• Journal of Magnetics
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• 제8권1호
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• pp.18-23
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• 2003

In our previous work, microstructure and magnetic properties of two-phase exchange-coupled $Sm_2Fe_{15}Ga_2C_{x}$/$\alpha$-Fe nanocomposites have been investigated by means of x-ray diffraction, transmission electron microscopy and magnetization measurement. It was found the exchange coupling between the magnetically hard phase $Sm_2Fe_{15}Ga_2C_{x}$ and the magnetically soft one ${\alpha}$-Fe results in an enhancement of the remanence. The sizes of crystallites of both phases are, however much larger than the Block domain-wall width of the magnetically hard phase. This microstructure gives rise to a concave demagnetization curve and consequently reduces the maximum energy Product. In order to improve their magnetic properties, a few Percent of Zr, which may be effective to refine the microstructure through rapid quenching, was introduced into the nanocomposites. The addition of Zr was found to improve the magnetic properties significantly, Under optimum heat-treatment conditions, the remanence, coercivity and maximum energy Product increase from 0.65 T, 0.48 T and 50 kJ/$m^{3}$ for the Zr-free sample to 0.72 T, 0.77 T and 71.6 kJ/$m^{3}$ for the 1 at.% Zr-containing one, respectively, The improvements of magnetic properties are due to the refinement of microstructure by the addition of Zr.

• 한국분말재료학회지
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• 제9권3호
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• pp.182-188
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• 2002

Conventional Fe-Co alloys are important soft magnetic materials that have been widely used in industry. Compared to its polycrystalline counterpart, the nanostructured materials have showed superior magnetic properties, such as higher permeability and lower coercivity due to the single domain configuration. However, magnetic properties of nanostructured materials are affected in complicated manner by their microstructure such as grain size, internal strain and crystal structure. Thus, studies on synthesis of nanostructured materials with controlled microstructure are necessary for a significant improvement in magnetic properties. In the present work, starting with two powder mixtures of Fe and Co produced by mechanical alloying (MA) and hydrogen reduction process (HRP), differences in the preparation process and in the resulting microstructural characteristics will be described for the nano-sized Fe-Co alloy particles. Moreover, we discuss the effect of the microstructure such as crystal structure and grain size of Fe-Co alloys on the magnetic properties.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2002년도 동계연구발표회 논문개요집
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• pp.22-22
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• 2002

It is well known that nanoscale magnetic materials can exhibit significantly different magnetic properties than the corresponding bulk materials. In present work, we summarized the preparation, microstructure, Mossbauer study and magnetic properties of nanocomposites. It was found that both grain size and the amount of magnetically soft phase ${\alpha}$-Fe play a very important role in determining the magnetic properties. (omitted)

• 열처리공학회지
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• 제37권1호
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• pp.9-15
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• 2024

Nd-Fe-B permanent magnets have been utilized on various industrial fields such as electric vehicles, generator, robots with actuator, etc, due to their outstanding magnetic properties even 10 times better than conventional magnets. Recently, there are many researches that report magnetic properties improved by controlling microstructure through adjusting alloying elements or conducting various processing. Especially, post-sintering annealing (PSA) can significantly improve the coercivity by modifying the distribution and morphology of Nd-rich phase which formed at grain boundaries. In this study, Nd-Fe-B sintered magnets were subjected to primary heat treatment followed by secondary heat treatment at 460℃, 500℃, and 540℃ to investigate the changes in microstructure and magnetic properties with the secondary heat treatment temperature. EBSD analysis was conducted to compare anisotropic characteristics. Through the SEM and TEM observation for analyzing the morphology and distribution of Nd-rich phase, we investigated the relationship between microstructure and magnetic properties of sintered Nd-Fe-B magnets.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1286-1287
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• 2006

[ $Nd_2Fe_{14}B/{\alpha}-Fe$ ] nanocomposite powders with a nominal composition of $Nd_{12}Fe_{82}B_6$ were prepared by HDDR combined with mechanical milling. The microstructure was studied by Mossbauer spectrometry and TEM. The magnetic properties were investigated by VSM using bonded magnet samples. The results showed that the annealing temperature had significant influence on both the recombination kinetics and the grain size of the $Nd_2Fe_{14}B$ and ${\alpha}-Fe$ phases, and the bonded magnets presented the best magnetic properties when the nanocomposite powders were prepared by annealing at $760^{\circ}C$ for 30 min.

• 한국재료학회지
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• 제28권3호
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• pp.159-165
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• 2018

In order to increase the efficiency of the sputtering method widely used in thin film fabrication, a dc sputtering apparatus which supplies both high frequency and magnetic field from the outside was fabricated, and cobalt thin film was fabricated using this apparatus. The apparatus can independently control the applied voltage, the target-substrate distance, and the target current, which are important parameters in the sputtering method, so that a stable glow discharge is obtained even at a low gas pressure of $10^{-3}$ Torr. The fabrication conditions using the sputtering method were mainly performed in $Ar+O_2$ mixed gas containing about 0.6 % oxygen gas under various Ar gas pressures of 1 to 30 mTorr. The microstructure of Co thin films deposited using this apparatus was examined by electron diffraction pattern and X-ray techniques. The magnetic properties were investigated by measuring the magnetization curves. The microstructure and magnetic properties of Co thin films depend on the discharge gas pressure. The thin film fabricated at high gas pressure showed a columnar structure containing a large amount of the third phase in the boundary region and the thin film formed at low gas pressure showed little or no columnar structure. The coercivity in the plane was slightly larger than that in the latter case.

• 한국분말재료학회지
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• 제24권2호
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• pp.122-127
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• 2017

Fe-6.5 wt.% Si alloys are widely known to have excellent soft magnetic properties such as high magnetic flux density, low coercivity, and low core loss at high frequency. In this work, disc-shaped preforms are prepared by spark plasma sintering at 1223 K after inert gas atomization of Fe-6.5 wt.% Si powders. Fe-6.5 wt.% Si sheets are rolled by a powder hot-rolling process without cracking, and their microstructure and soft magnetic properties are investigated. The microstructure and magnetic properties (saturation magnetization and core loss) of the hot-rolled Fe-6.5 wt.% Si sheets are examined by scanning electron microscopy, electron backscatter diffraction, vibration sample magnetometry, and AC B-H analysis. The Fe-6.5 wt.% Si sheet rolled at a total reduction ratio of 80% exhibits good soft magnetic properties such as a saturation magnetization of 1.74 T and core loss ($W_{5/1000}$) of 30.7 W/kg. This result is caused by an increase in the electrical resistivity resulting from an increased particle boundary density and the oxide layers between the primary particle boundaries.

• Journal of Magnetics
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• 제11권1호
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• pp.36-42
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• 2006

In this report, we demonstrate a comprehensive analysis of the effects of Au addition on the microstructure and magnetic properties of $Fe_{73.5}Si_{13.5}B_{9}Nb_{3}Au_1$ Finemet-type alloy. It was found that the as-quenched alloys were the amorphous state and turned into nanocrystalline state under heat treatments. The DSC analysis indicates that the sharply exothermal peak corresponding to the crystallization of the $\alpha-Fe(Si)$ was observed at $547-579^{\circ}C$ depending on the heating rates, which is little higher than that of original Finemet (542-$570{^{\circ}C}$, respectively). Besides, the thermomagnetic result confirmed that the full substitution of Cu by Au with the single phase structure in the M(T) curve along cooling cycle. Ultrasoft magnetic properties of the nanocrystallized samples were significantly enhanced by the proper annealing such as the increase of permeability and the decrease of the coercivity. The optimum annealing condition was found at the annealing temperature of $540^{\circ}C$ and the increase of the annealing time up to 90 min.

• Journal of Magnetics
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• 제21권1호
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• pp.51-56
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• 2016

The microstructure and magnetic properties of HDDR-treated powders after grain boundary diffusion process (GBDP) with Nd-Cu alloy at different temperatures have been studied. The variation of GBDP temperature had multifaceted influences on the HDDR-treated powders involving the microstructure, phase composition and magnetic performance. An enhanced coercivity of 16.9 kOe was obtained after GBDP at $700^{\circ}C$, due to the modified grain boundary with fine and continuous Nd-rich phase. However, GBDP at lower or higher temperature resulted in poor magnetic properties because of insufficient microstructural modification. Especially, the residual hydrogen induced phenomenon during GBDP strongly depended on the GBDP temperature.

• 한국분말재료학회지
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• 제15권6호
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• pp.471-476
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• 2008

Sintered Nd-Fe-B magnets have been widely used due to their excellent magnetic properties, especially for driving motors of hybrid and electric vehicles. The microstructure of Nd-Fe-B magnets strongly affects their magnetic properties, in particular the coercivity. Therefore, a post-sintering process like heat-treatment is required for improving the magnetic properties of Nd-Fe-B sintered magnets. In this study, cyclic heat treatment was performed at temperatures between $350^{\circ}C$ and $450^{\circ}C$ up to 16 cycles in order to control microstructures such as size and shape of the Nd-rich phase without grain growth of the $Nd_{2}Fe_{14}B$ phase. The 2 cycles specimen at this temperature range showed more homogeneous microstructure which leads to higher coercivity of 35 kOe than as-sintered one.