• Title/Summary/Keyword: mineral leakage

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Analysis of Development Trends on Bio-based Environmental Transformers Oils in Power Sector (전력분야의 바이오 기반 친환경 전기 절연유 적용에 관한 개발 동향 분석)

  • Kim, Jae-Kon;Min, YoungJe;Kim, Mock-Yeon;Kwark, ByeongSub;Park, Hyunjoo
    • Tribology and Lubricants
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    • v.38 no.2
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    • pp.41-52
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    • 2022
  • Mineral electrical insulating oil, which is widely used in transformers, exhibits excellent cooling performance and transformer efficiency. However, given that it is composed of petroleum-based components, it is weak in terms of biodegradability. This causes environmental problems in case of leakage and a low flash point, which is a factor that would cause great damage in the event of a fire in a substation. In this context, the use of eco-friendly electric insulating oil composed of bio-based vegetable oil and synthetic ester, which has excellent biodegradability and flame retardancy performance, has recently been expanded to the field of electric power, and various research and development (R&D) studies are in progress. According to different research results, vegetable oil and synthetic ester manufacturing technology, thermal stability, oxidation stability, property change, and quality control, which are characteristics of eco-friendly electrical insulating oils, are major factors affecting the maintenance of insulating oil properties. In addition, power companies have established and operated quality control standards according to the use of eco-friendly electrical insulating oil as they expand the exploitatoin of renewable energy in electricity production. In particular, deterioration and oxidation characteristics were jointly identified in R&D as an important influencing factor according to the content of saturated and unsaturated fatty acids present in vegetable oils and synthetic esters in power transformer applications.

Evaluation of Sealing Effect and Working Time of Root Canal Filling MTA Materials (근관 충전용 MTA의 밀폐 효과와 작업 시간 평가)

  • Kim, Hyojin;Kim, Youngjin;Nam, Soonhyeun;Kwon, Taeyub;Kim, Hyunjung
    • Journal of the korean academy of Pediatric Dentistry
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    • v.43 no.2
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    • pp.129-136
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    • 2016
  • The purpose of this study is to examine the sealing effect and efficiency of root canal filling MTA (Endoseal, Endoseal MTA). A total of 106 extracted single rooted teeth were used and classified with group AH (AH-26), group PR (ProRoot MTA), group ES (Endoseal) and group EM (Endoseal MTA) depending on filled sealers. Time was measured in each group when sealers were filled. The groups were divided into subgroup A and subgroup B. The sealing of root canal walls and penetration of sealer in the dentinal tubule were evaluated, respectively. According to the results, the sealing of root canal walls and dentinal tubule penetration of root canal filling MTA were inferior to AH-26 (p < 0.05). When compared with ProRoot MTA, however, there was no significant difference in sealing of root canal walls (p > 0.05), but dentinal tubule penetration was high (p < 0.05). Working time was shorter in root canal filling MTA than ProRoot MTA and AH-26 (p < 0.05). In conclusion, root canal filling MTA has lower root canal sealing effect than resin-based sealer, however, when in MTA needed root canal filling, it could be an effective alternative.

Effect of Turbid Water on Fishes in the Streams of Imha Reservoir (임하호 유입지천에 서식하는 어류에 미치는 탁수의 영향)

  • Yu, Sam-Hwan;Kim, Jeong-Sook;Shin, Myung-Ja;Lee, Jong-Eun;Seo, Eul-Won
    • Journal of Life Science
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    • v.19 no.10
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    • pp.1410-1416
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    • 2009
  • The present study aims to examine the effect of turbid water on fishes in streams which branch into a turbid water area (Yeongyang-gun) and a non-turbid water area (Cheongsong-gun), and finally flow into the Imha reservoir. In a comparison of water quality, the chemical status of the water showed higher pH, DO and SS in the turbid water area than in the non-turbid water area. Also, high density of clay minerals such as vermiculite (V) and illite (I), which is from clay mineral leakage during rainfall, was detected in turbid water, resulting in an increase of turbidity. Fishes inhabiting the turbid water showed irregular spaces in gill lamella, cell separation, edema, and clubbing in epithelial tissues. Also, the gill surface showed roughness and plenty of muddy debris substances inside the gills. The Bowman's space was expanded because of contraction of the glomerulus in the Bowman's space of the kidney tissues. Antioxidant enzymes such as SOD, CAT, GPX, and GST showed higher activities in the specific tissues, muscles and kidney, of fishes living in turbid water than in the non-turbid area. We suggested that; first, the antioxidant activities were increased due to removal of harmful radicals generated in fish bodies in the turbid water area, second, long-time exposure of these histological changes in the tissues might have induced secondary lesion accompanying the inaccurate physiological constancy of fishes.

Assessment of Hydrogeochemical Characteristics and Contaminant Dispersion of Aquifer around Keumsan Municipal Landfill (금산 매립장 주변 대수층의 수리지화학적 특성 및 오염 확산 평가)

  • Oh, In-Suk;Ko, Kyung-Seok;Kong, In-Chul;Ku, Min-Ho
    • Economic and Environmental Geology
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    • v.41 no.6
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    • pp.657-672
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    • 2008
  • The purposes of this study are to investigate the hydrogeochemical characteristics of groundwaters around Keumsan municipal landfill, and to evaluate the contaminant dispersion from the landfill and its environmental impact. To achieve these goals, groundwater quality logging, hydrochemical analysis, multivariate statistical analysis, and contaminant transport modeling were performed. The water quality logging indicated a leaking from the landfill at the depth of 4-12m around a leachate sump. Electrical conductivity data indicated that groundwaters within 70-100m from landfill were affected by the landfill leakage. Principal components 1 and 2 obtained from principal components analysis (PCA) reflect the influence of leachate and the characteristics of aquifer media, respectively. The results of principal component analysis also indicated the natural attenuation processes such as cation exchange, sorption, and microbial biodegradation. The modeling results showed that groundwater flow westward along a valley from the landfill and contaminants transport accordingly.

Application of Cyber Physical System (CPS) for Risk Management of a CO2 Storage Site (이산화탄소 저장부지 위해성 관리를 위한 가상물리시스템 적용성 평가)

  • Jeong, Jina;Park, Eungyu;Jun, Seong-Chun;Kim, Hyun-Jun;Yun, Seong-Taek
    • Economic and Environmental Geology
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    • v.50 no.5
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    • pp.363-373
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    • 2017
  • In the present study, adaptability of cyber-physical system (CPS) for risk management of $CO_2$ storage site is examined and the subagging regression (SBR) method is proposed as a key component of the cyber-twin to estimate the risk due to potential $CO_2$ leakage. For these purposes, $CO_2$ concentration data monitored from a controlled $CO_2$ release field experiment is employed to validate the potentialities of the SBR method. From the validation study, it is found that the SBR method has robust estimation capability by showing minimal influence from anomalous measurements, and makes stable and sound predictions for the forthcoming $CO_2$ concentration trend. In addition, the method is found to be well suited as a tool of operational risk assessment based on real-time monitoring data due to the computational efficiency. The overall results suggest that the SBR method has potential to be an important component comprising the cyber twin of CPS for risk management of $CO_2$ storage site.

Evaluation on the Basic Properties of Phosphate Modified Portland Cement Paste for Potential Application of Geologic CO2 Sequestration (이산화탄소 지중 격리용 인산염 혼입 시멘트 페이스트에 관한 기초물성 평가)

  • Yoon, Ju-Han;Kim, Seong-Geun;Kim, Ji-Hyun;Lee, Jae-Yong;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.3
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    • pp.253-260
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    • 2017
  • As global warming became a worldwide issue, a significant effort has been made on the development of technology related to $CO_2$ capture and storage. Geologic sequestration of $CO_2$ is one of those technologies for safe disposal of $CO_2$. Geologic sequestration stores $CO_2$ in the form of supercritical fluid into the underground site surrounded by solid rock, and concrete is used for prevention of $CO_2$ leakage into the atmosphere. In such case, concrete may experience severe damage by attack of supercritical $CO_2$, and especially in contact with underground water, very aggressive form of carbonation can occur. In this work, to prevent such deterioration in concrete, calcium phosphates were added to the portland cement to produce hydroxyapatite, one of the most stable mineral in the world. Temperature rise, viscosity, set and stiffening, and strength development of cement paste incorporating three different types of calcium phosphates were investigated. According to the results, it was found that the addition of calcium phosphate increased apparent viscosity, but decreased maximum temperature rise and 28 day compressive strength. It was found that monocalcium phosphate was found to be inappropriate for portland cement based material. Applicability of dicalcium and tricalcium phosphates for portland cement needs to be evaluated with further investigation, including the long term compressive strength development.

Optimal Method for Injection of Neutralizer into Embankment Structure Composed of Pyrite Rocks (황철석으로 조성된 성토구조체의 중화제 주입을 위한 최적 방안 제안)

  • Young-Suk Song;Jung-Mann Yun
    • Journal of the Korean Geosynthetics Society
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    • v.22 no.4
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    • pp.73-82
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    • 2023
  • In this study, the optimal method for injection of neutralizer to restraint the leakage of acid drainage in embankment structure composed of pyrite rocks is proposed. Finite Element Analysis was performed to examine the seepage effect caused by injection of neutralizer into the embankment structure. The diameter of the neutralizer injection hole was selected as 50cm, the interval space of injection ranged from 1m to 4m and the injecting pressure ranged from 100kPa to 220 kPa were applied for the numerical analysis. According to the analysis results, the saturation time of the whole embankment structure was shown to be fast at a relatively low injecting pressure in the case of injecting interval space of 1.0m and injecting pressure of 130kPa and in the case of injecting interval space of 2.0m and injecting pressure of 160kPa. When the interval space of injection for saturation of whole embankment structure is selected as 3m, various injection pressures can be applied from 130kPa to 190kPa, and the saturation time of whole embankment is similar regardless of the injection pressure. Therefore, the optimal method for injection of neutralizer considering economic efficiency was selected as injecting interval space of 3.0m and injection pressure of 130kPa.

Desiccation Tolerance and Storage Behavior of Sarcandra glabra Seeds for Use in ex-situ Conservation (현지외 보존을 위한 죽절초 종자의 건조 내성과 저장성 평가)

  • Da-Eun Gu;Sim-Hee Han;Eun-Young Yim;Jin Kim;Ja-Jung Ku
    • Journal of Korean Society of Forest Science
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    • v.112 no.4
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    • pp.442-450
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    • 2023
  • This study sought to determine the desiccation tolerance and storage behavior of Sarcandra glabra seeds to assist in the establishment of an ex-situ conservation strategy for the species. The basic germination characteristics of S. glabra seeds were investigated. Subsequently, the seeds were dried to various desiccation levels to allow for analysis of their germination characteristics and seed integrity. In addition, the seeds were subjected to germination tests after being stored for different durations. The initial seed moisture content following the removal of the fleshy fruit was 32.8%, and the fresh seeds maintained their seed viability even after a decrease in the seed moisture content to 4.8%, while the germination percentage was 81.0%. The germination percentage of the seeds decreased to 55.0% and 30.0% when they were desiccated to moisture contents of 2.3% and 2.2%, respectively. By contrast, when the stored seeds were desiccated, they maintained their seed viability and vigor at a moisture content of 18.6%; however, when the moisture content decreased below 5.0%, both the seed viability and vigor significantly declined and the germination percentage fell below 20.0%. Furthermore, analysis of the seed leachate revealed that the decrease in the seed viability and vigor was associated with both increased electrical conductivity and increased concentrations of inorganic compounds such as potassium and calcium. In conclusion, the findings of this study show S. glabra seeds to possess desiccation tolerance that falls somewhere between the recalcitrant and intermediate seed types, with the observed variations depending on the degree of deterioration.

Spatio-Temporal Monitoring of Soil CO2 Fluxes and Concentrations after Artificial CO2 Release (인위적 CO2 누출에 따른 토양 CO2 플럭스와 농도의 시공간적 모니터링)

  • Kim, Hyun-Jun;Han, Seung Hyun;Kim, Seongjun;Yun, Hyeon Min;Jun, Seong-Chun;Son, Yowhan
    • Journal of Environmental Impact Assessment
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    • v.26 no.2
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    • pp.93-104
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    • 2017
  • CCS (Carbon Capture and Storage) is a technical process to capture $CO_2$ from industrial and energy-based sources, to transfer and sequestrate impressed $CO_2$ in geological formations, oceans, or mineral carbonates. However, potential $CO_2$ leakage exists and causes environmental problems. Thus, this study was conducted to analyze the spatial and temporal variations of $CO_2$ fluxes and concentrations after artificial $CO_2$ release. The Environmental Impact Evaluation Test Facility (EIT) was built in Eumseong, Korea in 2015. Approximately 34kg $CO_2$ /day/zone were injected at Zones 2, 3, and 4 among the total of 5 zones from October 26 to 30, 2015. $CO_2$ fluxes were measured every 30 minutes at the surface at 0m, 1.5m, 2.5m, and 10m from the $CO_2$ releasing well using LI-8100A until November 13, 2015, and $CO_2$ concentrations were measured once a day at 15cm, 30cm, and 60cm depths at every 0m, 1.5m, 2.5m, 5m, and 10m from the well using GA5000 until November 28, 2015. $CO_2$ flux at 0m from the well started increasing on the fifth day after $CO_2$ release started, and continued to increase until November 13 even though the artificial $CO_2$ release stopped. $CO_2$ fluxes measured at 2.5m, 5.0m, and 10m from the well were not significantly different with each other. On the other hand, soil $CO_2$ concentration was shown as 38.4% at 60cm depth at 0m from the well in Zone 3 on the next day after $CO_2$ release started. Soil $CO_2$ was horizontally spreaded overtime, and detected up to 5m away from the well in all zones until $CO_2$ release stopped. Also, soil $CO_2$ concentrations at 30cm and 60cm depths at 0m from the well were measured similarly as $50.6{\pm}25.4%$ and $55.3{\pm}25.6%$, respectively, followed by 30cm depth ($31.3{\pm}17.2%$) which was significantly lower than those measured at the other depths on the final day of $CO_2$ release period. Soil $CO_2$ concentrations at all depths in all zones were gradually decreased for about 1 month after $CO_2$ release stopped, but still higher than those of the first day after $CO_2$ release stared. In conclusion, the closer the distance from the well and the deeper the depth, the higher $CO_2$ fluxes and concentrations occurred. Also, long-term monitoring should be required because the leaked $CO_2$ gas can remains in the soil for a long time even if the leakage stopped.

Evaluation of Hydrogeologic Seal Capacity of Mudstone in the Yeongil Group, Pohang Basin, Korea: Focusing on Mercury Intrusion Capillary Pressure Analysis (포항분지 영일층군 이암층의 수리지질학적 차폐능 평가: 수은 모세관 압입 시험의 결과 분석을 중심으로)

  • Kim, Seon-Ok;Wang, Sookyun;Lee, Minhee
    • Economic and Environmental Geology
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    • v.53 no.1
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    • pp.23-32
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    • 2020
  • Geological CO2 sequestration is a global warming response technology to limit atmospheric emissions by injecting CO2 captured on a large scale into deep geological formations. The presented results concern mineralogical and hydrogeological investigations (FE-SEM, XRD, XRF, and MICP) of mudstone samples from drilling cores of the Pohang basin, which is the research area for the first demonstration-scale CO2 storage project in Korea. They aim to identify the mineral properties of the mudstone constituting the caprock and to quantitatively evaluate the hydrogeologic sealing capacity that directly affects the stability and reliability of geological CO2 storage. Mineralogical analysis showed that the mudstone samples are mainly composed of quartz, K-feldspar, plagioclase and a small amount of pyrite, calcite, clay minerals, etc. Mercury intrusion capillary pressure analysis also showed that the samples generally had uniform particle configurations and pore distribution and there was no distinct correlation between the estimated porosity and air permeability. The allowable CO2 column heights based on the estimated pore-entry pressures and breakthrough pressures were found to be significantly higher than the thickness of the targeting CO2 injection layer. These results showed that the mudstone layers in the Yeongil group, Pohang basin, Korea have sufficient sealing capacity to suppress the leakage of CO2 injected during the demonstration-scale CO2 storage project. It should be noticed, however, that the applicability of results and analyses in this study is limited by the lack of available samples. For rigorous assessment of the sealing efficiency for geological CO2 storage operations, significant efforts on collection and multi-aspect evaluation for core samples over entire caprock formations should be accompanied.