Plywoods (내화약제(耐火藥劑)의 처리방법(處理方法) 및 처리단판(處理單板)의 조판형태(調板形態)가 합판(슴板)의 성능(性能)에 미치는 영향(影響))

  • Son, Jung-Il;Cho, Jae-Sung;Suh, Jin-Suk
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.3
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    • pp.39-50
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    • 1999
  • This research was carried out to investigate the development of fire-retardancy treatment technology and performance evaluation of fire-retardant treated plywoods. Radiata pine, keruing, dillenia, calophyllum and terminalia veneers were treated by normal(conventional) pressure soak(NPS) and vacuum-pressure-soak(VPS) using 20% water solution of diammonium phosphate. Then, 4.8mm thick, 3ply plywoods were fabricated with combination of fire-retardant treated, untreated or water-immersion types and several composition types of radiata pine and keruing veneers, i,e. the uniform and the mixed types in species composition, and the homogenious and the alternate layer types in veneer treatment. In composed species, the retention and the treatment effects of fire-retardant chemicals III radiata pine was still greater than those of keruing. The effect of VPS treatment was larger than that of NPS treatment, however, adhesive bonding strength and bending strength of plywoods treated by these two methods were not necessarily lowered, compared to those of untreated plywood. And also, fire endurance performance of the urea melamine resin-bonded plywood was greater than that of the phenol resin-bonded plywood. In result, the appropriate combination in veneer species and layer as well as alternate fire-retardant treatments would be more efficiently available in service.

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Study on the Property and Applicability of the Bisphenol-A Type Epoxy Putty According to the Mix of Filler (개발된 Bisphenol-A계 Epoxy Putty의 충전제 배합에 따른 물성 및 적용성에 관한 연구)

  • Wi, Koang-Chul;Oh, Seung-Jun
    • Journal of Conservation Science
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    • v.32 no.4
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    • pp.459-469
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    • 2016
  • The goal of this study was to examine property changes induced by the choice of filler used with an epoxy resin that was developed in 2014 to restore cultural assets and consider the applicability of the resin as a restorative agent. The properties of putty mixed with 9 types of fillers and as-developed resins were compared with those of existing materials with regard to stability, superiority and applicability. The potential of the putty as an alternative material was also examined. The materials produced the best adhesiveness, color change and hardness results when mixed with lime. Micro balloon produced the best wear rates and hardening times, while diatomite produced the best tensile and compressive strengths. A plaster and white mineral pigment mixture produced the best specific gravity. Every material except for lime exhibited about 2.5-20 times higher wear rates than the existing material, which is thought to exhibit an excellent cutting force. The hardening time was enhanced by about 0.5-9 times to improve convenience. The stability of the relic was also ensured by improving hand staining without any shrinkage or deformation. The material exhibited about 0.5-27 times less yellowing. Thus, it is thought to be a material that can reduce property changes and reduce the degree of relic fatigue which occurs during reprocessing and sense of difference from relic.

IN VIVO CHANGES OF THE ACIDITY OF VARIOUS DENTAL LINERS (In vivo에서 수종이장재의 산도변화에 관한 연구)

  • Lee, Mi-Jeong;Ahn, Yun-Sil;Lee, Yong-Woo;Son, Ho-Hyun;Lee, Kwang-Won
    • Restorative Dentistry and Endodontics
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    • v.23 no.1
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    • pp.433-442
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    • 1998
  • The purpose of this study was to observe the changes of acidity of resin cement(Time Line), glass ionomer cement(GC Fugi Lining LC), zinc phosphate cement(Fleck's zinc cement). zinc oxide eugenol cement(Sultan,Chemists.) in vivo and in vitro. Class I cavities with 3mm depth were prepared on the occlusal surfaces of 20 recently extracted human Mn. molar teeth and 20 human Mn. 3rd molar teeth in oral cavity. The prepared cavities were divided into 4 groups of each 5 teeth using the above 4 cavity liners. Each cement was mixed in accordance with manufacturer's direction at the room temperature of $23^{\circ}{\pm}5^{\circ}C$ and filled into the cavity in a width of 1 mm. The microelectrode of pH meter was inserted into the prepared cavity which was filled with mixed cement, and the acidity of cement was measured for 3 days from the beginning of cement mix in vitro and in vivo. The measured acidity was then statistically analyzed by ANOVA. The results were as follows. 1. In vitro, the pH of zinc oxide eugenol cement was statistically lower than that of the three other groups at 2min, 4min, 6min, 8min, 10min, 12min, 18min, 20min. (p<0.05). 2. The pH of zinc oxide eugenol cement in vivo was statistically higher than that in vitro at 16min,16min, 20min(p<0.05). 3. The pH of zinc phosphate cement in vivo was statistically higher than that in vitro at 4min, 20min(p<0.05). 4. In vitro and in vivo, there was no significant difference in the pH between the resin cement and the glass ionomer cement(p>0.05). 5. The initial acidity was not high, but almost neutral in all kinds of the cements.

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