• Applied Chemistry for Engineering
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• v.19 no.2
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• pp.191-198
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• 2008

The thermal degradation characteristics of high molecular components obtained from pyrolysis of mixed waste plastics have been studied by thermogravimetric analysis (TGA) and gas chromatography spectrometry (GC-MS). The kinetics of thermal degradation has been studied by a conventional nonisothermal thermogravimetric technique at several heating rates between 10 and $50^{\circ}C/min$. The dynamic thermogravimetric analysis curve and its derivative have been analyzed using a variety of analytical methods reported in the literature to obtain information on the kinetic parameters such as activation energies and reaction orders. The yields of liquid products have been monitored by batch pyrolysis reactor under various reaction temperatures and reaction times. And the characteristic of liquid products with the increase in reaction temperature has been performed by GC-MS.

• Resources Recycling
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• v.16 no.5
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• pp.57-64
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• 2007

Triboelectrostatic separation of mixed three kinds of plastics, PVC, PET and PMMA, in the range of similar gravity has been performed through a two-stage separation process. Polypropylene (PP) and high-impact polystyrene (HIPS) were found to be the most effective materials for a tribo-charger in the separation of PVC, PET and PMMA. In the 1st stage using the PP cyclone charger, PVC grade and recovery depended considerably on the air velocity (10 m/s), the relative humidity (<30%), the electric field (>200 kV/m) and the splitter position (+2 cm from the center) in the triboelelctrostatic separator unit. At an optimum condition a PVC grade of 99.6% and a recovery of 97.5% was achieved. In the 2nd stage using the HIPS cyclone charger, a PMMA grade of 98.3% and a recovery of 97.0% was obtained under the conditions of 10m/s air velocity, over 250 kV/m electric field, central splitter position and less than 40% relative humidity.

• Journal of ILASS-Korea
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• v.7 no.2
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• pp.7-15
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• 2002

A particle flow visualization, electrostatic charging measurement and separation of triboelectrically charged particles in the external electric field by a fluidized bed tribocharger are conducted for the removal of PVC particles from mixed waste plastics. The laboratory-scale triboelectrostatic separation system consists of the fluidized bed tribocharger, a separation chamber, a collection chamber and a controller. PVC and PET particles can be imparted negative and positive surface charges respectively due to the difference of triboelectric charging series between particles and particles in the fluidized bed tribocharger, and can be separated by passing them through an external electric field. To visualize these charged particles, He-Ne laser is used with cylindrical lenses to generate a sheet beam. In the charging measurement, the particle motion analysis system (PMAS), capable of determining particle velocity and diameter. is used to non-intrusively measure particle behavior in high strength electric field. The average charge-to-mass ratios of PVC and PET particles are $1.4\;and\;1.2{\mu}C/kg$, respectively. The highly concentrated PVC (91.9%) can be recovered with a yield of about 96.1% from the mixture of PVC and PET materials for a single-stage processing. The triboelectrostatic separation system using the fluidized tribocharger shows the potential to be an effective method for removing PVC from mixed plastics for waste plastic recycling.

• Journal of Mechanical Science and Technology
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• v.16 no.10
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• pp.1336-1345
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• 2002

A triboelectrostatic separation system using a fluidized bed tribocharger for the removal of PVC material in the mixture of PVC/PS plastics is designed and evaluated as a function of electric field strength, air flow rate, and the mixing ratio of two-component mixed plastics. It consists of a fluidized-bed tribocharger, a separation chamber, a collection chamber and a controller. PVC and PS particles can be imparted negative and positive surface charges, respectively, due to the difference in the work function values of plastics suspended in the fluidized-bed tribocharger, and can be separated by passing them through an external electric field. Experimental results show that separation efficiency is strongly dependent on the electric Deld strength and particle mixing ratio. In the optimum conditions of 150 Ipm air flow rate and 2.6 kV/cm electric field strength a highly concentrated PVC (99.1%) can be recovered with a yield of more than 99.2% from the mixture of PVC and PS materials for a single stage of processing.

• International Journal of Advanced Culture Technology
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• v.9 no.3
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• pp.305-314
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• 2021

Currently, due to COVID-19, household waste has a lot of impact on the environment due to packaging of food delivery. In this paper, we design and implement Faster-RCNN, SSD, and YOLOv4 models for municipal waste detection and classification. The data set explores two types of plastics, which account for a large proportion of household waste, and the types of aluminum cans. To classify the plastic type and the aluminum can type, 1,083 aluminum can types and 1,003 plastic types were studied. In addition, in order to increase the accuracy, we compare and evaluate the loss value and the accuracy value for the detection of municipal waste classification using Faster-RCNN, SDD, and YoloV4 three models. As a final result of this paper, the average precision value of the SSD model is 99.99%, the average precision value of plastics is 97.65%, and the mAP value is 99.78%, which is the best result.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.20 no.4
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• pp.80-86
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• 2021

Plastics are widely used in mechanical and other fields due to their light weight, design flexibility, and molding processability. In processing plastics, defective products are mixed and reprocessed to improve production efficiency and reduce costs. In this study, an experiment was conducted to confirm the coefficient of thermal expansion of HDPE during this reprocessing. The coefficient of thermal expansion was measured at different measurement directions and heating rates. As a result, we observed that the coefficient of thermal expansion in the direction perpendicular to the injection direction is greater than that in the horizontal direction.

• Proceedings of the KSRS Conference
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• 2003.11a
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• pp.1460-1463
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• 2003

In this study, plastic detection technique was developed, applying remote sensing technology as a method to extract plastic wastes, which is one of the big causes of concern contributing to environmental destruction. It is possible to extract areas where plastic (including polypropylene and polyethylene) wastes are prominent, using ASTER data by taking advantage of its absorptive characteristics of ASTER/SWIR bands. The algorithm is applicable to define large industrial wastes disposal sites and areas where plastic greenhouses are concentrated. However, the detection technique with ASTER/SWIR data has some research tasks to be tackled, which includes a partial secretion of reference spectral, depending on some conditions of plastic wastes and a detection error in a region mixed with vegetations and waters. Following results were obtained after making comparisons between several detection methods and plastic wastes in different conditions; (a)'spectral extraction method' was suitable for areas where plastic wastes exist separated from other objects, such as coastal areas where plastic wastes drifted ashore. (single plastic spectral was used as a reference for the 'spectral extraction method') (b)On the other hand, the 'spectral extraction method' was not suitable for sites where plastic wastes are mixed with vegetation and soil. After making comparison of the processing results of a mixed area, it was found that applying both 'separation method' using un-mixing and ‘spectral extraction method’ with NDVI masked is the most appropriate method to extract plastic wastes. Also, we have investigated the possibility of reducing the influence of vegetation and water, using ASTER/TIR, and successfully extracted some places with plastics. As a conclusion, we have summarized the relationship between detection techniques and conditions of plastic wastes and propose the practical application of remote sensing technology to the extraction of plastic wastes.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.1
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• pp.89-95
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• 2009

The current enforce decree of "The Act on the Promotion of Construction Waste Recycling" divides seventeen kinds of construction wastes by property and configuration. Mixed construction waste, one of them classified by the enforce decree, is composed two more than justified construction wastes except refuse soil and rock. In construction wastes justified by enforce decree of this law, most refuse concrete and asphalt concrete of construction wastes are recycled. As well as refuse metal is separated, sorted from bulk them, and merchandised for value. Finally this is used the secondary manufactured products. Even though combustible construction wastes like refuse wood, plastics, fiber can be recycled RDF(Refuse derived fuel) or RPF(Refuse plastic fuel) because of high caloric value and low heavy metal but most of them are discharged as mixed construction waste and then treated by treated by incineration and landfill. Therefore, to control construction waste flow efficiently, construction wastes are classifies first combustible, incombustible, mixed combustible, incombustible and etc. in this study. The combustible waste is consisted refuse wood, plastics, fiber and etc. and incombustible waste contains refuse concrete, asphalt, and etc. Mixed construction is construction waste that can not separate from mixed waste bulk with different kinds.

• Resources Recycling
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• v.16 no.5
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• pp.71-76
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• 2007

The mixed plastic waste generated from households after hand-picking and/or mechanical sorting processes amounts to 1,750,000 ton in 2006, and most of these waste are finally end up with landfill and/or incineration due to the lacks of separation technologies and economical reasons. The mixed plastic wastes can not be used as raw materials for chemical and/or thermal recycling processes because of their high content of PVC(upto 4.0 wt.%). In the present research, gravity separation system has been developed to remove PVC from the mixed plastic waste and to recover the PO-type plastics. This system mainly consists of air classification, magnetic separation, one-step crushing, feeding system at fixed rate and wet-type gravity separation system. The gravity system based on centrifugal separation has been developed at capacity of 0.5 ton/h and it consists of mixing, precleaning, separation, dewatering, recovery system and wastewater treatment system, etc. The main objective of this process is to achieve high separation efficiency of polyolefins with less than 0.3 wt.% PVC content and less than 10% moisture content in the final products. In addition, a crushing unit of with 8 rotor system is also developed to improve the crushing efficiency of soft-type plastics. The system with a capacity of 1.0 ton/h is developed and operational results are presented.

• Journal of the Korean Society of Safety
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• v.21 no.1 s.73
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• pp.65-71
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• 2006

Flame retardancy and mechanical properties of polyolefinic mixed waste plastics/filler composites were investigated by using inorganic flame retardant(magnesium hydroxide) and PUB(polyurethane block) powder generated from cryogenic insulation process. All composites were obtained by extrusion and after compression molding. The effect of PUB powder on the properties of the composites was studied by tensile and izod impact test, morphology studies and flammability as LOI and UL94 vertical burning test and smoke density. The objective of this work is to obtain good mechanical properties from recycled PP composites with $Mg(OH)_{2}/PUB$ powder as fillers and optimum cost-performance balance, in addition to flame retardant characteristics.