• Title/Summary/Keyword: mineral additive

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Prediction Model on Autogenous Shrinkage of High Performance Concrete (고성능 콘크리트의 자기수축 예측모델에 관한 연구)

  • Yoo, Sung-Won;Soh, Yang-Sub;Cho, Min-Jung;Koh, Kyung-Taek;Jung, Sang-Hwa
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.3
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    • pp.97-105
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    • 2006
  • The autogenous shrinkage of high-performance concrete is important in that it can lead the early cracks in concrete structures. The purpose of the present study is to explore the autogenous shrinkage of high-performance concrete with admixture and to derive a realistic equation to estimate the autogenous shrinkage model of that. For this purpose, comprehensive experimental program has been set up to observe the autogenous shrinkage for various test series. Major test variables were the type and contents of admixture and water-cement ratio is fixed with 30%. The autogenous shrinkage of HPC with fly ash slightly decreased than that of OPC concrete, but the use of blast furnace slag increased the autogenous shrinkage. Also, the autogenous shrinkage of HPC is found to decrease with increasing shrinkage reduction agent and expansive additive. A prediction equation to estimate the autogenous shrinkage of HPC with admixture was derived and proposed in this study. The proposed equation show reasonably good correlation with test data on autogenous shrinkage of HPC with mineral and chemical admixture.

Studies for CO2 Sequestration Using Cement Paste and Formation of Carbonate Minerals (시멘트 풀을 이용한 CO2 포집과 탄산염광물의 생성에 관한 연구)

  • Choi, Younghun;Hwang, Jinyeon;Lee, Hyomin;Oh, Jiho;Lee, Jinhyun
    • Journal of the Mineralogical Society of Korea
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    • v.27 no.1
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    • pp.17-30
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    • 2014
  • Waste cement generated from recycling processes of waste concrete is a potential raw material for mineral carbonation. For the $CO_2$ sequestration utilizing waste cement, this study was conducted to obtain basic information on the aqueous carbonation methods and the characteristics of carbonate mineral formation. Cement paste was made with W:C= 6:4 and stored for 28 days in water bath. Leaching tests using two additives (NaCl and $MgCl_2$) and two aqueous carbonation experiments (direct and indirect aqueous carbonation) were conducted. The maximum leaching of $Ca^{2+}$ ion was occurred at 1.0 M NaCl and 0.5 M $MgCl_2$ solution rather than higher tested concentration. The concentration of extracted $Ca^{2+}$ ion in $MgCl_2$ solution was more than 10 times greater than in NaCl solution. Portlandite ($Ca(OH)_2$) was completely changed to carbonate minerals in the fine cement paste (< 0.15 mm) within one hour and the carbonation of CSH (calcium silicate hydrate) was also progressed by direct aqueous carbonation method. The both additives, however, were not highly effective in direct aqueous carbonation method. 100% pure calcite minerals were formed by indirect carbonation method with NaCl and $MgCl_2$ additives. pH control using alkaline solution was important for the carbonation in the leaching solution produced from $MgCl_2$ additive and carbonation rate was slow due to the effect of $Mg^{2+}$ ions in solution. The type and crystallinity of calcium carbonate mineral were affected by aqueous carbonation method and additive type.

Stripping of Asphalt Pavements and Antistripping Addities (도로포장 구조물에서의 스트리핑 현상과 스트리핑 방지제의 이용방안)

  • 윤현희
    • Journal of Korean Society of Transportation
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    • v.8 no.2
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    • pp.119-131
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    • 1990
  • Physico-chemical properties of asphalt, aggregate, and asphalt-aggregate mixture that might influence stripping were summarized in Table 1, based on the fundamental theories concerning stripping. It was found that although physical properties of aggregate affected stripping, there was no strong correlation between the physical properties of aggregate, such as pore volume and surface area, and the stripping propensity of the aggregate. Chemical and electrochemical properties of aggregate surface in the presence of water were most important factors for stripping. All mineral aggregates tested in this study imparted distinctive pH values to the contacting water and possessed distinctive electrochemical properties as measured by zeta potential. It was found that aggregates which had relatively higher surface potential in water and/or which imparted relatively higher pH to the contacting water were more susceptible to stripping. The functionalities contained in antistripping additives tested were primary and secondary amines and those of organic nitrogen compounds. The functionalities were determined by examining their infrared spectra. Based on the interfacial energy concept, the contact angle of an asphalt drop on an aggregate surface immersed in water related to the stripping propensity. The contact angle and stripping propensity were markedly reduced by the presence of an antistripping additive. In general, all the additives tested improved stripping resistance to some extent, depending on their concentration in the asphalts. The optimum dosage of an additive varied with different asphalts, as well as different aggregates. All antistripping additives tested in this study lost their effectiveness and failed to function to some extent when maintained for hours in a hot asphalt.

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Fungal bioconversion of Korean food wastes for the production of animal feed additive enzymes

  • Jeong, Yun-Seung;Jeong, Sang-Won;Jo, A-Ra;Gwon, Sun-U;Han, Seung-Ho
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.529-532
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    • 2001
  • Korean food waste, one of the abundantly available but environmentally problematic organic wastes in Korea, was utilized as solid-substrate by fungal strain Aspergillus niger ATcC 6275 for the production of enzymemixture containing amylase, cellulase and xylanase. The enzyme mixture can be used as high value-added animal feed. Solid-state fermentation method yielded a 84-fold enhancement in xylanase activity compared with submerged fermentation method. The effect of incubation period, incubation temperature, pH of medium, moisture content, inoculum size and enrichment of the medium with nitrogen and carbon sources were observed for optimal production of these enzymes The optimal amylase activity of 33.10 U/g, cellulase activity of 24.41 U/g, xylanase activity of 328.84 U/g were obtained at 8 days incubation with 50%(w/w) soy bean flake, with incubation temperature of $25^{\circ}C$, pH of 6.38, optimal moisture content of 55% and with inoculum size of $3.8{\times}10^6$spore/g. Enzyme activities were enhanced when ImM $CaSO_4$, 2% Malt extract and 2% galactose were added as mineral, nitrogen and carbon enrichment respectively.

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미생물을 이용한 다용도 고형 탈취제의 개발

  • Kim, Yu-Jin;Lee, Eun-Jeong;Jeon, Mi-Uk;Kim, Cho-Hui;Park, Seong-Hun;Lee, Eun-Yeol
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.513-516
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    • 2001
  • This study was to develop of efficient microbial agent for malodor removal. Total ten strains of beneficial bacteria Bacillus sp., Pseudomonas sp., and photosynthetic bacteria were isolated and identified on the basis of their morphological and biochemical characteristics. The enzyme activities such as amylase, protease, lipase and cellulase of bacteria cells were measured. Furthennore, effective formulation procedure 、 ,vas developed with nutrient additive, stabilizing agent and mineral materix. For preparation of microbial agent, developing of formulation technique was very helpful for incresing the cell survival rate.

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Wear, Oxidation and Shear Characteristics of Mixed Lubricating Oil (Mineral/Vegetable oil) with ZnDTP (ZnDTP를 첨가한 혼합윤활유(광유/식물성 오일)의 마모, 산화 및 전단 특성)

  • Lim, TaeYoon;Kim, YangHoe;Na, Byung-Ki
    • Tribology and Lubricants
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    • v.34 no.4
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    • pp.160-167
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    • 2018
  • Vegetable oils can contribute to the goal of energy independence and security owing to their naturally renewable resources. One of the representative vegetable oils is biodiesel, which is being used in domestic and European markets as a blended fuel with automotive diesel. Vegetable oils are promising candidates as base fluids to replace petroleum lubricants because of their excellent lubricity and biodegradability. We prepared biodiesel with a purity of 99.9% via the esterification of waste cooking oil. Blended biodiesel and Petro-lube base oil were mixed to produce five types of mixed lubricating oil. We analyzed the various characteristics of the blended biodiesel with Petro-lube base oil for different blending ratios. The lubricity of the vegetable lubricant improves as the content of biodiesel increases. In addition, since zinc dialkyldithiophosphates (ZnDTPs) are widely used as multifunctional additives in petroleum-based lubricants, we optimized the blending ratio for lubricity, oxidation stability, and shear stability by adding ZnDTP as a performance additive to improve the biodiesel properties, such as oxidation stability and hydrolysis. The optimized lubricants improve by approximately 25% in lubricity and by 20 times in oxidation stability and shear stability after the addition of ZnDTP.

he Correlation of Usual Dietary Isoflavone Intake and Serum Osteocalcin (여대생의 대두제품을 이용한 이소플라본섭취 및 혈중 Osteocalcin과의 상관성)

  • 안홍석;박윤신
    • Korean Journal of Community Nutrition
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    • v.9 no.1
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    • pp.38-46
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    • 2004
  • Few studies have conducted the bone health benefits of usual dietary isoflavone intake in Korean college-student women. To elucidate this benefitial effects and correlations between dietary isoflavone and nutrients intake and bone formation marker (ALPase, osteocalcin), questionnaires, anthropometric measurements, serum mineral (Ca, P, Mg) concentrations were analyzed. Fifty three subjects were used in this study. The average age, height, body weight, BMI, body fat content and triceps skinfold thickness were 21.43 year, 161.07 cm, 52.81 kg, 20.48 kg/$m^2$, 20.72% and 17.59 mm respectively. Soy food intake frequencies were soybean > soybean curd > soypaste stew > soybean milk. The average calorie, protein and Ca intake were 1766.21 $\pm62.54 kcal\;66.45\pm2.00 g\;and\; 549.62 \pm 27.55 mg$ respectively. Serum ALPase activity and osteocalcin concentration were 115.74$\pm3.6u/L$ and 7.15 ng/$m\\ell$ respectively. Usual dietary isoflavone intake was positively related to calory, protein, Ca, P intake and serum Ca, Mg concentration. Serum osteocalcin concentration was negatively correlated with isoflavone intake ($r^2$=0.28, p < 0.05). In these results, usual dietary isoflavone can support an additive effect to bone health and Ca nutrition.

Influence of ground pumice powder on the bond behavior of reinforcement and mechanical properties of self-compacting mortars

  • Benli, Ahmet;Karatas, Mehmet;Sastim, M. Veysel
    • Computers and Concrete
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    • v.20 no.3
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    • pp.283-290
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    • 2017
  • The aim of this study is to investigate the effect of the bond strength of self-compacting mortars (SCMS) produced from ground pumice powder (GPP) as a mineral additive. In this scope, six series of mortars including control mix were prepared that consist of 7%, 12%, 17%, 22% and 27% of ground pumice powder by weight of cement. A total of 54 specimens of $40{\times}40{\times}160mm$ were produced and cured at the age of 3, 28 and 90-day for compressive and tensile strength tests and 18 specimens of $150{\times}150{\times}150mm$ mortar were prepared and cured at 28 days for bond strength tests. Flexural tensile strength and compressive strength of $40{\times}40{\times}160mm$ specimens were measured at the curing age of 7, 28 and 90-day. Mini V-funnel flow time and mini slump flow diameter tests were also conducted to obtain rheological properties. As a result of the study, it was observed that the SCMs containing 12% of GPP has the highest bond strength as compared to control and GPP mortars. Compressive strength slightly increased up to 12% of GPP.

Effects of Heavy Metals on Biomonitoring using Recombinant Bioluminescence Bacteria (유전자재조합균주를 이용한 생물모니터링에 중금속 오염물이 미치는 영향 평가)

  • Kong, In Chul;Kim, Jin Young;Ko, Kyung-Seok
    • Journal of Soil and Groundwater Environment
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    • v.18 no.4
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    • pp.32-39
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    • 2013
  • This research focused on the effects of heavy metals on the biomonitoring activity of genetically engineered bioluminescent bacteria, Pseudomonas putida mt-2 KG1206. KG1206 was exposed to single or binary mixtures of different heavy metals as well as soils contaminated with heavy metals. In case of single exposure with different inducer pollutant, the toxicity order was as followings : As(III) > Cd, As(V) >> Cu, Cr(VI). The toxic effects of the binary mixtures was compared to the expected effect based on a simple theory of probabilities. The interactive effects were mostly additive, while in few cases antgonistic and synergistic mode of action was observed for some concentration combinations. No considerable correlation was found between the total metal contents in soils and the bioluminescence activity of each sample. However, statistically significant differences (p = 0.0102) were observed between two groups, classified based on arsenite contamination. These results demonstrate the usage of recombinant bioluminescent microorganism in biomonitoring and the complex interactive effects of metals.

Studies on Methanol-assimilating Yeasts (메탄올 자화효모에 관한 연구)

  • 전순배
    • Korean Journal of Microbiology
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    • v.19 no.4
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    • pp.163-173
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    • 1981
  • The distribution of methanol-assimilating yeasts on three different sources (elm bark, soil and fresh-water mud) and the growth conditions of a new strain of Candidaboidinii (SIO) wereexamines. From 150 samples, 91 methanol yeasts were isolated through enrichment culture ; they were identified as 77 strains of Candida boidinii including four new strains, 5 isolates of Torulopsis pinus, 3 strains of Hansenula polymorpha and one sstrain of Pichia pastoris respectively. The comparison of these yeasts with three sources indicated that decaying bark of elm tree other two, and that Gandida boidinii was most frequently distributed in all three sources. Four new strains of Candida boidinii were freshly isolated and their taxonomical properties were discussed. Of them, SIO strain was selected and characterized for its growth on methanol. This yeast could grow well on less than 1%(v/v) methanol. However, its growth was inhibited at 10% methanol. The cell yield was 3.1g (dry weight) per 1000ml of mineral mediurr, containing 1%(v/v) methanol as well as 01.% yeast extract as additive. The concentration of 0.1% yeast extract appears to be effective for the biomass production. Optimum conditions for growth on methanol was found to be : $28^{\circ}C,\;NH_4^+$ as nitrogen sources, thiamine as vitamin, and pH 4.5 to 6.0. The cell composition was as follows : crude protein and nucleic acids were 54% and 7% respectively. The amino acids were also described.

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