• 한국재료학회지
• /
• 제31권7호
• /
• pp.409-419
• /
• 2021

The effect of solidification rate on micro-segregation in investment casting of IN738LC superalloy was studied. In Ni-based superalloys, the micro-segregation of solute atoms is formed due to limited diffusion during cast and solidification. The microstructure of cast Ni-based superalloys is largely divided into dendrite core of initial solidification and interdendrite of final solidification. In particular, mosaic shaped eutectic γ/γ' and carbides are formed in the interdendrite of the final solidification region in some cases. The micro-segregation phenomena formed in regions of dendrite core and interdendrite including eutectic γ/γ' and carbides were analyzed using OM, SEM/EDS and micro Vickers hardness. As a result of analysis, the lack of (Cr, W) and the accumulation of Ti were measured in the eutectic γ/γ', and the accumulation of (Cr, Mo) and the lack of Ti were measured in the interdendrite between dendrite and eutectic. Carbides formed in interdendritic region were composed of (Ti, W, Mo, C). The segregation applied to each microstructure is mainly due to the formation of γ' with Ni₃(Al,Ti) composition. The Ni accumulation accompanied by Cr depletion, and the Ti accumulated in the eutectic region as a γ' forming elements. The Mo tends to diffuse out from the dendrite core to the interdendrite, and the W diffuse out from the interdendrite to the dendrite core. Therefore, the accumulation of Mo in the interdendrite and the deficiency of W occur in the eutectic region located in the interdendrite. Heat treatment makes the degree of the micro-segregation decrease due to the diffusion during solid solution. This study could be applied to the heat treatment technology for the micro-segregation control in cast Ni-based superalloys.

• 한국주조공학회지
• /
• 제17권1호
• /
• pp.28-35
• /
• 1997

SiC whisker and $Al_2O_3-SiO_2$ short fiber reinforced AC8A, AC8B and AC8B(J) marix composites were fabricated by squeeze casting method. Preform deformation, change of reinforcement volumefraction and formation of macro-segregation in two composites were investigated by using micro Vickers hardness test, analysis of macro and micro structures with OM, SEM and EDAX. $Al_2O_3-SiO_2$ short fiber preform manufactured with 5% $SiO_2$ binder in this study was considerably deformed and cracked, nevertheless, the short fibers were distributed homogeneously in the composites. In SiC whisker reinforced composites, on the other hand, preform deforming and cracking were not occurred, however, macro segregation zone formed along the infiltration routes by interface reaction during infiltration of molten metal into the preform was observed at center-low area in the composites. The decrease of hardness in the macro segregation zone resulted from the depletion of Si and Mg atoms.

• 한국해양공학회지
• /
• 제16권2호
• /
• pp.72-79
• /
• 2002

In this study, time-dependent distributions of temperature and stresses, in the box-column welded from ultra thick plates with center segregation, has been analyzed by the commercial finite element package SYSWELD+, for several types and angles of groove. The major points of investigation are the optimum type and angle of groove that minimize weld stress specially at the center segregation, as well as temperature distribution, residual stresses and changes in the mechanical properties. The results can be summarized as follows; 1) Generally the thermal cycle at the root of groove exhibits relatively rapid cooling pattern, however, most of the other part weldment have a slow cooling pattern in all groove types. 2) Most of the micro-structures of weldment are composed of ferrite and pearlite, meanwhile we could find martensite and bainite locally a the root of the groove. 3) Optimum groove type for high heat input welding of box-column corner is a double groove type, and the optimum angle for the groove is 30~$45^{\circ}$ that minimize deformation and weld stress at the center segregation.

• 한국경제지리학회지
• /
• 제18권1호
• /
• pp.1-16
• /
• 2015

세계화와 산업구조조정으로 사회경제적 양극화가 진행됨에 따라 계층 간 거주지 분리가 심화될 것으로 여겨진다. 본 연구는 한국사회에서 1990년대 말 경제위기로 사회경제적 양극화가 급진전했음을 주목하고 이가 도시 내 거주지 분리에 미친 영향을 살펴보고자 하였다. 서울시를 사례로 2000년대를 걸쳐 일어난 계층별 거주지 분리의 변화를 분석하였다. 계층은 교육수준으로 정의되었으며 자료는 동별로 통계청 마이크로데이터서비스시스템(MDSS)을 통해 추출하였다. 거주지 분리의 주요 지리적 양태별로 개별 도시에서 시계열적 변화를 가늠하는 전역적 측도와 도시 내 공간적 변이를 보여주는 국지적 측도를 활용하였다. 구체적으로 집중-균등을 측정하기 위해 전역적 지표로 상이지수를 그리고 국지적 지표로 입지계수를 활용하였으며 군집-노출을 측정하기 위해 전역적 지표로는 상호작용지수와 노출지수를 국지적 지표로는 로컬 Moran's I를 활용하였다. 분석 결과, 사례지역에서 계층별 거주지 분화가 심화되었으며 도시내에서 뚜렷한 공간적 패턴을 보이고 있으며 계층 간 거주 패턴은 상호 연관되어 있음이 밝혀졌다. 본 연구는 국내 수위 도시에서 경제 위기 이후 거주지 분리의 최근 변화상을 보다 체계적인 방법으로 파악하였다는데 그 의의가 있다.

• Corrosion Science and Technology
• /
• 제16권6호
• /
• pp.305-316
• /
• 2017

Austenitic stainless steels have been widely used for various systems of nuclear power plants. Among these stainless steels, small pipes with diameter less than 14 inch have been produced in the form of seamless pipe. Annealing and cooling process during the manufacturing process can affect corrosion properties of seamless stainless steels. Therefore, 12 inch-diameter of as-received 304L stainless steel pipe was annealed and aged in this study. Intergranular corrosion resistance was evaluated by ASTM A262 Practice A, C, and E methods. The degree of sensitization was determined using a DL-EPR test. U-bend method in an autoclave was used to evaluate the SCC resistance in 0.01 M $Na_2S_4O_6$ or 40% NaOH solution at $340^{\circ}C$. As-received specimen showed relatively high degree of sensitization and intergranular corrosion rate. Carbon segregation was also observed near grain boundaries. Annealing treatment could give the dissolution of segregated carbon into the matrix. Aging treatment could induce segregation of carbon and finally form carbides. Microstructural analysis confirmed that high intergranular corrosion rate of the as-received seamless pipe was due to micro-galvanic corrosion between carbon segregation and grains.

• 한국주조공학회지
• /
• 제16권2호
• /
• pp.149-157
• /
• 1996

Several aluminum based alloys were fabricated by a twin roll strip casting mill. As-cast microstructures and microsegregations of these aluminum alloys were investigated by means of optical microscope, scanning electron microscope and electron probe micro analysis. Clear distinction on microsegregation among the alloy systems was observed, that is, A1235 and A8011 alloys showed diffused segregation in the middle of the strip, while A3003 and A5086 alloys revealed a centerline segregation consisted of lamellar structure. Above center line segregation was resulted from enrichment of the alloying elements such as Mn, Fe, Cu, Si and eutictic reaction in central region of the alloy strip.

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 2007년도 추계학술발표대회 및
• /
• pp.80.2-80.2
• /
• 2007

• 한국자기학회:학술대회 개요집
• /
• 한국자기학회 2012년도 임시총회 및 하계학술연구발표회
• /
• pp.102-102
• /
• 2012

• 한국가스학회지
• /
• 제24권5호
• /
• pp.39-46
• /
• 2020

본 논문에서는 파이프라인에서 사용되는 API 5L 철강의 중심선 편석에 대해 다루고자 한다. Mn/S와 Nb 그리고 C는 파이프 두께 방향으로의 중심선에서 편석되는 요소로 알려져 있다. Mn은 일반적으로 긴 점성상을 이루는 S를 동반한다. 중심선의 미세조직은 MnS와 산소를 포함한 Nb/Ti로 구성되어 있는데 이 중심선 지역의 편석효과를 OM, SEM/EDS 및 마이크로비커스 경도기로 분석하였다. Mn, Nb 및 C는 오스테나이트가 페라이트 또는 마르텐사이트로 변태하는 것을 억제시키는 원소이다. 이러한 원소들은 마르텐사이트의 한 종류인 베이나이트 미세조직을 만들 수 있는데 이는 용융 및 열처리에서 얻어지는 중심선과 매트릭스 간의 원소 편석과는 다르다.

• 대한기계학회논문집B
• /
• 제21권10호
• /
• pp.1303-1313
• /
• 1997

A micro-macroscopic analysis on the conduction-controlled directional casting of Al-Cu alloys is performed, in which emphases are placed on the microstructural features. In order to facilitate the solution procedure, an iterative micro-macroscopic coupling algorithm is developed. The predicted results show that the effect of finite back diffusion on the transient solidification process in comparison with the lever rule depends essentially on the initial concentration of an alloy. In the final casting, the eutectic fraction is distributed in an increasing-decreasing-increasing pattern, each mode of which is named the chill, interior and end zones. This nonuniformity per se suffices to justify the necessity of this work because it originates from the combined effects of finite back diffusion and cooling path-dependent nature of the eutectic formation. As the cooling rate is enhanced, not only the influence depths of boundaries narrow, but also the eutectic fractions in the chill and interior zones increase. In addition, it is revealed for the first time that the micro segregation band is formed in response to a sudden change in cooling rate during the directional casting. An increasing change creates an overshooting band in the eutectic fraction distribution, and vice versa.