• Title/Summary/Keyword: mixed hydrocarbon

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Effect of Hydrocarbon Uptake Modes on Oil Degradation Rate by Mixed Cultures of Petroleum Degraders (Hydrocarbon Uptake Modes에 따른 유류분해 미생물 혼합체의 원유분해능)

  • 고성환;이홍금;김상진
    • KSBB Journal
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    • v.13 no.5
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    • pp.606-614
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    • 1998
  • In this study, biodegradation rate of Arabian light crude oil by mixed cultures of selected petroleum-degraders was determined. Their modes of hydrocarbon uptake were then observed to determine whether there are differences in biodegradation rate by the mixed cultures. By the mixed cultures of petroleum-degraders having same modes of hydrocarbon uptake, such as strain US1 and K1 (using pseudo-solubilized hydrocarbons by a biosurfactants), K2-2 and P1(using hydrocarbons by direct contact), CL 180 and IC-10 (mixed type of uptake modes), the biodegradation rates of aliphatics in the crude oil were increased more than those by their pure cultures, about 40%, 25% and 20%, respectively. Biodegradation rate of strain KH3-2 (using only water- dissolved hydrocarbons) was increased by mixed cultures with strain K1, CL180 or IC-10 possessing high emulsifying activity. However, the biodegradation rate of the crude oil was decreased about 20%-40% by the mixed cultures of petroleum-degraders having different mode of hydrocarbon uptake, such as addition of strain US1 or K1 in the cultures of K2-2 or P1. Biosurfactants produced by US1 or K1 seems to enhance the emulsification of crude oil in aqueous phase but inhibit the attachment of K2-2 or P1 to crude oil. As same phenomena, the addition to Triton X-100 into the culture of strain US1, K1, CL180, IC-10 or KH3-2 increased the biodegradation rate, but the addition in the culture of strain K2-2 or P1 decreased the biodegradation rate. The mixed culture made of CL180, IC-10 and KH3-2 degraded 61.5% of aliphatics and 69% of aromatics in 3% (v/v) of Arabian light crude oil added.

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Microemulsifieation of Chlorinated Hydrocarbon/water with Mixed Surfactant Systems (혼합 계면활성제를 이용한 염소화 탄화수소l물의 마이크로에멀젼 연구)

  • 김천희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.22 no.3
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    • pp.265-265
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    • 1998
  • The phase behavior of chlorinated hydrocarbon/mixed surfactants/water microemulsion systems were investigated for dry cleaning solvent properties. With appropriate surfactant mixtures, Winsor type I-III-II microemulsions were generated which is the same as hydrocarbon systems. For perchloroethylene(PCE) with mixed Tween systems, the optimum salinity(S*) decreases and the optimum solubilization parameter(o*) increases with decreas- ing HLB. For PCE with mixed Aerosol MA and ethoxylated alcohol systems, S* and o* both increase with increasing ethylene oxide moles. For dichlorobenzene(DCB) with mixed Aerosol MA and ethoxylated or propoxylated sulfate systems, S* and o* both increase with increasing ethylene oxide moles or propylene oxide moles.

Microemulsifieation of Chlorinated Hydrocarbon/water with Mixed Surfactant Systems (혼합 계면활성제를 이용한 염소화 탄화수소l물의 마이크로에멀젼 연구)

  • 김천희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.22 no.3
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    • pp.365-373
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    • 1998
  • The phase behavior of chlorinated hydrocarbon/mixed surfactants/water microemulsion systems were investigated for dry cleaning solvent properties. With appropriate surfactant mixtures, Winsor type I-III-II microemulsions were generated which is the same as hydrocarbon systems. For perchloroethylene(PCE) with mixed Tween systems, the optimum salinity(S*) decreases and the optimum solubilization parameter(o*) increases with decreas- ing HLB. For PCE with mixed Aerosol MA and ethoxylated alcohol systems, S* and o* both increase with increasing ethylene oxide moles. For dichlorobenzene(DCB) with mixed Aerosol MA and ethoxylated or propoxylated sulfate systems, S* and o* both increase with increasing ethylene oxide moles or propylene oxide moles.

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An Experimental study on Analysis of Hydrocarbon of Exhaust gas Using Oxygenated Fuels by Gas Chromatography in Diesel Engine (디젤기관의 배기 배출물 중 가스 크로마토그래피를 이용한 탄화수소분석에 관한 실험적 연구)

  • Choi, S.H.;Oh, Y.T.
    • Journal of Power System Engineering
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    • v.4 no.3
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    • pp.12-18
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    • 2000
  • Recently, our world is faced with very serious and hard problems related to the air pollution due to the exhaust emissions of the diesel engine. So, lots of researchers have studied to reduce the exhaust emissions with various methods of diesel engine that influenced the environment strong. In this paper, the quantities of the low and high hydrocarbon among the exhaust emissions in diesel engine have been investigated by the quantitative analysis of the hydrocarbon $C_1{\sim}C_6$ using the gas chromatography. This study carried out by comparing the chromatogram with diesel fuel and three kinds of mixed fuels. One is the diesel fuel blended DGM(diethylene glycol dimethyl ether) 5%. Another is the diesel fuel blended DEE(diethyl ether) 25% and DMC(dimethyl carbonate) 10%. The results of this study show that the hydrocarbon $C_1{\sim}C_6$ among the exhaust emissions of the mixed fuels are exhausted lower than those of the diesel fuel at the all load and speed.

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Condensing heat transfer characteristics of hydrocarbon refrigerants in a horizontal tube (탄화수소 냉매의 수평 원관내 응축열전달 특성)

  • Jang, Yeong-Su;Kim, Min-Su;No, Seung-Tak
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.12
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    • pp.1656-1667
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    • 1997
  • Condensing heat transfer characteristics of hydrocarbon refrigerants are experimentally investigated. Single component hydrocarbon refrigerants (propane, isobutane, butane and propylene) and binary mixtures of propane/isobutane and propane/butane are considered as test fluids. Local condensing heat transfer coefficients of selected refrigerants are obtained from overall conductance measurement. Average heat transfer coefficients at different mass fluxes and heat transfer rates are shown and compared with those of R22. Pure hydrocarbon refrigerants have higher values of heat transfer coefficient than R22. It is also found that there is a heat transfer degradation for hydrocarbon mixtures due to composition variation during condensation. Measured condensing heat transfer coefficients are compared with predicted values by available correlations. An empirical correlation for pure and mixed hydrocarbon is developed, and it shows good agreement with experimental data.

An Experimental Study on the Analysis of Exhaust Gas Concentration by Using DMC in Diesel Engine (디젤엔진에서 DMC를 사용한 경우의 배기가스의 농도분석에 관한 실험적 연구)

  • 최승훈;오영택
    • Transactions of the Korean Society of Automotive Engineers
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    • v.8 no.2
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    • pp.1-8
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    • 2000
  • Recently, Our planet is faced with very serious problems related to the air pollution due to the exhaust emissions of the diesel engine. So, lots of researchers have studied to reduce the exhaust emissions of diesel engine that influenced the environment strong. But most researchers have mainly studied and suggested the solution of reduction on the total exhaust emissions of diesel engine. In this study, the quantities of the low and high hydrocarbon among the exhaust emissions in diesel engine have been investigated by the quantitative analysis of the hydrocarbon C1~C6 using the gas chromatography. This study carried out by comparing the chromatograms with diesel fuel and mixed fuel which are blended the diesel and DMC(dimethyl carbonate)that includes the oxygen of about 53%. The results of this study show that the hydrocarbon C1~C6 among the exhaust emissions of the mixed fuel are exhausted lower than those of the diesel fuel at the all load.

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The Experimental Study on Emission Reduction by Oxygenate Additive in D.I. Diesel Engine (직접분사식 디젤기관에서 함산소계 첨가에 의한 배출가스 저감에 관한 실험적 연구)

  • 최승훈;오영택
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.4
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    • pp.33-42
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    • 2002
  • Recently, our world is faced with very serious and hard problems related to the air pollution due to the exhaust emissions of the diesel engine. In this paper, the effect of oxygen component in fuel on the exhaust emissions has been investigated fur direct injection diesel engine. It was tested to estimate change of engine performance and exhaust emission characteristics for the commercial diesel fuel and oxygenate blended fuel which has three kinds of mixed ratio. And, it was tried to analyze not only total hydrocarbon but individual hydrocarbon components from Cl to C6 in exhaust gas using gas chromatography to seek the reason far remarkable reduction of smoke emission. This study was carried out by comparing the chromatogram with diesel fuel and diesel feel blended DGM(diethylene glycol dimethyl ether) 5%. The results of this study show that individual hydrocarbon(C1∼C6) as well as total hydrocarbon of oxygenated fuel is reduced remarkably than that of diesel fuel.

Properties of Sodium Dodecyl Sulfate / Triton X-100 Mixed Micelle

  • Park, Joon-Woo;Chung, Myung-Ae;Choi, Kyung-Moon
    • Bulletin of the Korean Chemical Society
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    • v.10 no.5
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    • pp.437-442
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    • 1989
  • The cmc's of sodium dodecyl sulfate (SDS)/Triton X-100 surfactant mixtures were determined by surface tension measurement at various surfactant compositions. The cmc values were lower than those predicted from ideal mixture. The regular solution theory was applied to calculate the interaction parameter, micellar composition, and the activity coefficients of surfactants in the mixed micelle. The interaction parameter (${\beta}$) was - 2.1. The nonideality arised largely from decreased activity of SDS in the mixed micelle. The mean aggregation numbers (${\bar{n}}$) and micropolarity of hydrocarbon region of the mixed micelles were determined by luminescence probe techniques. The total aggregation number (${\bar{n}}_{SDS}+{\bar{n}}_{TX}$) in mixed micelles showed little dependency on the composition of the micelle. The apparent dielectric constant of the hydrocarbon region of the micelle vs micellar composition plot showed positive deviation from linearity. Emission and emission quenching of excited tris(2,2'-bipyridine)ruthenium(Ⅱ) cation, $(Ru(bpy)_3^{2+})$, by methylviologen ($MV^{2+}$) were also investigated in the mixed micellar solutions. The quenching rate was lowest when the mole fraction of SDS in the surfactant mixtures (${\alpha}_{SDS}$) is about 0.25 and highest at ${\alpha}_{SDS}$ = 0.85. This was explained in terms of combined effects of binding of the cations with the micelle and mobility of the bound cations on the surface of the micelles.

A Study on Organic Solvent Exposure in Painting Operation of Automobile Manufacturing Industry (자동차 도장 작업장에서의 유기용제 폭로에 관한 연구)

  • 김영식
    • Journal of Environmental Health Sciences
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    • v.20 no.4
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    • pp.10-16
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    • 1994
  • A Study was performed in order to measure mixed organic solvent concentrations in air of painting operations during January 5-28, 1991. The mixed organic solvent concentrations were analyzed by the gas chromatography. The results were as follows: 1. The detection of organic solvent was highest in aromatic hydrocarbon(68%), and followed by aliphatic hydrocarbon (18%), and ketone (14%). 2. The detection of organic solvent by component category was highest in the grid class solvent (79.4%), and followed by the 3rd class solvent (20.6%). 3. Number of cases exceeding TLVS of mixed solvent level in air was highest on dipping operation (44%), and followed by spray operation (40%), dry and washing operation (33%), and adhensive operation (12%).

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이상추출배양을 통한 Botryococcu braunii에서의 탄화수소 생산

  • Sim, Sang-Jun;An, Jin-Yeong;Kim, Byeong-U
    • 한국생물공학회:학술대회논문집
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    • 2002.04a
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    • pp.112-115
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    • 2002
  • The green colonial algae Botryococcus braunii is characterized by unusual high hydrocarbon contents, ranging from 15 to 75% of dry weight, as long-chain unsaturated hydrocarbons. In two-phase bubble column using various organic solvents, poor recovery 08 - 32%) of hydrocarbon seems to be caused by insufficient mixing between two phases, which was operated using only aeration on the narrow interface between hydrophobic solvent and cell suspension. In addition, hydrocarbon was entrapped tightly in cell-matrix (formed by exopolysaccharide) of algal colony, which make difficult to extract using two-phase system. To improve recovery efficiency, mixed-solvent of extractive solvent (octane) and biocompatible solvent (octane) was tested in two-phase column for in situ extraction. In two-phase extraction culture using mixed-solvent, the algal growth was intensely inhibited even at low concentration of polar octanol solvent. the hydrocarbon recovery in two-stage cell-recycle extraction showed a 2.9 fold increase (57%) over that in two-phase extraction. Up to 60 % of hydrocarbon could be recovered without serious cell-damage in the case of downstream separation for 6 h at the high recycle flow rate using this process after batch culture.

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