• Title/Summary/Keyword: mineral mixtures

Search Result 127, Processing Time 0.027 seconds

Thermodynamic Evaluation of Fe Effect on Alumina Solubility in Orthopyroxene coexisting with Garnet

  • Lee, Han-Yeang
    • Journal of the Korean earth science society
    • /
    • v.25 no.1
    • /
    • pp.39-47
    • /
    • 2004
  • In the FMAS system the effect of iron on alumina solubility in orthopyroxene has been determined by experiments with crystalline starting mixtures of garnet and orthopyroxene of known initial compositions at 20 kb, 975$^{\circ}C$ and 25 kb, 1,200$^{\circ}C$. These data have been modeled to develop a thermodynamic method for the calculation of Al$_{2}$O$_{3}$ in orthopyroxene as a function of P, T and composition. The direct application of the alumina solubility data in the MAS system to natural assemblages could lead to significant overestimation of pressure, probably by about 5kb for the relatively common garnet-lherzolites with abot 25 mol per cent Ca + Fe$^{2+}$ in garnet and about 1 wt. per cent Al$_{2}$O$_{3}$ in orthopyroxene since the effect of Fe is similar to that of Ca and Cr$^{3+}$in reducing the alumina solubility in orthopyroxene in equilibrum with garnet relative to that in the MAS system.

The New Calculation Model of Film Thickness to Evaluat Asphalt Mixtures (아스팔트혼합물을 평가하기 위한 유효아스팔트 함량의 새로운 계산 모델)

  • Kim, Sung-Ho;Kim, Boo-Il
    • International Journal of Highway Engineering
    • /
    • v.9 no.1 s.31
    • /
    • pp.57-67
    • /
    • 2007
  • Many researches have recently discussed about the film thickness as a good substitute or supplement for VMA or other volumetric criteria in the design procedure. Some researchers have not only proposed the specific number for the recommended film thickness, but also introduced the new calculation procedures or concepts. Each model (index model and the virtual model) has its own advantages and disadvantages in terms of the ability to account for the volumetric properties of the mixture. In this paper, the modified virtual model was proposed to combine advantages from both models. However, it cannot be disregarded the way to determine the appropriate particle shape factors for different sources and sizes of aggregates. In order to evaluate the different calculation methods, mixtures with two aggregate sources and eight gradations were designed based on the dominant aggregate size range (DASR) porosity concept. Superpave indirect tensile test (IDT) and asphalt pavement analyzer (AEA) test were used to describe the performance of mixtures. Test results indicated that the virtual model, which is the same to the modified virtual model for sphere 1:1 case, is better than the conventional standard model to define the range of the film thickness to have better performance of asphalt mixtures.

  • PDF

Synergic Effects of Mixed Formula Consisted of Polycan and Calcium-gluconate on the Experimental Periodontitis and Alveolar Bone Loss in Rats

  • Lee, Won-Ho;Kim, Kyung Hu;Kang, Su Jin;Lee, Young Joon;Ku, Sae Kwang
    • Journal of Society of Preventive Korean Medicine
    • /
    • v.18 no.1
    • /
    • pp.125-138
    • /
    • 2014
  • Objective : Polycan, exopolymers purified from Aureobasidium pullulans SM-2001 and calcium gluconate have been showed favorable inhibitory effects on the periodontitis and related alveolar bone losses through antioxidant and anti-inflammatory activities, respectively. In the present study, we intended to observe the possible synergic effects of mixed formula consisted of Polycan and calcium gluconate on ligation-induced experimental periodontitis and related alveolar bone losses in rats, and to select the fittest compositions for further developing as effective agents to ameliorate periodontal diseases. Method : Experiments were conducted as two separated two tests - first is synergic effects of Polycan and calcium gluconate 1:1, 1:9 and 9:1 mixtures, and second is 1:99, 2:98, 4:96, 8:92 and 1:9 mixtures. Experimental periodontal diseases were induced by ligature placed around the cervix of upper left incisior teeth of rats. One day after ligation placements, 200mg/kg of each single or mixed formulas of Polycan or/and calcium gluconate were orally administered for 10 days. The changes on the alveolar bone loss index and maxillary bone mineral density (BMD) were observed for detecting alveolar bone losses, and for anti-inflammatory effects, myeloperoxidase (MPO) activities and proinflammatory cytokine (tumor necrosis factor; TNF-${\alpha}$) contents were also evaluated in gingival tissues around ligature placed incisior teeth. The results of mixtures were compared with those of singe Polycan and calcium gluconate treated rat. Results : Each single or mixed formulas of Polycan or/and calcium gluconate favorably and significantly inhibited the inflammatory changes. The inhibitory effects of mixed formula consisted of Polycan and calcium gluconate 1:9 showed against periodontitis and related alveolar bone losses as compared with those of each Polycan and calcium gluconate single formula (p<0.05). In second experiment, Polycan and calcium gluconate 2:98, 4:96, 8:92 and 1:9 mixed formulas also showed significant increased anti-inflammatory and inhibitory effects against alveolar bone losses as compared with those of each single formula. Among them, Polycan and calcium gluconate 2:98 showed the highest efficacy against to ligation-induced experimental periodontitis and related alveolar bone losses. Conclusion : The results obtained in this study suggest that appropriated mixtures of Polycan and calcium gluconate showed synergic inhibitory effects against ligation-induced experimental periodontitis and related alveolar bone losses in rats. Moreover, Polycan and calcium gluconate 2:98 showed the highest efficacies in this experiment, suggesting the fittest composition for further developing as effective agents to ameliorate periodontal diseases.

Manufacture of Ordinary Portland Cement Clinker Using Cement Paste of the Waste Concrete (폐콘크리트로부터 회수된 시멘트 페이스트 미분말의 시멘트 원료화 연구)

  • Ahn, Ji-Whan;Kim, Hyung-Seok;Cho, Jin-,Sang;Han, Gi-Chun;Han, Ki-Suk;Kim, Hwan
    • Journal of the Korean Ceramic Society
    • /
    • v.40 no.8
    • /
    • pp.804-810
    • /
    • 2003
  • The fine powder produced by heating and grinding of the waste concrete in the waste construction was investigated whether utilize as substitution raw material of SiO$_2$, CaO, and Al$_2$O$_3$ source for OPC clinker manufacture is possible or not. In order to synthesize OPC clinker, limestone, shale, converter slag and fly ash were used as main raw materials, and modulus was fixed LSF 91.0, SM 2.60, IM 1.60. The synthesized clinkers were characterized. The Main products of synthesized clinker were C$_3$S, ${\beta}$-C$_2$S, C$_3$A, C$_4$AF as OPC clinker at 1,43$^{\circ}C$. As a result of TG-DTA and burnability index(B.U) analysis of each raw mixtures, the formation temperature of clinker phases was similar and B.I was showed easy burning as 48.6∼51.4.

Spectmscopic and Magnetic Properties of Yanggiseok, Yeonok and Eumgiseok used as Mineral Medicine (광물성 한약으로 이용되는 양기석, 연옥,음기석의 분광학적 및 자기적 특성)

  • 김선옥;박맹언;정율필
    • Economic and Environmental Geology
    • /
    • v.35 no.4
    • /
    • pp.317-323
    • /
    • 2002
  • Mineral medicines are single or mixtures of minerals and rocks which have been used to treat disease. Recently, their application has been increased by emphasizing the physical properies of the medicines, in addition to their chemical properies. In this study, mineralogical, chemical, spectroscopic and magnetic properties were measured using X-ray diffraction analysis, X-ray fluorescence spectrometry, Ff-Infrared spectroscopy, nuclear magnetic resonance spectroscopy, mass magnetic susceptibility. Experiments were done using these properties to evaluate application of traditional mineral medicines such as Yanggiseok, Yeonok and Eumgiseok. Mineralogical study proves that Yanggiseok, generally known as tremolite, consists of actinolite. Yeonok for medical usage mostly consists of fine grained tremolite. Eumgiseok is mainly composed of vermiculite and minor kaolinite and halloysite. Yeonok and Yanggiseok, belong to the amphibole group among inosilicates and both have similar emission power properties. The intensity of emission power, calculated from FT-IR measurements, follows in the order of Yeonok, Yanggiseok and Eumgiseok at 40$^{\circ}$C and Yanggiseok, Yeonok and Eumgiseok in such order at 150$^{\circ}$C. As a result of NMR analysis after 20 days in distilled water, the three mineral medicines decreased in the following order; Eumgiseok, Yanggiseok and Yeonok. However, the same minerals decreased in the order of Eumgiseok, Yeonok and Yanggiseok after 80 days. In response temperature, magnetic susceptibility of Yanggiseok and Eumgiseok systematically increased by heating to 25$^{\circ}$C, 100$^{\circ}$C and 700$^{\circ}$C. Magnetic susceptibility of Yeonok shows a decreasing pattern due to heating.

Activation Property of Blast furnace Slag by Alkaline Activator (알칼리 자극제에 의한 고로수쇄슬래그의 활성화 특성)

  • Ahn, Ji-Whan;Cho, Jin-Sang;Kim, Hyung-Seok;Han, Gi-Chun;Han, Ki-Suk;Kim, Hwan
    • Journal of the Korean Ceramic Society
    • /
    • v.40 no.10
    • /
    • pp.1005-1014
    • /
    • 2003
  • This paper examines the hydration and physical properties of alkali-blast furnace slag cement activated by Na$_2$SiO$_3$, Na$_2$CO$_3$, NaOH, Na$_2$SO$_4$. Four levels of Na$_2$O content in mixtures, 1, 3, 5, and 7 wt%, were investigated, and a W/S ratio 0.5 was used to prepare paste and mortar specimens. Compressive strength measurement of mortars was carried out adding alkali activated slag 30 wt% to OPC. The main hydration products with alkali activator kinds were C-S-H,C$_4$AH$\_$13/, AFt and Al(OH)$_3$ etc. For using Na$_2$CO$_3$ activated slag, hydration ratio of slag was higher than that of different activators, and Na$_2$SO$_4$ activated slag mortar appeared the highest compressive strength values at 28 days with activator content of 5 and 7 wt%.

An Experimental Study for Improving the Durability of Concrete Bridge Decks (교량 바닥판 콘크리트의 내구성 증진을 위한 실험적 연구)

  • Suh, Jin-Won;Rhee, Ji-Young;Ku, Bon-Sung;Shin, Do-Chul
    • Journal of the Korea Concrete Institute
    • /
    • v.19 no.4
    • /
    • pp.393-399
    • /
    • 2007
  • Concrete bridge decks are directly exposed to the severe environmental conditions such as rain water and deicing chemicals resulting in the freeze-thaw action and the rebar corrosion during their service lift. These deteriorations of bridge decks shorten the service lift and consequently they are the major concerns of the maintenance. The high performance concrete (HPC) deck is proposed as the alternative to minimize the deterioration problems. To develop more durable concrete deck, the performance characteristic tests of HPC mixtures were carried out. In this study, 4 different concrete mixtures were used varying the mineral admixtures as the cement replacement; ordinary portland cement (OPC), 20% fly ash (FA),20% fly ash with 4% silica fume (FS), and 40% ground granulated blast-furnace slag (BS). The design compressive strengths of HPC specimens were 27 MPa and 35 MPa, respectively. The results showed that the compressive strength of concrete did not much affect the durability of concrete. HPC with fly ash and silica lune (FS) were turned out to have the good durability and crack resistance.

Environmental Effect of the Reduced Slag in the Electric Furnace (전기로 제강 환원슬래그 혼합토의 환경적 영향)

  • Na, Hyunsu;Yoon, Yeowon;Yoon, Gillim
    • Journal of the Korean GEO-environmental Society
    • /
    • v.12 no.7
    • /
    • pp.23-29
    • /
    • 2011
  • The oxidation slag has been widely used in civil engineering project, whereas the reduced slag from electric furnace has yet to be applied. Consequently in order to find out the recycling method in civil engineering field, the mineral compositions of the reduced slag were analyzed and some tests on water quality were performed to estimate the potential release of toxic compounds. Slag-soil mixtures of 0, 10, 20 and 30%(dry weight) soil were prepared in lysimeter columns and the effluents were collected with the period of one, two and four week options in closed system, respectively. The result from qualitative and quantitative analysis using X-ray Diffraction(XRD) and X-ray Fluorescence(XRF) indicates that the main mineral of the reduced slag is $Ca_2(SiO_4)$, a kind of calcium silicate. Also, the leaching medium analyzed by Inductively Coupled Plasma Optical Emission Spectroscopy(ICP-OES) showed that main heavy metals such as Al, Fe and Mn are included in the reduced slag due to the effect of steel production process. It can be seen that the leachate does not violate the regulation guide line of waste material of heavy metal. Also the pH levels were increased from pH 6.9 for 0% soil to pH 10 for 30% soil. However the influence on leachate circulation period of one through four weeks was negligible.

A Experimental Study on the Seawater Attack Resistance of Grouting Mixtures (내해수성 주입재 배합에 관한 실험적 연구)

  • Chun, Byungsik;Choi, Dongchan;Kim, Younghun;Kim, Jinchun
    • Journal of the Korean GEO-environmental Society
    • /
    • v.11 no.1
    • /
    • pp.53-59
    • /
    • 2010
  • In seawater deposition condition, the corrosion and chemical attack of grouts are similar to those of concrete structure. Used in domestic MSG (Micro Silica Grouting) mixtured large amounts of silicate materials containing as cement powder is $8,000cm^2/g$ of the specific surface area or more due to the high hydration activity and high-strength, high durability, and features, $C_3A$ content of less than 5% to meet the standards chemical attack of seawater was evaluated as a cement material. Therefore, in this paper, with excellent seawater attack resistant MSG in combination with rapid hardening mineral was used, those of seawater characteristics were evaluated experimentally. Typically, sodium-silicate minerals or rapid hardening cements are used in domestic. About the homogel specimens with combination of MSG and rapid hardening agents for compressive strength, weight and length change characteristics were evaluated experimentally, and so we could present the excellent seawater resistant grouts combination.

Control Efficiency for Ginseng Anthracnose by Eco-Friendly Organic Materials (유기농업자재를 이용한 인삼 탄저병의 친환경 방제효과)

  • Kim, Woo Sik;Park, Jee Sung;Ahn, In;Park, Kyung Hoon;Kim, Ki Hong
    • Korean Journal of Medicinal Crop Science
    • /
    • v.22 no.4
    • /
    • pp.270-275
    • /
    • 2014
  • This study was conducted to select and develop effect of eco-friendly organic materials for the eco-friendly prevention of Anthracnose occurred in the ginseng. Anthracnose on ginseng is occurred by Colletotrichum gloeosporioides and the crop damage is severe especially from July to August after rainy season. The test results showed that control effect by test products materials on the three years ginseng and four years ginseng field was lower in eco-friendly organic materials than that of chemical pesticide. However, the control effect of bordeaux mixture was higher with 71.3% and 73.8% levels than those of mineral matter, microbial agent, and developed plants extract mixtures (Eugenol, Curcumin, Wood vinegar, etc). On the other hand, three types of developed plants extract mixtures (3 types) showed control effect in a range of from 58.1% to 63.6% against Anthracnose which was higher as compared with plant extract alone and sodium silicate regardless of ages of ginseng. The results of this study would attribute in verifying the control effect of eco-friendly materials against Anthracnose for ginseng through investigating antimicrobial compounds contained in the plants body. Also, it would be used as control method against Anthracnose occurred in ginseng by judging the right control time through monitoring occurrence of disease.