• Title/Summary/Keyword: mixed heavy metal ions

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A study on the removal of mixed heavy metal ions using crab shell (게 껍질을 이용한 수중의 복합 중금속 제거에 관한 연구)

  • Kim, Dong-Seog
    • Journal of Environmental Science International
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    • v.11 no.7
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    • pp.729-735
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    • 2002
  • In order to examine the inhibition effect of other heavy metal ions on the removal of heavy metal ions by crab shell in aqueous solution, 10 heavy metal ions $(Cr^{3+},\;Cd^{2+},\;Ni^{2+},\;Zn^{2+},\;Hg^{2+},\;Cu^{2+},\;Mn^{2+],\;Fe^{2+},\;Fe^{3+},\;Pb^{2+})$ were used as single heavy metal ions and mixed heavy metal ions, respectively. In single heavy metal ions, $Pb^{2+},\;Cr^{3+},\;Cu^{2+}$ were well removed by crab shell, however, $Cd^{2+},\;Ni^{2+},\;Zn^{2+},\;Mn^{2+}$ were not. The heavy metal removal increased as the increase of covalent index (Xm$^2$r), and the relationship classified heavy metal ions as 2 heavy metal groups $(Fe^{3+},\;Fe^{2+},\;Cu^{2+},\; Cr^{3+},\;Mn^{2+},\;Ni^{2+},\;Zn^{2+}\;group\;and\;Pb^{2+},\;Hg^{2+},\;Cd^{2+}\;group)$. In mixed heavy metal ions, the removals of $Fe^{2+},\;Fe^{3+},\;Pb^{2+},\;Cu^{2+}$ as 0.49 m㏖/g, regardless of the existence of other heavy metal ions, were similar to the result of single heavy metal ions experiment. The removals of $Mn^{2+},\;Cd^{2+},\;Ni^{2+}$ decreased as the existence of other heavy metal ions, however, the removal of $Zn^{2+},\;Cr^{3+},\;Hg^{2+}$ increased.

Study on the Adsorption of Heavy Metal Ions by Biomaterials (생물질재료에 의한 중금속 흡착에 관한 연구)

  • 정석희;김상규;이민규
    • Journal of Environmental Science International
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    • v.2 no.4
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    • pp.357-365
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    • 1993
  • This study was conducted for the efficient utilization of biomaterials such as starch residue, tangerine skin, and green tea residue, which are agricultral by-products discarded in Cheju Province annually, as adsorbents and biomaterials were examined for their removal ability of heavy metal ions in waste water by batch adsorption experiments. The removal efficiency of biomaterials for heavy metal ions was above 80-90% and almost similar to activated carbon and the adsorption ability of those treated with 포르말린 was improved in the green tea residue only for $Pb^{2+}$, $Cu^{2+}$, and $Zn^{2+}$. In the conditions of pH, the removal efficiency of heavy metal ions was high in the range of 5-7. In the solutions which heavy metal ions were mixed, the removal efficiency was similar at $Ag^+$, $Pb^{+2}$ and reduced to about 10% at the other ions, as compared with the solutions they were not mixed. Adsorption isotherm of biomaterials was generally obeyed to Freundlich formular than Langmuir formular and Freundlich constant, 1/n were obtained in the range of 0.1-0.5.

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Biosorption of Heavy Metals by Saccharomyces uvarum (Saccharomyces uvarum에 의한 중금속 생체흡착에 관한 연구)

  • Ahn, Kab-Hwan;Suh, Kuen-Hack
    • Journal of Environmental Science International
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    • v.4 no.5
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    • pp.141-141
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    • 1995
  • The waste biomass of Sacchromyces uvarum, used in fermentation industries to produce ethanol, were studied for their ability to absorb various heavy metal ions. Heavy metal ions studied in this research were Cd, Co, Cr, Cu, Ni and Pb. The order of the sorption capacity was Pb>Cu>Co=Cr=Cd>Ni. The living Sacchromyces uvarum exhibited higher metal-uptake capacity than the dead Sacchromyces uvarum. After we compare the uptake capacity of the Sacchromyces uvarum for individual metal ions with for a mixture of them, the following was observed: in the mixed heavy metal solution the uptake capacity was decreased than the one heavy metal solution. The selective uptake was observed when all . the heavy metal ions were dissolved in a mixed solution. The adsorption isotherm modelling was decribed with the Langmuir and Freundlich model. The results were in good agreement with the Langmuir model.

Biosorption of Heavy Metals by Saccharomyces uvarum (Saccharomyces uvarum에 의한 중금속 생체흡착에 관한 연구)

  • 안갑환;서근학
    • Journal of Environmental Science International
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    • v.4 no.5
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    • pp.527-534
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    • 1995
  • The waste biomass of Sacchromyces uvarum, used in fermentation industries to produce ethanol, were studied for their ability to absorb various heavy metal ions. Heavy metal ions studied in this research were Cd, Co, Cr, Cu, Ni and Pb. The order of the sorption capacity was Pb>Cu>Co=Cr=Cd>Ni. The living Sacchromyces uvarum exhibited higher metal-uptake capacity than the dead Sacchromyces uvarum. After we compare the uptake capacity of the Sacchromyces uvarum for individual metal ions with for a mixture of them, the following was observed: in the mixed heavy metal solution the uptake capacity was decreased than the one heavy metal solution. The selective uptake was observed when all . the heavy metal ions were dissolved in a mixed solution. The adsorption isotherm modelling was decribed with the Langmuir and Freundlich model. The results were in good agreement with the Langmuir model.

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Removal of Divalent Heavy Metal Ions by Na-P1 Synthesized from Jeju Scoria (제주 스코리아로부터 합성된 Na-P1 제올라이트에 의한 2가 중금속 이온의 제거특성)

  • Kam, Sang-Kyu;Hyun, Sung-Su;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.20 no.10
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    • pp.1337-1345
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    • 2011
  • The removal performances of divalent heavy metal ions ($Pb^{2+}$, $Cu^{2+}$, $Cd^{2+}$, $Sr^{2+}$ and $Mn^{2+}$) were studied using the Na-P1 zeolite synthesized from Jeju scoria in the batch and continuous fixed column reactor. The uptakes of heavy metal ions by synthetic Na-P1 zeolite decreased in the order of $Pb^{2+}$ > $Cu2^{2+}$ > $Cd^{2+}$ > $Sr^{2+}$ > $Mn^{2+}$ based on the selectivity of each ion to ionic exchange site of Na-P1 zeolite for single and mixed solutions in batch or continuous fixed column reactor. For mixed solution, each heavy metal ion uptake was lower than that in single solution, and especially the uptake for $Mn^{2+}$ decreased greatly. In batch reactor, the uptakes of heavy metal ions by synthetic Na-P1 zeolite were described by Freundlich or Langmuir equation, but they followed the former better than the latter. In continuous fixed column reactor, the maximum ion exchange capacity obtained for each of heavy metal ions, was about 90----- of that in batch reactor. The uptakes of heavy metal ions by synthetic Na-P1 zeolite increased with the increase of initial heavy metal concentration and solution pH, and the decrease of the amount and particle size of synthetic zeolite.

The Solidification of the Heavy Metal Ion by Using DSP Cement (DSP 시멘트를 이용한 중금속 이온의 고화)

  • 소정섭;최상홀
    • Journal of the Korean Ceramic Society
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    • v.33 no.8
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    • pp.889-894
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    • 1996
  • This study was subjected to the stabilization of heavy metals using DSp cement. Heavy metal Cr and Pb ions were mixed with cement paste and hydration behavior and leaching property by heavy metal were exami-ned. It was found that, Cr ion accelerated the early hydration of the cement and has no accelerating effect in later hydration period. However Pb ion retarded the hydration of the cement for a early hydration periods. As a result of leaching test the quantity of leachant has a very low value and the influence of leached heavy metal effected on the environments is very weak.

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Leaching of Heavy Metal Ions in Mortar Using Municipal Waste Incinerator (소각재 사용 모르타르중의 중금속 이온 용출에 대한 연구)

  • Moon, Dae-Joong;Lim, Nam-Woong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.564-567
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    • 2004
  • FAs and BAs indicated different chemical compositions and physical properties. Leaching of Pb in FAl and Cu in FA2 were 33.2mg/L and 5.92mg/L, these were high concentration above 30 and 2 times respectively in compared to permit level. Leaching of Hg and Cr were about 1/2 of permit level. When diatom was complexly mixed with portland cement, the 28 days compressive strength of mortar with FA2 was similar with that of control mortar. Furtherfore, leaching of heavy metal ions like as Pb, Cu, Hg, Cr was highly reduced.

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Availability of Carboxylated Magnetic Beads for Extracting Heavy Metals from Aqueous Solution

  • So, Hyung-Suk;Yoo, Yeong-Seok;Schaeffer Andreas
    • Journal of Magnetics
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    • v.11 no.2
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    • pp.98-102
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    • 2006
  • It was examined in this study that magnetic beads, which are assumed to be environmentally functional, could be effective in processing heavy metals that are water pollutants. For the purpose, magnetic beads containing carboxyl groups, which has strong binding force with heavy metals, are mixed with each Cd, Pb, Ni, Cu and Cr(III) solution, then stirred in pH 6. As a results of the process, it was proven that heavy metals bind quickly with magnetic beads through the reaction. In order to analyze heavy metal concentration, magnetic beads bind with heavy metal were collected by external magnetic force and dissolved in acid. The graphite furnace AAS was used to get heavy metal concentration melted in the acid solution. The results showed that heavy metal extractions by magnetic beads were influenced by the type and the concentration of a heavy metal, and over 90% of a heavy metal can be extracted in ppm level save for Cr(III). It was also examined in the study whether heavy metal extraction is influenced when other ions exist in each heavy metal solution. According to experiment, adding other heavy metals to a solution did have little influence on extracting an intended heavy metal. But in case salt or heavy metal chelate was added, Ni extraction changed sensitively although extracting other heavy metals were influenced only when the concentration of an added substance is high. In conclusion, it was shown that magnetic beads could be used to treat wastewater with relatively high heavy metal concentration.

Heavy Metal Biosorption and its Significance to Metal Tolerance if Streptomycetes

  • Park, Jae-young;Kim, Jae-heon
    • Journal of Microbiology
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    • v.40 no.1
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    • pp.51-54
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    • 2002
  • Heavy metal adsorptions of four streptomycetes were compared with each other, Among the test strains, Streptomyces viridochromogenes showed the most efficient metal binding activity, which was carried out by cell wall as well as freeze-dried mycelium. An order of adsorption potential (zinc > copper > lead > cadmium) was observed in single metal reactions, whereas this adsorption order was disturbed in mixed-metal reactions. The metal adsorption reactions were very fast, pH dependent and culture age-independen, suggestive of a physico-chemical reaction between cell wall components and heavy metal ions. The metal tolerant stains presented the weakest adsorbing activity, indicating that the metal biosorption was not the basis of the metal tolerance.

Adsorption of Hg(I), Pb(II), and U(VI) ions using from Fruits of Schizandra Chinensis (오미자를 이용한 Hg(I), Pb(II), U(VI) 이온들의 흡착)

  • Kim, Kwan-Chun;Kim, Joon-Tae
    • Journal of environmental and Sanitary engineering
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    • v.22 no.1 s.63
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    • pp.29-35
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    • 2007
  • This study was examined adsorption ability of heavy metal Hg(I), Pb(II), and U(Vl) ion use of fruit from schizandra chinensis, The fruits of schizandra chinensis sample used breaking into fragments $50{\sim}100$ mesh. The sample solution was mixed fruits of schizandra chinensis and heavy metal ion. Each heavy metal ion of into solution was quantum analysis with ICP-AES. As the result, each condition of maxium adsorption ability of heavy metal ion was high in the range of pH 5-7, adsorption time was about 15 minutes, and the optimum temperature was $100^{\circ}C$. The heavy metal ion was increased adsorption in order of increasing concentration and in ethanol solution better than in aqueous solution.