• Carbon letters
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• 제15권2호
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• pp.142-145
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• 2014

Isotropic synthetic graphite scrap and phenolic resin were mixed, and the mixed powder was formed at 300 MPa to produce a green body. New bulk graphite was produced by carbonizing the green body at $700^{\circ}C$, and the bulk graphite thus produced was impregnated with resin and re-carbonized at $700^{\circ}C$. The bulk density of the bulk graphite was $1.29g/cm^3$, and the porosity of the open pores was 29.8%. After one impregnation, the density increased to $1.44g/cm^3$ while the porosity decreased to 25.2%. Differences in the pore distribution before and after impregnation were easily confirmed by observing the microstructure. In addition, by using an X-ray diffractometer, the degrees-of-alignment (Da) were obtained for one side perpendicular to the direction of compression molding of the bulk graphite (the "top-face"), and one side parallel to the direction of compression molding (the "side-face"). The anisotropy ratio calculated from the Da-values obtained was 1.13, which indicates comparatively good isotropy.

• 대한치과보철학회지
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• 제28권1호
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• pp.203-216
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• 1990

The purpose of this study was to evaluate the cervical margin fitness in the collarless metal ceramic crowns formed by different techniques. Specimens were divided as follows : the metal ceramic crowns with metal butt margin as group I, the collarless metal ceramic crowns formed with resin binder technique as group II, and the collarless metal ceramic crowns formed with shoulder powder mixed with phosphate-bonded investment liquids on a refractory die as group III. Each group was made of five specimens, and their marginal fitness on each epoxy die was evaluated under scanning electron microscope of x200 magnification at three measuring points : mesial, central, distal. The following results were obtained. 1. The metal ceramic crowns with metal butt margin exhibited significantly better marginal fitness than the collarless metal ceramic crowns. The marginal fitness in descending order was group I, III, II. 2. The collarless metal ceramic crown formed with resin binder technique had the worst marginal fitness & showed cervical color variation and dermacation between the corrected porcelain & the dentin porcelain. 3. The collarless metal ceramic crowns formed with shoulder powder mixed with phosphate-bonded investment liquids on a refractory die exhibited significantly better marginal fitness & sharper marginal configuration than the other collarless group.

• Journal of the Korean Wood Science and Technology
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• 제29권3호
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• pp.27-35
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• 2001

Four different sources of wood-fibers from Eucalyptus, Italian poplar, hemlock, and mixed species fibers were used to study the influence of their fiber characteristics on the performance of medium density fiberboard (MDF) panels bonded with both urea-formaldehyde (UF) and phenol-formaldehyde (PF) adhesives. Included fiber characteristics were fiber length, size distribution, bulk density, and acidity. Physical and mechanical properties of MDF panels manufactured by dry process using these different fibers were determined for the comparison of board performance. Two hardwood species had a large fraction of short fibers resulting in a higher bulk density while very long hemlock fibers had lower bulk density. Fiber acidity was revealed to strongly affect the internal bond (IB) strength of MDF panels bonded with UF resins. MDF panels made from mixed species fibers showed highest IB strength of all panels prepared. UF-bonded MDF panels showed poor dimensional stability. In conclusion, the present study showed that wood-fiber characteristics such as fiber length, bulk density, and acidity affect the performance of MDF boards, and also suggested that fiber characteristics be considered for MDF panel manufacture.

• 대한화학회지
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• 제18권1호
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• pp.31-39
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• 1974

$Mn^{++}, Co^{++} 및 Zn^{++}$용액을 실온에서 양이온 교환수지와 2염기 유기산이 들어 있는 용액에 섞어 넣었다. 방사성 금속이온을 추적자로 사용함으로써 금속이온이 수지층과 용액사이에 어떻게 분배되는가를 조사하였다. 이 분배 비율이 유기산이온 농도에 따라 어떻게 달라지는가를 보아, $Mn^{++}, Co^{++} 및 Zn^{++}$이 수용액, 에탄올-물 및 아세톤-물에서 썩신산, 말론산, 프타르산 및 타르타르산과 사이에 1:1착물을 형성한다고 결론하였다. 또한 본 연구의 결과 이들 착물의 안정도가 다음순으로 증가함을 알았다.$Mn^{++}

• 대한치과보철학회지
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• 제44권5호
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• pp.503-513
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• 2006

Statement of the problem: The cold-cured resins used in fabrication of the provisional crown and fixed partial dentures could cause pulpal damage by heat generated during exothermic polymerization reactions. Purpose: In this in vitro study investigates the how external conditions such as material of the matrix, thickness of the matrix and thickness of dentin affect the temperature of the tooth during polymerization reaction of the cold-cured resins. Material and methods : To measure the temperature of the resin, metal die was maintained to the temperature of $37^{\circ}C$ with water bath to simulate the temperature of thetooth and thermocouple was placed in the center of the metal die. Acrylic pipe was cut in height of 1, 2, 3, 6, 10 mm and placed on the metal die and mixed resin was pored in the acrylic pipe As the resin polymerized temperature was recorded with the thermometer. Temperature of the resin using matrix was recorded by using the individual tray relieved in different thickness 2, 5, 7, 10 mm. The material of the matrix was irreversible hydrocolloid impression material, vinyl polysilloxane impression material and vacuum-formed template Temperature rise of the resin using different thickness of tooth section was record ed by placing tooth section on the metal die and placing resin over the tooth section. Results : Conclusion : 1. Temperature rise increased as the thickness of the resin increased but there was no significant differences over 3 mm thickness of the resin. 2. The lowest temperature rise was showed in irreversible hydrocolloid impression material and vinyl polysilloxane impression material vacuum-formed template as in orders. 3, Temperature rise of the resin decreased regardless of the thickness of the matrix when vinyl polysilloxane impression material was used as the matrix. 4 When irreversible hydrocolloid impression material was used as matrix, the temperature rise of the resin decreased as the thickness of the matrix increased and there was no temperature rise when thickness of the matrix reached 10 mm, 5. The temperature rise of the resin did not decreased when Polypropylene vacuum-formed template was used as the matrix. 6, The temperature of the resin increased as the thickness of the dentin decreased.

• Journal of the Korean Wood Science and Technology
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• 제27권2호
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• pp.23-30
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• 1999

한지제지 공정 중에서 발생하는 백색슬러지와 흑색슬러지를 각각 일정비율(10:90, 20:80, 30:70, 40:60)로 목재 섬유와 혼합하고 PMDI, 요소 및 폐지수지를 이용하여 목표비중 0.60, 0.75, 0.90 별로 복합보드를 제조한 결과 전반적으로 볼 때 백색슬러지를 20% 정도까지 혼합하고 PMDI 수지를 적용하면 통상적인 보드와 유사하거나 오히려 더 좋은 치수안정성을 가지는 것으로 판단된다. 또한 흑색슬러지의 경우는 요소수지를 사용하거나 PMDI 수지의 첨가량을 증가시켜 조절한다면 20%의 슬러지 첨가량까지는 치수안정성 면에서 통상적인 보드와 큰 차이가 없는 보드를 제조할 수 있다고 믿어진다.

• Journal of the Korean Wood Science and Technology
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• 제22권1호
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• pp.44-53
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• 1994

This research was carried out to investigate the effect of paper sludge addition on formaldehyde emission, and physical and mechanical properties of UF-particleboard. In order to investigate the effect of paper sludge addition to resin, particleboards were bonded with urea-formaldehyde resins containing 5, 10, 15% paper sludge powders of three types(A Type: -200 mesh, B Type: -100~+200 mesh. C Type: -50~+100 mesh), based on weight of resin solid. Also the effect of paper sludge addition to furnish was studied from particleboards fabricated with ratios of sludge to particle of 5:95, 10:90, 15:85 based on oven-dry weight. Tests were conducted on the manufactured particleboards to determine formaldehyde emission, bending properties, internal bond strength and thickness swelling. The obtained results were summarized as follows: The addition of paper sludge powder to resin yielded a higher pH of cured resin. Formaldehyde emission decreased with the increase of paper sludge powder addition to resin and paper sludge composition ratio to furnish. Particleboard bonded with urea-formaldehyde resin containing paper sludge powder and particleboard mixed with paper sludge have similar bending properties(MOR, MOE) and thickness swelling compared with control particleboard. Internal bond strength of particleboards treated with paper sludge were lower than that of control particleboard. The use of paper sludge as scavenger was achieved reduction of formaldehyde emission without depression of physical and mechanical properties of particleboard. Also the use of paper sludge was able to concluded that there is possibility of partial substitution of wood particle materials.

• 대한치과기공학회지
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• 제30권2호
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• pp.79-86
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• 2008

The purpose of this study was to investigate the effect retention element formed by metal surface treatment method on the bond strength of indirect composite resin and metal. The metal specimens were cast from Ni-Cr alloy($Rexillium^{(R)}$ III). They were divided into 5 groups by applied retention element: $50{\mu}m$ aluminium oxide sandblasting group, $250{\mu}m$ aluminium oxide sandblasting group, 0.2mm retention crystal group, 10% $H_{2}SO_{4}$ solution etching group, $110{\mu}m$ $Rocatec^{TM}$ Plus system group. Total 50 metal specimens were veneered with Sinfony indirect composite resin system. Specimens were tested for shear bond strength on an Instron universal testing machine and fracture mode of fractured specimens were analyzed by SEM and EDS. 1. 0.2 mm retention crystals were most effective in improving the resin-metal shear bond strength (p<0.05). 2. Sandblasting by $250{\mu}m$ aluminium oxide were more effective than sandblasting by $50{\mu}m$ aluminium oxide in improving the resin-metal shear bond strength(p<0.05). 3. Fracture mode of resin-metal fractured surface were cohesive failure mode in 0.2mm retention crystal, mixed failure mode in sandblasted specimens, etched specimens and the specimens sandblasted with $110{\mu}m$ $Rocatec^{TM}$ Plus system.

• 대한치과보철학회지
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• 제44권4호
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• pp.383-393
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• 2006

Statement of problem : Limited research on flowable resin has been undertaken on its application directly on dentin associated with the adhesive systems. Purpose : This study was to evaluate the shear bond strengh and fracture aspect of flowable resin on human dentin with various types of dentin bonding adhesives with thermo cycling effect. Materials and methods: Filtek-Flow(3M ESPE, USA) was used as flowable resin and Eighty human molars were randomly divided into 4 groups : three dentin bonding adhesives (Scotchbond-Multipurpose : 3-step contentional system, One-Step : One-bottle system. Prompt L-Pop : All-in-one, self-etching primer) and 32% etching treatment without bonding adhesive as a control group. For evaluating their durability of bonding, each group was subdivided : storaging in the water at 37$^{\circ}C$(24 hours) and thermocycling (0$^{\circ}C$-55$^{\circ}C$, 30 seconds intervals, 1000 cycle). Shear bond strength tests were performed and resin-dentin interface and fracture mode were observed. Results were analysed by one-way ANOVA and Scheffe's multiple range test. Results and Conclusion : 1. At 0 cycle, the mean shear bond strength of One-Step exhibited the highest value of all groups(p<0.05), and there were no significant differences between Prompt L-Pop and Scotchbond-Multipurpose, Scotchbond-Multipurpose and control(p>0.05). After 1000 thermocycling, One-Step exhibited higher value than other groups(p<0.05), and there were no significant differences among other groups (p>0.05). 2. The shear bond strength of each group was significantly decreased after thermocycling except Scotchbond-Multipurpose (p>0.05). 3. The most common failure mode was adhesive type and mixed type, next in order.

• 대한치과보철학회지
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• 제34권2호
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• pp.233-245
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• 1996

The purpose of this study was to evaluate the effect of thermocycling on bond strength between metal and resin cement according to thermocycling, and to observe the bond failure modes with optical microscope(X30). For this purpose, Super-Bond C & B and Panavia 21 resin cement were used. Metal specimens were made of Vera-Bond and the surface of specimens were sandblasted with $50{\mu}m$ aluminum oxide. All experimental groups were stored in $37^{\circ}C$ distilled water for 72 hours, followed by thermocycling between $5^{\circ}C$ and $55^{\circ}C$ with 15 second dwell time. 500, 1000, 2000 cycles of thermocycling were executed and the tensile bond strength was measured by Instron Universal Testing Machine(Model 4201) The obtained results were as follows : 1. Super-Bond C & B and Panavia 21 did not show statistically significant difference accor-ding to thermocycling test(P>0.05). 2. Super-Bond C & B specimens exhibited statistically significant higher tensile bond stre-ngth than Panavia 21 for all experimental groups(P<0.05). 3. Super-Bond C & B exhibited mixed mode failure with partial adhesive and partial cohe-sive failure, and most of Panavia 21 exhibited cohesive failure and some mixed mode failure.