• Fibers and Polymers
• /
• 제2권1호
• /
• pp.157-162
• /
• 2001

Dyebath used for metal complex dyeing of nylon microfiber was recycled to reduce the overall amounts of metal complex dyeing effluents. Instead of discharging the dyebath after each dyeing cycle, the residual dyebath was analyzed spectrophotometrically and reconstituted to the required concentration of dyes and auxiliaries. Dyebaths were reused eight times and the CIELAB coordinates of dyed samples were measured after each recycling. Color difference($\Delta$E*) between the sample dyed in the fresh bath and that from reused dyebath was maintained below 1.5. The levelness and fastness of dyed fabrics from recycled dyebath were not impaired either. Chromium content of each recycled dyebath was similar to that of the first residual dyebath.

• 한국염색가공학회지
• /
• 제12권1호
• /
• pp.68-75
• /
• 2000

In this study, polyester DTY faille(yoryu) and N/NP microfiber fabrics were pretreated (desizing, scouring and shrinking) by Continuous Scouring and Shringking Equipment with rota-drum and conveyor type in which types were different with retaining method. The results were as follows. The shrinkage ratio of wp/wf direction of DTY fabrics scoured by conveyor type was 1.5/23% higher than those by rota-drum type at $97^\circ{C}$ with 10min. treatment. In this case, The shrinkage ratio of wp/wf direction by those types was about 15/27%, respectively. The shrinkage ratio of wp/wf direction of N/NP microfiber fabrics scoured by conveyor type was 1.5/23% higher than that by rota-drum type at $97^\circ{C}$ with 10min. treatment. The size add-on of DTY fabrics scoured at $97^\circ{C}$ with 10min. treatment by conveyor type and by rota-drum type were 0.15% and 0.42%, respectively. The size add-on of DTY fabric treated by rota-drum type decreased until 9min. of treated time, but increased after 9min. The size add-on of N/NP microfiber fabrics treated by conveyor type was decreased by increasing temperature and treated time, while the size add-on of that treated by rota-drum type was decreased until 6min. treated time and increased after 6min. The size add-on of N/NP microfiber fabrics treated by conveyor type at $97^\circ{C}$ for 10min. was 0.3% lower than that by rota-drum type.

• 대한가정학회지
• /
• 제36권8호
• /
• pp.95-104
• /
• 1998

PET microfiber fabric dissociation reactions by ethylene glycol (EG) catalayzed by the corresponding EG anions were examined to provide an empirical basis for the improvement of a PET microfiber fabrics. The alkoxide ions, monosodium ethylene glycolate in ethylene glycol solution(MSEG-EG) are prepared by the reaction between NaH and the EG respectively. The dissociation reactions were carried out until the sample PET microfiber fabrics dissociate up to 80%. Temperature used ranged 100~$160^{\circ}C$. The kinetic behaviors of the dissociated PET microfiber fabrics were examined. The results are as follows : 1. In all cases, it was found that the PET-alkoxide dissociation rate constants increased exponentially with increasing temperature. The activation energies (Ea) of the reactions were 23.31kcal/mol in PET-EG system respectively. The calculated enthalpies of the activated [PET-EG] complexes from the corresponding Ea values were 22.53 ~ 22.61 kcal/mol, and the entropies were -19.03 ~ -19.24 kcal/mol/k respectively. 2. The kinetic behavior of the PET-alkoxide dissociation reactions examined was explained by the transition state theory. PET-alkoxide transition state is believed to be formed during the ester interchange mechanism between PET and MSEG-EG in the course of the PET dissociation reactions.

• 한국염색가공학회지
• /
• 제35권3호
• /
• pp.179-187
• /
• 2023

In this study, we developed a microfiber-based flexible pressure sensor with high sensitivity and excellent skin breathability. A nonwoven fabric composed of microfibers was prepared by electrospinning, which resulted in excellent moisture permeability of the sensor (143 g∙m^-2∙h^-1). In particular, high-pressure sensitivity (0.36 kPa^-1) was achieved by introducing submicron structures on the microfiber surface by controlling the ambient humidity during electrospinning. The fabrication technology of the microfiber-based flexible pressure sensors reported in this study is expected to contribute to the commercialization of flexible pressure sensors applicable to long-term wearable health monitoring as well as virtual/augmented reality and electronic skin applications.

• 한국의류산업학회지
• /
• 제3권5호
• /
• pp.466-472
• /
• 2001

To find a suitable condition in this process examined, we investigated the main control factors, such as, the NaOH concentrations, such as, the NaOH concentrations, the heat treating times, and the heating temperatures. The resulting mechanical properties of the fabrics also studied. The samples used were Nylon/Co-PET sea-island type composite microfiber (Co-PET content: 35%) non-woven fabric. The conclusions obtained were as follows. 1. For the complete extraction of Co-PET from the sample non-woven fabric in the dry hot air process, $160^{\circ}C$ of air temperature, 15 min. of treatment time, and around 30% of NaOH concentration were required. On the other hand, in the wet hot air process, $140^{\circ}C$ of air temperature, 3.5 min. of treatment time, and around 30% of NaOH concentration were required. 2. The mechanical properties of the continuous processed samples showed that the WT, B, and WC increased with increasing the weight reduction ratio. However, the G, decreased with increasing the weight loss ratio. Note that, particularly in B, it increased drastically when the weight deduction ratios exceeded 30%. 3. As increasing the wet hot air temperature from 130 to $140^{\circ}C$, B appeared to increase, however, WT, G, and WC appeared to decrease. 4. The best condition found in this continuous process to extract Co-PET is the wet hot air temperature of 140, NaOH concentration of 28% or above, and the treatment time 2-4 min.

• 한국염색가공학회지
• /
• 제16권1호
• /
• pp.40-47
• /
• 2004

Alkaline treatment gives Sea-Island type yam to produce microfiber and silk-like touch. But this treatment have some problems in dyeing and finishing process. To solve some problem occurred in dyeing and finishing of polyester fabric, the ultrasonic treatment technique was used recently. This study was carried out to confirm the effect of the ultrasonic treatment on alkaline weight loss finishing of polyester fiber under general alkaline treatment conditions; NaOH concentration 2, 3, 4, and 5％, treatment time 5, 10, 15, and 20 minutes, treatment temperature 70, 80, 90, and 99'E, respectively. On the other hand, the three way lay out method was used to test of significant obtained data from alkaline treatment. It was found that weight loss increased with increasing the NaOH concentration, temperature, and time. Also, in case of PET/Co-PET fabrics by ultrasonic, weight loss and dissolution of microfiber were superior to PET/Co-PET fabrics without ultrasonic. Tensile strength and modulus decreased with increasing NaOH concentrations and hydrolysis time. Therefore, the effect of alkali hydrolysis by ultrasonic application was better than that of the conventional method.

• Fibers and Polymers
• /
• 제6권1호
• /
• pp.82-88
• /
• 2005

We have investigated the luster of modified cross-sectional fiber fabrics as one of the essential quality estimates for clothing development. We have confirmed an objective evaluation method, and have determined the experimental luster char­acteristics of modified cross-section fibers. The cross-section of the fibers in a fabric affects the appearance of a textile. We used the image analysis method to investigate the luster to determine the critical factors influencing the appearance of modi­fied cross-section fiber fabrics. For similarly structured textiles in a component fabric, clear differences were observed in the fabric weave, density, percentage, and total area of blobs, which is image region. Color played a decisive role in the luster of the textiles, and luster was not significantly influenced by the modified cross-section fabric weave. In addition, the degree of luster did not increase in the order plain to twill to satin for modified cross-sectional fiber fabrics. All the split-type microfi­bers exhibited higher numerical luster values (percentage of pixels, and number and total area of blobs) than sea-island microfibers did. The degree of luster of the modified cross-sectional fiber fabrics was not high at specular reflection angles.

• 한국염색가공학회지
• /
• 제8권3호
• /
• pp.36-51
• /
• 1996

In order to investigate the degradation behavior of PET fabrics, sodium diethylene glycolate (SDEG)-diethylene glycol (DEG) solutions were prepared and PET fabrics were treated in the solution. The dissolution rate constant and apparent activation energy of the PET fabrics were calculated by Eyring's and Arrhenius's equation respectively and measured dyeing properties, moisture and antistatic properties. Then compared SDEG-treated fabrics with NaOH-treated. The results were as follows; 1. PET fabrics decreased their weight in SDEG-DEG solution, and the decreasing rate showed a linear relationship to the treating time at constant temperature and concentration of SDEG-DEG solution. 2. The dissolution rate constant showed a linear relationship to the concentration of SDEGDEG solution and an exponential relationship to treating temperature. 3. Apparent activation energy of dissolution was 23.45 kcal/mol. 4. The K/S values and the ΔL values of fabrics treated with SDEG-DEG solution are higher and lower respectively than fabrics treated with NaOH. 5. SDEG-DEG solution treatment improved fabric's moisture regain and it reached almost maximum at about 40% weight loss. 6. In the both reagent the light, wet and sublimation fastness of fabrics are similar. 7. SDEG-DEG solution gave more electrical discharge effect to the fabrics than that of NaOH. 8. NaOH treated PET microfiber have crater-like surface, while SDEG-DEG solution give bathochromic effect to the PET microfiber because which has wrinkles on the surface.

• 한국염색가공학회지
• /
• 제11권2호
• /
• pp.9-18
• /
• 1999

In order to establish fundamental data for the betterment of Polyester microfiber fabric handle, a study by using fixed warp of ITY yarn samples with P/F, DTY, and ITY weft yarns was performed. For this purpose the samples of total 27 kinds were prepared. That is, each sample yarn was twisted in three ways and for each twisted yarn the fabric structures were modified in three ways, plain, twill, and satin. The examination was done by focusing on the point of the change of handles and the characteristics of the mechanical properties of the samples with the change of yarn and the fabric structure. The handles and the mechanical properties were examined with the KES-F system suggested by Kawabata. The results were as follows : 1. WT and MIU increased with increasing the twist. By comparing WT and MIU by yarn, DTY was higher than P/F. It appeared that twill and satin were higher than plain. 2. The bending rigidity change in DTY with increasing the twist was not significant, however in P/F it appeared apparently decreased with increasing the tlvist. Also, it appeared that when using P/F as weft the bending rigidity was higher than when using DTY and the twill structure appeared higher than the satin structure. 3. In shear force the increasing rates of plain and the twill were higher than satin. When DTY and P/F were used as weft, the shear force was higher in ITY and DTY than in P/F case. 4. Koshi appeared higher in the order of plain, twill and satin. When DTY and P/F were used as the weft Koshi increased with increasing the twist in plain, however in twill and satin it appeared to decrease. In hand value ITY(=7.5) appea.ed to be highe. than DTY and P/F(=6.5). 5. In all cases Shinayakasa decreased with increasing the twist. The hand values observed that satin was =4, twill was =3, and plain was =1.5. 6. Fukurami showed no significant change with increasing the twist in DTY, however in P/F and ITY it decreased.

• 한국염색가공학회지
• /
• 제34권3호
• /
• pp.135-145
• /
• 2022

In this study, the dyeability of 0.06-denier-per-filament (dpf) ultrafine sea-island-type nylon knitted fabric was investigated and compared with that of 1.0-dpf general nylon with respect to four types of dyes. In particular, leveling, milling, half-milling, and metal-complex dyes were compared at concentrations of 0.5%, 1.0%, 2.0%, 4.0%, and 8.0% on-weight-fabric (o.w.f). In each case, staining was performed at 100 ℃. The dyeabilities of the materials were compared in terms of the depth of color as defined by the ratio of the absorption coefficient (K) to the scattering coefficient (S). Results indicated generally low K/S values for both the 0.06-dpf ultrafine sea-island-type nylon and 1.0-dpf general nylon. In terms of the dye type, the milling and half-milling dyes exhibited K/S values of ≥20 for all colors of yellow, red, and blue for the 0.06-dpf ultrafine yarn sea-island-type nylon, which were superior to those of the other dye types. Hence, the milling and half-milling dyes are considered more suitable than the other dyes. Further, a comparison of dye fastness and compatibility revealed that the half-milling dye was the most suitable dye for the 0.06-dpf ultrafine sea-island-type nylon.