• Title/Summary/Keyword: mineral additive

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Effect of NaOCl and Gold Plating Additive on the Gold Recovery in Cyclone Electrolytic Cell from Solution for Stripping Gold of PCB by Cyanide (시안을 이용한 PCB 금 박리용액으로부터 사이클론 전해조에서의 금 회수거동에 미치는 차아염소산나트륨과 금 도금첨가제의 영향)

  • Jo, Hyeonji;Yoo, Kyoungkeun;Bae, Mooki;Sohn, Jeongsoo;Yang, Donghyo;Kim, Sookyung
    • Resources Recycling
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    • v.26 no.4
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    • pp.88-94
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    • 2017
  • The recovery of gold in cyclone type electrolytic cell was conducted from solution for stripping gold of PCB by cyanide. The electrolytic recovery behaviors of gold was investigated by reaction time and addition of electrolytic sodium hypochlorite (NaOCl) and gold plating additive (KG-120). Because the electrolysis generated NaOCl reacted with the cyanide in the leachate by alkaline chlorination, more than 99% of the cyanide was removed at a $NaOCl(g)/CN^-(g)$ ratio of 1.0. When NaOCl was added during the recovery of the gold from cyanide leachate in the cyclone electrolytic cell, the recovery of gold was 98% at the ratio of $NaOCl(g)/CN^-(g)$ from 0.5 to 2.5 in 480 minutes and decreased rapidly over the ratio of 3.0. Gold was recovered more than 99% by adding 1.5 and 4.5%(v/v) of KG-120 with NaOCl in 480 minutes. In particular, when the concentration of KG-120 was 3.5 and 4.5%(v/v), more than 96% of gold was recovered within 240 minutes and the initial recovery rate was relatively faster. The optimum concentration of KG-120 is 3.5%(v/v) considering the economic feasibility and efficiency.

Preparation of Pure Silver Powders by using Mechanochemical Process (기계화학공정(機械化學工程)에 의한 은(銀)염화물로부터 고순도 은(銀)분말 제조(製造))

  • Lee, Jaer-Yeong;Tung Le, M.;Ahn, Jong-Gwan;Kim, Jong-Oh;Chung, Hun S.;Kim, Byoung-Gyu
    • Resources Recycling
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    • v.15 no.5 s.73
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    • pp.33-37
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    • 2006
  • An equal-molar mixture of silver chloride (AgCl) and copper (Cu) was ground in atmosphere conditions using a planetary ball mill to investigate mechanochemical (MC) reaction for preparation of silver powders. The reaction causes the mixture of AgCl and Cu to change the composition of the mixture, such as silver (Ag) and cuprous chloride (CuCl). Through the leaching with ammonium hydroxide solution (1 mol), CuCl can be separated from MC product, so that pure Ag powders can be obtained as the final product. Moreover, polyvinylpyrrolidone (PVP) was used as the additive not only to improve dispersion of Ag pow- der during MC process, but also to control surface oxidation of Ag powders, prepared as the final product.

3D Printed Building Technology using Recycling Materials (리사이클링 원료를 사용한 건축용 3D 프린팅 기술 동향)

  • Baek, Chul-Seoung;Seo, Jun-Hyung;Cho, Jin-Sang;Ahn, Ji-Whan;Cho, Kye-Hong
    • Resources Recycling
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    • v.27 no.1
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    • pp.3-13
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    • 2018
  • 3D printing, also known as Additive Manufacturing (AM), is being positioned as a new business model of revolutionizing paradigms of existing industries. Launched in early 2000, 3D printing technology for architecture has also advanced rapidly in association with machinery and electronics technologies mostly in the United States and Europe. However, 3D printing systems for architecture require different mechanical characteristics from those of cement/concrete raw materials used in existing construction methods. Accordingly, in order to increase utilization of raw materials produced in the cement and resource recycling industry, it is necessary to develop materials processing and utilization technology, to secure new property evaluation and testing methods, and to secure database related to environmental stability for a long period which aims to reflect characteristics of an architectural 3D printing technology.

Effects of Environmentally Friendly Agents on Growth Performance, Nutrient Digestibility, Nutrient Excretion and Carcass Characteristics in Growing-Finishing Pigs

  • Min, T.S.;Kim, J.D.;Hyun, Y.;Sohn, K.S.;Heo, K.N.;Han, In K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.14 no.4
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    • pp.540-547
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    • 2001
  • An experiment was conducted to investigate the effects of environmentally friendly agents (yucca extract, mineral feed additive, acidifier, nonspecific immunostimulating anionic alkali solution) on the growth performance, nutrient digestibility, nutrient excretion and carcass characteristics in growing-finishing pigs. A total of 125 pigs were allotted into 5 treatments with 5 replications, 5 pigs per pen in a completely randomized block design. Dietary treatments consisted of 1) control: basal diet, 2) YE: basal diet+120 mg/kg of yucca extract, 3) MFA: basal diet+50 mg/kg of mineral feed additive, 4) NIS: basal diet+3% of NIS (nonspecific immunostimulating anionic alkali solution), and 5) Acidifier: basal diet+0.5% of acidifier (organic acid complex). During the growing phase of the feeding trial, There were no significant differences in average daily feed intake (ADFI) and feed conversion ratio (F/G) among treatments, but the Acidifier group showed higher average daily gain (ADG) than the MFA group (p<0.05). During the finishing phase, there were no significant differences in growth performance among treatments, however YE supplementation increased ADG and F/G by 3.1 and 6.15%, respectively, when compared to control group. Proximate nutrients (dry matter, DM; crude protein, CP; crude ash, CA; crude fat, CF; gross energy, GE; calcium, Ca and phosphorus, P) digestibility did not show any significant differences among the treatments. And there were no significant differences in DM, N and P excretion as well. The supplementation of environmentally friendly agents tended to increase carcass weight compared to control group. Pigs fed MFA showed significantly heavier (p<0.05) carcass weight than those fed control or Acidifier diets. Addition of these agents except for NIS to diet for growing-finishing pigs caused a similar feed cost/kg weight gain than control group. Therefore, present study suggested that the optimum environmentally friendly agent would be yucca extracts, considering the effects on growth performance, nutrient digestibility, nutrient excretion, carcass characteristics and feed cost in growing-finishing pigs.

Effect of Clay-Mineral Composition on Flexural Strength of Clay-based Membranes (점토 광물 조성이 점토기반 분리막의 곡강도에 미치는 영향)

  • Lee, Young-Il;Eom, Jung-Hye;Kim, Young-Wook;Song, In-Hyuck
    • Journal of the Korean Ceramic Society
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    • v.51 no.5
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    • pp.380-385
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    • 2014
  • Clay-based membranes with submicron pore size were successfully prepared by a simple pressing process using low-cost starting materials(e.g., kaolin (K), bentonite (B), talc (T), and sodium borate). The green bodies were sintered at $1000^{\circ}C$ for 2 h in air. The effect of clay-mineral composition on the flexural strength of clay-based membranes was investigated. The porosity of the clay-based membranes could be controlled within the range of 34 - 42% by adjusting the starting composition. The flexural strength of the low-cost membranes depended on both the porosity and the ${\alpha}$-quartz content. In turn, the porosity and ${\alpha}$-quartz content were affected by the (B+T) /(K+B+T) ratio. The plot of strength relative to this ratio, showed a maximum when the ratio was 0.4. The typical flexural strength of these clay-based membranes (with ratio 0.4) was 28 MPa at 34% porosity.

Evaluation on Basic Properties of Crushed Sand Mortar in Freezing-Thawing and Sulfate Attack (동결융해와 황산염의 복합작용을 받는 부순모래 모르타르의 기초 특성 평가)

  • Kim, Myeong-Sik;Baek, Dong-Il;Choi, Kang-Seok
    • Journal of Ocean Engineering and Technology
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    • v.23 no.5
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    • pp.54-60
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    • 2009
  • Exposed to various environments, concrete confronts degradation by a lot of physical and chemical reaction. Though so many experiments and theorizations on the single condition of concrete degradation have been carried out by constant studies, the truth for now is that there are few studies on the compound phenomenon of degradation related with marine environments. Accordingly, this study measured the degree of degradation in the change of external shape, the change of unit weight and compressive strength, ultrasonic velocity test, and the change of length, etc. after exposing the specimen of cement mortar to the environment between 0 cycle and the maximum of 300 cycles under the condition of aquatic curing, freezing and thawing, and compound degradation, using mineral admixture effective for concrete degradation as a binder. The result indicated that the case of adding mineral admixture showed greater resistance than that of using OPC only, and specifically, the specimen with the additive of slag powder and three component system showed very excellent resistance to freezing and thawing, and compound degradation.

Concentrations and Daily Intake of Arsenic and Heavy Metals in Polished Rice Around Abandoned Metal Mines in Korea (국내 휴·폐금속광산 주변 백미의 비소 및 중금속 함량과 일일 섭취량)

  • Kwon, Ji Cheol;Lee, Goontaek;Kim, Jeong Wook;Jung, Myung Chae
    • Journal of Soil and Groundwater Environment
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    • v.23 no.1
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    • pp.63-73
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    • 2018
  • Rice is a staple food source in Asian countries. In paddy field, rice plant can take up toxic elements through its roots from contaminated soils, and its leaves and grain can absorb the toxic elements deposited on the soil surface. A totla of 40 soil and polished rice samples were collected around four abandoned metal mines in Korea and analyzed for As, Cd, Cu, Pb and Zn by atomic absorption spectrophotometer (AAS). The average contents of As, Cd, Cu, Pb and Zn in rice grain grown on the contaminated soils were 0.247, 0.174, 4.694, 0.804 and 16.78 mg/kg, respectively. These levels are higher than worldwide average concentrations. Assuming the rice consumption of 169 g/day by overall households in Korea, the estimated daily intakes from the rices were found to be 33, 48, and 63% for As, Cd, and Pb, respectively, of the acceptable daily intake (ADI) suggested by the FAO/WHO Joint Food Additive and Contaminants Committee.

Fabrication of Mo based Thermal Spray Composite Powder by Self- propagating High- temperature Synthesis (SHS 합성에 의한 몰리브덴계 용사용 복합분말의 제조)

  • Park, Je-Sin;Sim, Geon-Ju
    • Korean Journal of Materials Research
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    • v.11 no.9
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    • pp.763-768
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    • 2001
  • Molybdenum-based thermal spray powder is widely used for coating the moving parts of the internal combustion engines due to its excellent wear resistance. A composite powder of the $Mo_{40}(Al_{1-x}Si_x)_{60}$ system was synthesized using the SHS method. The synthesized bulk was pulverized and specially treated to produce thermal spray powder. It was found that the synthesis reaction consisted of two-steps: the formation of $Al_8/Mo_3$ and the formation of Mo(Al,Si)$_2$. Both the temperature and the rate of the SHS reaction linearly increased with the increase of the value of x in $Mo_{40}(Al_{1-x}Si_x)_{60}$, The temperature and the rate of the reaction were also affected by the compacting density of the specimens, exhibiting the maximum valves at 62% and 60%, respectively. Since spherical shape is advantageous to the thermal spraying process, shape-control of the powder was attempted with PVA as a binding additive, resulting in the successful production of almost perfectly spherical powder of 80 $\mu\textrm{m}$ Ø$(d_{50})$ mean particle size.

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An Experimental Study on Shrinkage of High Strength Concrete with Mineral Admixture (혼화재 사용에 따른 고강도 콘크리트의 수축에 관한 실험적 연구)

  • Lee, Young-Jae
    • Journal of the Korean Society of Industry Convergence
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    • v.13 no.2
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    • pp.99-106
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    • 2010
  • The effects of additive and shrinkage reducing agent on the drying and autogenous shrinkage of high strength concrete are investigated in this study. As results, when the ratio of W/B(low water to binder ratio) increase, the compressive strength is decreased. Comparing with PC(portland cement) concrete, the strength is 2.8%, 3.2% and 3.8% lower respectively than that of PC when concrete mixing ratio is 0.2%, 0.3% and 0.4% in 28 days curing. Drying shrinkage strain of PC concrete showed $-650{\times}10^{-6}$ in 91 days curing. When SR(shrinkage reducing agent) of 0.2%, 0.3% and 0.4% is mixed, the drying shrinkage strains are 21%, 34% and 41% lower than those of PC in 91 days curing. Autogenous shrinkage strain of PC concrete appeared $-480{\times}10^{-6}$ in 56 days curing. When SR of 0.2%, 0.3% and 0.4% is mixed, the autogenous drying shrinkage strain are 12.5%, 19.8% and 33.3% lower than those of PC in 56 days curing. In cases of using the mineral and shrinkage agent or only using a shrinkage reducing agent also appeared same reducing effects for drying shrinkage and autogenous shrinkage.

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INTUMESCENT INORGANIC AND ORGANIC COATINGS

  • Kodolov, V.I.;Mikhalkina, T.M.;Shuklin, S.G.;Bystrov, S.G.;Larionov, K.I.
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1997.11a
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    • pp.130-137
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    • 1997
  • Intumescent inorganic and organic coatings which dintr one from the other by the type of gas formers and the mechanisms of foam formation have been obtained and investigated. Inorganic intumescent coatings are the compositions based on water glass and mineral additives with different dispersity. Mineral additives contain adsorbed and absorbed water and carbonates which are destructed with the carbon dioxide and water evolution during the flame action on coating. The decreasing of mineral additives particle sizes under the mechanical milling with the fraction precipitation promotes the foam coke formation with less defects. Here the main structure of comparing compositions does not change. In organic coatings based on epoxy-polymers the polyammonium phosphate additive is used. It is the cabonization catalyst and the foam agent. The polyammonium phosphate of various dispersity employed is uniformly distributed on the polymeric matrix. The decreasing of the particle sizes leads to the increasing of the fire resistant properties of the intumescent coa-ting. The fire resistant analysis of the coating during more than an hour: the coating back side the temperature on plastic or wooden materials does not exceed 423K, and on metal-573K.

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