• 한국레이저가공학회:학술대회논문집
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• 한국레이저가공학회 2005년도 추계학술발표대회 논문집
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• pp.105-108
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• 2005

• 한국지반공학회논문집
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• 제22권10호
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• pp.77-91
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• 2006

국내 숏크리트 관련 기술들은 지금까지 많은 발전을 이루어 왔으나 재료, 시공 및 관련 품질규격 등에서 여전히 문제들을 가지고 있다. 국외의 경우 $39.2{\sim}58.8 MPa$에 이르는 고강도 숏크리트 시공이 가능하여 터널에서 2차 라이닝의 대체나 장기내구성의 확보가 충분히 가능한 반면, 국내의 경우 설계강도가 20.6MPa 내외로 낮은 편이며 장기내구성도 신뢰하지 못하고 있는 실정이다. 본 연구에서는 국내 숏크리트의 강도 증진을 위해 고품질 혼화재와 고성능 급결제를 적용한 현장실험을 실시하였고, 유럽통합규격(EFNARC)에 의거하여 품질평가를 수행하였다. 또한, 탄산화와 동결융해의 복합인자에 의한 열화시험을 수행하여 고강도 숏크리트의 장기내구성을 평가하였다. 실험결과 알칼리 프리계 급결제를 사용한 경우 초기강도 증진율이 $90{\sim}97%$로 가장 높게 나타났고, 실리카 흄을 혼입한 숏크리트의 압축강도는 $45.2{\sim}55.8MPa$, 휨강도는 $5.01{\sim}6.66MPa$로 혼입하지 않은 경우에 비해 각각 $37{\sim}79%$, $17{\sim}61%$의 강도 증진 효과가 나타났다. 또한, 실리카 흄 치환율이 $7.5{\sim}10%$일 때 강도증진 효과가 가장 우수한 것으로 나타났다. 특히, 실리카 흄의 치환은 강섬유 혼입에 의한 숏크리트의 열화현상을 최소한으로 감소시켜, 숏크리트의 장기내구성을 확보하는데 효과가 있음을 알 수 있었다.

• 대한토목학회논문집
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• 제26권2C호
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• pp.121-131
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• 2006

국내 숏크리트 강도기준은 고강도 숏크리트의 개발과 적용이 활발한 유럽과 비교해 볼 때 상대적으로 낮게 설정되어 있어서 고강도 숏크리트의 품질을 평가하기에는 어려움이 있다. 본 연구에서는 국내 숏크리트의 강도증진과 장기 내구성을 향상시킬 수 있는 방법을 모색하기 위해 현장실험을 실시하였다. 현장실험은 고품질 혼화재와 고성능 급결제를 적용한 고강도 숏크리트를 지향하였고, 숏크리트의 강도증진에 미치는 혼화재와 급결제의 영향을 파악하고자 하였다. 그리고 유럽통합규격(EFNARC)에 의거하여 품질평가를 수행하였는데, 실험결과 알칼리프리계 급결제를 사용한 경우의 초기강도 증진율이 90~97%로 가장 높게 나타나 초기강도 증진효과에 알칼리프리계 급결제가 효과적이었다. 또한, 실리카 흄을 혼입한 숏크리트는 압축강도가 45.2~55.8MPa, 휨강도가 5.01~6.66MPa로 혼입하지 않은 경우에 비해 각각 37~79%, 17~61%의 강도증진 효과가 나타났고, 실리카 흄 치환율은 7.5~10%일 때 강도증진 효과가 가장 우수한 것으로 나타났다. 현장실험 결과 국내 숏크리트의 고강도화를 위해서는 알카리프리계 급결제와 실리카 흄과 같은 고품질 혼화재의 사용이 필요할 것으로 판단된다.

• Structural Engineering and Mechanics
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• 제51권1호
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• pp.1-13
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• 2014

This paper reports an experimental study into the rheological behaviour of self consolidating concrete (SCC). The investigation aimed at quantifying the impact of the varying amounts of mineral admixtures on the rheology of SCC containing natural sand. Apart from the ordinary Portland cement (OPC), the cementitious materials such as fly ash (FA), ground granulated blast furnace slag (GGBS) and micro-silica (MS) in conjunction with the mineral admixtures were used in different percentages keeping the mix paste volume and flow of concrete constant at higher atmospheric tempterature ($30^{\circ}$ to $40^{\circ}C$). The rheological properties of SCC were investigated using an ICAR rheometer with a four-blade vane. The rheological properties of self-consolidating concrete (SCC) containing different mineral admixtures (MA) were investigated using an ICAR rheometer. The mineral admixtures were fly ash (FA), ground granulated blast furnace slag (GGBS), and micro silica (MS). The results obtained using traditional workability results are compared with those obtained using ICAR rheometer. The instrument ICAR (International Center for Aggregate Research) rheometer employed in the present study for evaluating the rhelogical behaviour of the SCC is found to detect systematic changes in workability, cementitious materials, successfully. It can be concluded that the rheology and the slump flow tests can be concurrently used for predicting the flow behaviours of SCC made with different cementitious materials.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.705-710
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• 2001

So for the quartz-glassy crucible wastes which was used for pulling up silicon-single-crystal ingot have simply reused for refractory raw-materials, or exhausted. This study is concerned on the advanced recycling-technology that is obtained by the proper micro-particle preparation process in order to fabricate fine amorphous silica filler for EMC (Epoxy Molding Compound). Therefore, this paper will deal with the physical, chemical and thermal pre-treatment process for efficient impurity removal and with the proper micro-particle process for producing the amorphous silicafiller. In view of the results, if the chemical, physical and thermal pre-treatment process for efficient elimination of impurity was passed, the purity of wasted fused glassy crucible is almost equal to the its of first anhydrous quartz glass. Thus, it was understood that this wasted fused glassy crucible was sufficient value of recycling, though it was damaged. When the ingot was fabricated, Phase transformation of crystallization by heat treatment (heat hysteresis phenomenon) was not changed. So, it was understood that as fused silica in the amorphous state, as It is, recycling possibility was very high

• 한국표면공학회지
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• 제29권6호
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• pp.788-796
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• 1996

$TiO_2$ films prepared by RF magnetron sputtering, electron beam evaporation, ion assisted deposition (IAD) and sol-gel method are prepared on c-Si substrate and vitreous silica substrate respectively. From the transmission spectra of $TiO_2$ films on vitreous silica substrate in the spectral region from 190 nm to 900 nm, k($\lambda$) of $TiO_2$ is obtained. Using k($\lambda$) in the interband transition region the coefficients of the quantum mechanical dispersion relation of an amorphous $TiO_2$ and hence n($\lambda$) including the optically opaque region of above fundamental transition energy are obtained. The spectroscopic ellipsometry spectra of $TiO_2$ films in the spectral region of 1.5-5.0eV are model analyzed to get the film packing density variation versus i) substrate material, ii) film thickness and iii) film growth technique. The complex refractive index change of these $TiO_2$ films versus water condensation is also studied. Film micro-structures by SE modelling results are compared with those by atomic force microscopy images and X-ray diffraction data.

• Korean Membrane Journal
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• 제6권1호
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• pp.16-23
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• 2004

The silica containing carbon (C-SiO$_2$) membranes were fabricated using poly(imide siloxane) (PIS) having -CO- swivel group. The characteristics of porous C-SiO$_2$ structures prepared by the pyrolysis of poly(imide siloxane) were related with the micro-phase separation between the imide block and the siloxane block. Furthermore, the nitrogen adsorption isotherms of the CMS and the C-SiO$_2$ membranes were investigated to define the characteristics of porous structures. The C-SiO$_2$ membranes derived from PIS showed the type IV isotherm and possessed the hysteresis loop, which was associated with the mesoporous carbon structures, while the CMS membranes derived from PI showed the type I isotherm. For the molecular sieving probe, the C-SiO$_2$ membranes pyrolyzed at 550, 600, and 700$^{\circ}C$ showed the O$_2$ permeability of 924, 1076, and 367 Barrer (1 ${\times}$ 10$\^$-10/㎤(STP)cm/$\textrm{cm}^2$$.$s$.$cmHg) and O$_2$/N$_2$ selectivity of 9, 8, and 12.

• Computers and Concrete
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• 제22권2호
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• pp.183-196
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• 2018

The rheological behaviour of high strength self compacting concrete (HS-SCC) studied through an experimental investigation is presented in this paper. The effect of variation in supplementary cementitious materials (SCM) $vis-{\grave{a}}-vis$ four different types of processed crushed sand as fine aggregates is studied. Apart from the ordinary Portland cement (OPC), the SCMs such as fly ash (FA), ground granulated blast furnace slag (GGBS) ultrafine slag (UFS) and micro-silica (MS) are used in different percentages keeping the mix -paste volume and flow of concrete, constant. The combinations of rheology, strength and durability are equally important for selection of mixes in respect of high-rise building constructions. These combinations are referred to as the rheo-strength and rheo-durability which is scientifically linked to performance based rating. The findings show that the fineness of the sands and types of SCM affects the rheo-strength and rheo-durability performance of HS-SCC. The high amount of fines often seen in fine aggregates contributes to the higher yield stress. Further, the mixes with processed sand is found to offer better rheology as compared to that of mixes made using unwashed crushed sand, washed plaster sand, washed fine natural sand. The micro silica and ultra-fine slag conjunction with washed crushed sand can be a good solution for high rise construction in terms of rheo-strength and rheo-durability performance.

• 한국세라믹학회지
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• 제48권5호
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• pp.454-457
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• 2011

We report the preparation of nanocrystalline cobalt ferrite, $CoFe_2O_4$, particles using recycled $Co_3O_4$ and their surface coating with silica using micro emulsion method. Firstly, the $Co_3O_4$ powders were separated from waste cemented carbide with acid-base chemical treatment. The cobalt ferrite nanoparticles with the size 10 nm are prepared by thermal decomposition method using recycled $Co_3O_4$. $SiO_2$ was coated onto the $CoFe_2O_4$ particles by the micro-emulsion method. The $SiO_2$-coated $CoFe_2O_4$ particles were studied their physical properties and characterized by X-ray diffraction (XRD), high resolution-transmission electron microscopy (TEM) analysis and CIE Lab value.

• Tribology and Lubricants
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• 제22권4호
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• pp.182-189
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• 2006

In this paper, the adhesion characteristics between a fused silica without or with an anti-sticking layer and a thermoplastic polymer film used in thermal NIL were investigated experimentally in order to identify the release performance of the anti-sticking layer. The anti-sticking layers were derived from fluoroalkylsilanes, (1H, 1 H, 2H, 2H-perfluorooctyl)trichlorosilane ($F_{13}-OTS$) and (3, 3, 3-trifluoropropyl)trichlorosilane (FPTS), and coated on the silica surface in vapor phase. The commercial polymers, mr-I 7020 and 8020 (micro resist technology, GmbH), for thermal NIL were spin-coated on Si substrate with a rectangular island which was fabricated by conventional microfabrication process to achieve small contact area and easy alignment of flat contact sur- faces. Experimental conditions were similar to the process conditions of thermal NIL. When the polymer film on the island was separated from the silica surface after imprint process, the adhesion force between the silica surface and the polymer film was measured and the surfaces of the silica and the polymer film after the separation were observed. As a result, the anti-sticking layers remarkably reduced the adhesion force and the surface damage of polymer film and the chain length of silane affects the adhesion characteristics. The anti-sticking layers derived from FPTS and $F_{13}-OTS$ reduced the adhesion force per unit area to 38% and 16% of the silica sur-faces without an anti-sticking layer, respectively. The anti-sticking layer derived from $F_{13}-OTS$ was more effective to reduce the adhesion, while both of the anti-sticking layers prevented the surface damages of the polymer film. Finally, it is also found that the adhesion characteristics of mr-I 7020 and mr-I 8020 polymer films were similar with each other.