• 한국가스학회지
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• 제27권3호
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• pp.59-71
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• 2023

온실가스 감축과 탄소 중립의 실현을 위해서 탄소의 포집, 저장(carbon capture, and storage, CCS) 기술은 매우 중요하다. CCS는 CO₂ 저장을 중점적으로 함으로써, 포획된 CO₂를 지하 저류층 내부에 영구적으로 보관하는 역할을 한다. CO₂--EOR(enhanced oil recovery)은 CCS의 한 형태로, 오일 회수 촉진을 위해 CO₂를 지하 내부로 주입시켜 잔류 오일 회수에 도움을 줄 뿐만 아니라 CO₂가 지하에 저장되어 탄소 중립에도 기여하는 기술이다. 이 CO₂-EOR은 혼화공법과 비혼화공법으로 분류하며 혼화공법의 대표적인 방식인 CO₂-WAG(water alternating gas)는 물과 CO₂를 저류층 내부에 교대로 주입하여 오일을 생산하고 CO₂를 저장하는 공법이다. WAG 방식은 주입 유체의 돌파를 조절할 수 있어 오일 회수에 유리한 특징을 보이며, 흡입과 배출 과정 중에 상대투과도의 이력현상을 유도해 CO₂의 잔류 격리량을 확대할 수 있다. 본 연구에서는 CO₂-EOR 과정에서의 석유회수증진 효과와 CO₂가 지중에 저장되는 메커니즘을 설명하였으며, CCS와 연계한 CO₂-EOR 적용 사례를 소개하였다.

• Macromolecular Research
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• 제8권1호
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• pp.34-43
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• 2000

The melt rheology of four binary blends of ethylene 1-octene copolymers (EOCs) which consist of one component by Ziegler-Natta and another by metallocene catalysts, was studied to elucidate miscibility in the melt by using torsion rheometer at 200$\^{C}$ and different shear rates. The four blend systems, designated into the FA+FM, SF+FM, RF+EN, and RF+PL blend, are divided and interpreted based on the melt index (MI), the density and the comonomer contents. The melt viscosity such asη', η", and η$\^$*/ is weight average value if the comonomer contents are similar, otherwise they show different manner. The experimental resole are analyzed based on the Cole-Cole plot of logη' uersus log η", the logarithmic plots of the dynamic storage modulus (G') versus the dynamic loss modulus (G") for various blend compositions, and the melt viscosity of 11', n", and f" as a function of blend compositions. As a cerise-quence, the FA+FM blend is miscible, but the SF+FM, RF+EN, and RF+PL blends are not in the melt. Thus miscibility of the blends studied in this communication is suggested to strongly influence by the comonomer contents rather than the density or the MI.

• 한국막학회:학술대회논문집
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• 한국막학회 1996년도 춘계 총회 및 학술발표회
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• pp.55-56
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• 1996

Heterophase polymer system has been attractive for a potential applicability to gas separation membrane material. It has been known that there is a trade-off between gas permeability and its selectivity in common polymers. Therefore, the heterophase polymer can be an alternative for a gas separation membrane material because its transport properties can be readily controlled by blending of two different polymers. The transport properties of immiscible polymer blends strongly depend upon the intrinsic transport properties of corresponding polymers. Another important factor to determine the transport properties is their morphology: volume fraction, size and shape of dispersed phase. Although the effect of the volume fraction of the dispersed phase on the transport properties has been widely investigated, the size and shape effects have been paid attention very much. In an immiscible polymer blend of two polymers, its morphology is primarily controlled by its volume fraction of dispersed phase. Therefore, the effect of the size of the dispersed phase can be hardly seen. Therefore, a block copolymer has been commonly employed to control their morphology when each block is miscible with one or the other phase. In this work, gas transport properties will be measured by varying the morphology of the heterophase polymer membrane. The transport properties will be interpreted in terms of their morphology. The effect of the volume fraction of the PI phase and, in particular, its size effect will be investigated experimentally and theoretically.

• Bulletin of the Korean Chemical Society
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• 제26권5호
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• pp.781-785
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• 2005

A fast and reliable method for the selective separation and preconcentration of $Cu^{2+}$ ions using homogeneous liquid-liquid extraction was developed. A new $\alpha$-dioxime derivative (2H-1,4-benzothioazine-2,3(4H)dionedioxime, Dioxime I) was synthesized and investigated as a suitable selective complexing ligand for $Cu^{2+}$ ions. Zonyl FSA (FSA) was applied as a phase-separator agent under the slightly acidic pH conditions. Under the optimal experimental conditions ([FSA] = 3.2% w/v, [THF] = 19.5% v/v, [Dioxime I] = 1.9 ${\times}\;10^{-3}$ M, and pH = 4.7), 10 ${\mu}g\;of\;Cu^{2+}$ in 5.2 mL aqueous phase could be extracted quantitatively into 80 $\mu$L of the sedimented phase. The maximum concentration factor was 65-fold. The limit of detection of the proposed method was 0.005 ng $mL^{-1}$. The reproducibility of the proposed method, on the 10 replicate measurements, was 1.3%. The influence of the pH, type and volume of the water-miscible organic solvent, concentration of FSA, concentration of the complexing ligand and the effect of different diverse ions on the extraction and determination of $Cu^{2+}$ ions were investigated. The proposed method was applied to the extraction and determination of $Cu^{2+}$ ion in different synthetic and natural water samples.

• 폴리머
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• 제24권4호
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• pp.477-487
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• 2000

Poly(L-lactic acid) (PLLA)/poly($\beta$-hydroxynonanoate) (PHN) 블렌드의 흔화도와 결정화거동을 연구하기 위해 여러 중량 흔합비의 시료를 제조하였다. DSC, XRD 및 편광현미경을 이용하여 PLLA/PHN 블렌드의 열적 성질 및 특성을 연구하였다. PLLA와 PHN은 무정형 영역에서 부분적인 상용성을 가졌으며 PLLA의 결정화도는 PHN이 첨가됨으로 인하여 증가되었다. 그리고 PHN이 첨가됨으로써 PLLA의 T$_{g}$, T$_{c}$, T$_{m}$ 의 이동이 있었다. 편광현미경 분석을 통하여 PLLA 구정의 수는 PHN이 증가할수록 증가하는 것을 알 수 있었다. 이로부터 PHN은 PLLA에 대하여 기핵제의 역할이 있음이 관찰되었다.

• 한국안전학회지
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• 제29권6호
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• pp.76-80
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• 2014

The flash point is one of the most important physical properties used to determine the fire hazard of flammable liquid mixture and defined as the lowest temperature at which a liquid produces sufficient vapor to form a combustible mixture with air. The main purpose of this paper is to measure and predict the flash point of binary flammable miscible mixtures. The flash points for n-hexanol+n-butyric acid and n-butanol+propionic acid, were measured by using Seta-flash closed cup method. The experimentally derived data were correlated with the binary interaction parameters of the van Laar and NRTL equations through the optimization method. The flash points estimated by these correlations were compared with those calculated by the method based on Raoult's law. The optimization method were found to be better than the method based on the Raoult's law.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2005년도 제31회 KOSCO SYMPOSIUM 논문집
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• pp.120-131
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• 2005

The evaporation characteristics of single and multicomponent droplets hanging at the tip of a quartz fiber are studied experimentally at the different environmental conditions under normal gravity. Heptane and Hexadecane are selected as two fuels with different evaporation rates and boiling temperatures. At the first step, the evaporation of single component droplet of both fuels has been examined separately. At the next step the evaporation of several blends of these two fuels, as a binary component droplet, has been studied. The temperature and pressure range is selected between 400 and 700 $^{\circ}C$, and 0.1 and 2.5 MPa, respectively. High temperature environment has been provided by a falling electrical furnace. The initial diameter of droplet was in range of 1.1 and 1.3 mm. The evaporation process was recorded by a high speed CCD camera. The results of binary droplet evaporation show the three staged evaporation. In the the first stage the more volatile component evaporates. The droplet temperature rises after an almost non evaporating period and in the third stage a quasi linear evaporation takes place. The evaporation of the binary droplet at low pressure is accompanied with bubble formation and droplet fragmentation and leads to incomplete microexplosion. The component concentration affects the evaporation behavior of the first two stages. The bubble formation and droplet distortion does not appear at high environment pressure. Nomenclature

• Macromolecular Research
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• 제10권2호
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• pp.91-96
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• 2002

To explore the effects of intramolecular interactions within the copolymer on the phase separation behavior of polymer blends, copolymers having two different types of intramolecular interactions, i.e., intramolecular repulsion and intramolecular attraction were prepared . In this study, poly(styrene-co-methylmethacrylate) (P(S-MMA)) having intramolecular repulsion caused by positive interaction between styrene and MMA and poly(styrene-co-ethyl-methacrylate) (P(S-EMA)) and poly(styrene-co-cyclohexylmethacrylate) (P(S-CHMA)) having intramolecular attraction caused by negative interaction between styrene and methacrylate were blended with tetramethyl poly-carbonate (TMPC). The phase behavior of blends was examined as a function of copolymer composition and blend composition. TMPC formed miscible blends with styrenic copolymers containing less than certain amount of methacrylate. The phase separation temperature of TMPC blends with copolymer such as P(S-MMA) and P(S-EMA), first increases with methacrylate content, goes through a maximum and then decreases just prior to the limiting content of methacrylate for miscibility, while that of TMPC blends with P(S-CHMA) always decreases. The calculated interaction energy for TMPC-P(S-EMA) pair is negative and monotonically increases with EMA content of the copolymer. Such behavior contradicted the general notion that systems with more favorable energetic interactions have higher LCST, The detailed inspection of the lattice-fluid theory related to the phase behavior was performed to explain such behavior.

• 한국환경과학회지
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• 제19권9호
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• pp.1161-1167
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• 2010

The effects of addition of non degradable polymers, polystyrene (PS) and poly(methyl methacrylate) (PMMA) on the rate of enzymatic degradation of biodegradable poly(l-lactide) (PLLA) have been studied in term of surface structure. Since a component in multicomponent polymeric system has shown surface enrichment, PS and PMMA which have lower surface energy than PLLA were selected as a minor blend component (5 wt%). Enzymatic degradation was carried out at $37^{\circ}C$ and pH 8.5 in the aqueous solution of Proteinase K. Two blend systems, partially miscible (PS/PLLA) and immiscible (PMMA/PLLA), showed the surface enrichment of 4 and 2 times of PS and PMMA, respectively. From the weight loss profile data, the slow degradation rate of both blend films was observed. This indicates that PS or PMMA domains which exist at surface act as a retardant of enzymatic attack.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 하계학술대회 논문집 C
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• pp.1498-1501
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• 1996

To evaluate insulating properties of polyimide thin film on high temperature over $100\;^{\circ}C$, polyimide film were prepared by electrophoretic deposition onto metal surface from nonaqueous emulsion. The emulsion is made by adding a solution of the resin to a precipitant, which is an organic liquid compeltely miscible with the solvent of the organic resin solution, but which does not dissolve the resin. The polyimide film obtained by annealing shows good insulation properties of 5.8 MV/cm at elevated temperature and breakdown strength of the film reveals thickness dependence.