• Journal of the Korean Society for Heat Treatment
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• v.26 no.3
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• pp.113-119
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• 2013

Grain growth behaviors of hot-rolled AZ31 (Mg-3%Al-1%Zn) and AZ31-0.3%CaO alloys at elevated temperatures have been investigated in order to clarify the effect of CaO addition on grain stability of Mg-Al-based wrought alloy. The grain size of CaO-free alloy increased steeply from 673 K with an increase in annealing temperature from 573 to 773 K, whereas the grains of CaO-containing alloy were relatively stable up to 723 K. The activation energies for grain growth ($E_g$) were 12.2 and 18.3 kJ/mole between 573 and 673 K and 119.2 and 126.9 kJ/mole between 673 and 773 K in the AZ31 and AZ31-0.3%CaO alloys, respectively. This result indicates that grains in the CaO-added alloy possess higher thermal stability than CaO-free alloy. SEM observations on the annealed alloy samples revealed that higher grain stability resulting from CaO addition would be associated with the suppression of grain growth by Ca-related precipitate particles distributed in the microstructure.

• Journal of Korea Foundry Society
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• v.18 no.3
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• pp.283-288
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• 1998

Interest in rapid solidification of magnesium alloys stems from the fact that conventional ingot metallurgy alloys exhibit poor strength, ductility, and corrosion resistance. Such properties can be improved by microstructural refinement via rapid solidification processing. In this study, Mg-Zn alloys have been produced as continuous strips by melt overflow technique. In order to evaluate the influence of additional elements on the grain refinement and mechanical properties, Th and Zr were added in rapidly solidified Mg-5wt%Zn alloy. Then the microstructual observations were undertaken with the objective of evaluating the grain refinement as function of the cooling rate and the additional elements. The tremendous increase in hardness of Mg-Zn base alloys was mainly due to the refinement of the grain structure by the effect of rapid solidification and alloying elements. The formation of intermetallic phases on the grain boundaries may have a positive effect on the corroion resistance. Therefore, despite competition from many other developments, the rapid solidification processing of magnesium alloys emerges as a valuable method to develop superior and commercially acceptable magnesium alloys.

• Journal of Korea Foundry Society
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• v.15 no.5
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• pp.514-522
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• 1995

The microstructural evolution with isothermal stirring during semi-solid state processing of hypoeutectic Al-6.2wt%Si alloy was studied. Substructure of the individual primary solid particle in the slurry was investigated through transmission electron microscopy(TEM). Formation of subgrain boundaries on the rheocast Al-6.2wt%Si alloy is observed and the misorientation between the grains is shown typically under 2 degrees by analyzing selected area diffraction (SAD) and convergent beam electron diffraction (CBED) patterns. The existence of high angle grain boundaries are also observed in the alloy. Based upon these observations, mechanisms for the primary particles fragmentation are considered. With isothermal stirring, the dislocation density increases, and the evolution of dislocation cell structure takes place, which is interpreted as a process of achieving uniform deformation by dynamic recovery under applied shear stress.

• Journal of Korea Foundry Society
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• v.35 no.6
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• pp.170-177
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• 2015

Segregation during solidification and homogenization during thermal exposure in GTD 111 were investigated. The microstructures of as-cast, standard heat-treated, and thermally exposed specimens were observed by SEM. A compositional analysis of each specimen was conducted by EDS. The dendrite core was enriched in W and Co, though lower levels of Ti and Ta were observed. An unexpected phase, in this case like the ${\eta}$ phase, was observed due to segregation near the ${\gamma}-{\gamma}^{\prime}$ eutectic in the standard heat-treated specimen. Segregation also induced microstructural evolution near the ${\gamma}-{\gamma}^{\prime}$ eutectic during the standard heat treatment. A quantitative analysis and microstructural observations showed that the thermal exposure at a high temperature enhanced the chemical homogeneity of the alloy.

• Journal of the Korean Vacuum Society
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• v.7 no.s1
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• pp.37-43
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• 1998

The mechanism of interaction between low energy ions and biological organisms has been paid much attention recently. In order to clarify the microstructural response to low energy ion irradiation embryonic cells of Paeonia rockii L. implanted by $Fe^{1+}$ ions with the energy of 80KeV were investigated by Optical Microscopy (OM), Scanning electron Microscopy(SEM) and Transmission Electron Microscopy(TEM). At the dose of 1$\times$1015 ions/$\textrm{cm}^2$, apparent cellular damage was observed in the outer several layers of the radicle. The shape of the cells was obviously deformed from regular polygon to irregular. The cell walls became obscure. SEM micrographs showed that the surface of the radicle was etched severely. It was observed by TEM that nucleus of the implanted cell was elongated and tended to fracture. Nuclear envelope lost its integrity. The implanted $Fe^{1+}$ ions were detected by Energy Dispersive Spectroscopy (EDS). These observations showed that low energy ions could damage to the plant organisms with the thickness of about 30~50$\mu\textrm{m}$. The possible reasons for radiation damage in the biological organisms were discussed.

• Journal of Powder Materials
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• v.25 no.1
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• pp.36-42
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• 2018

In order to expand the application of oxide dispersion-strengthened (ODS) steel, a composite material is manufactured by adding mechanically alloyed ODS steel powder to conventional steel and investigated in terms of microstructure and wear properties. For comparison, a commercial automobile part material is also tested. Initial microstructural observations confirm that the composite material with added ODS steel contains i) a pearlitic Fe matrix area and ii) an area with Cr-based carbides and ODS steel particles in the form of a $Fe-Fe_3C$ structure. In the commercial material, various hard Co-, Fe-Mo-, and Cr-based particles are present in a pearlitic Fe matrix. Wear testing using the VSR engine simulation wear test confirms that the seatface widths of the composite material with added ODS steel and the commercial material are increased by 24% and 47%, respectively, with wear depths of 0.05 mm and 0.1 mm, respectively. The ODS steel-added composite material shows better wear resistance. Post-wear-testing surface and cross-sectional observations show that particles in the commercial material easily fall off, while the ODS steel-added material has an even, smooth wear surface.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.547-550
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• 2005

Recently, there has been a intensive social interest for concrete structures with respect to durability by carbonation, chemical attack etc. Specially, the deterioration of concrete due to chemical attack in environments such as Wastewater Treatment Facilities is important factors degrading the durability of concrete structure. The purpose of this paper is to evaluate on deterioration of Wastewater Treatment Facilities concrete to chemical attack through instrumental analysis such as XRD, SEM and EDS. According to the results of this study. Wastewater Treatment Facilities concrete to chemical attack due to $So_{4}^{2-},\;Mg^{2+}$ ions founded out to appear deterioration materials peak : ettringite/thaumasite. gypsum and brucite peak.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.209-212
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• 2006

Until now, sulfate attack is not completely understood. The purpose of this study is to provide a fundamental data to understand deterioration mechanism by sulfate attack. Chemical processes for products formed by sulfate attack were explained in this study. ASTM C1012 test and microstructural observations such as XRD and BSE analysis were carried out to manifest behavior and role of the products formed during sulfate attack. Regarding the dominant causes of sulfate attack, the main deterioration modes could be divided into 3 types; (1) expansive type, (2) onion-peeling type, and (3) acidic type.

• Applied Microscopy
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• v.27 no.3
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• pp.257-263
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• 1997

Microstructural characterizations of II-VI blue laser diodes which consist of quaternary $Zn_{1-x}Mg_xS_ySe_{l-y}$ cladding layer, ternary $ZnS_ySe_{l-y}$ guiding layer and $Zn_{0.8}Cd_{0.2}Se$ quantum well as active layer were carried out using the transmission electron microscope working at 300 kV. Even though the entire structure is pseudomorphic to GaAs substrate, the structure had contained numerous extended stacking faults and dislocations which had created at ZnSe/GaAs interfaces and then further grown to the top of the epilayers. These faults might be expected to cause the degradation and shortening the lifetime of laser devices.

• Journal of the Korean Society for Heat Treatment
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• v.11 no.4
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• pp.283-294
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• 1998

This paper presents an investigation why Mn-steel high pressure gas cylinders have been failed in service. The fractured cylinders have been collected to identify the reason of the failure using various methods. The undamaged, new cylinder has also been tested for the base data. We examined the chemical compositions and fracture facets as well as the mechanical properties of the vessels. The microstructural observations of the fractured regions of the cylinder did not indicate the noticeable defects which might cause the failure. The experiments of cylinders on the compositinal and mechanical tests showed that the cylinder was in good shape according the standards of gas pressure vessel. The morphological analysis of the fracture surfaces concluded that the origin of the failure was the local weak segments induced by the external impact to the cylinder, which result in a sudden, fast fracture.