• Title/Summary/Keyword: micro fuel cell

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Thermal and Mechanical Properties of Epoxy/Micro- and Nano- Mixed Silica Composites for Insulation Materials of Heavy Electric Equipment

  • Park, Jae-Jun;Yoon, Ki-Geun;Lee, Jae-Young
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.3
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    • pp.98-101
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    • 2011
  • A 10 nm nano-silica was introduced to a conventional 3 ${\mu}M$ micro-silica composite to develop an eco-friendly new electric insulation material for heavy electric equipment. Thermal and mechanical properties, such as glass transition temperature (Tg), dynamic mechanical analysis, tensile and flexural strength, were studied. The mechanical results were estimated by comparing scale and shape parameters in Weibull statistical analysis. The thermal and mechanical properties of conventional epoxy/micro-silica composite were improved by the addition of nano-silica. This was due to the increment of the compaction via the even dispersion of the nano-silica among the micro-silica particles.

A Micro PEM Fuel Cell System Including a Hydrogen Generator (수소 발생기를 포함한 마이크로 PEM 연료전지 시스템)

  • Kim, Dae-Joong;Zhu, L.;Shannon, M.A.;Masel, R.I.
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.558-559
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    • 2008
  • 본 논문은 미 일리노이 주립대 어바나-샴페인 캠퍼스에서 주로 군사용 응용 관련하여 개발 중인 마이크로 PEM 연료전지 시스템 개발에 대한 논문이다. 본 연구는 수소 저장 장치까지 포함하여 1 $mm^3$의 초소형 연료전지 시스템을 목표로 진행 중이며 본 논문은 이러한 진행 과정 중 화학적 하이드라이드 기반의 수소 발생기와 10 $mm^3$의 시스템 개발 과정에 대해 보고한다.

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A Simulation Study of the Effect of Microstructural Design on the Performance of Solid Oxide Fuel Cells With Direct Internal Reforming (내부개질형 고체산화물 연료전지의 마이크로 전극구조가 성능에 미치는 영향에 관한 해석적 연구)

  • Sohn, Sangho;Nam, In Hyun
    • Journal of Hydrogen and New Energy
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    • v.24 no.5
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    • pp.401-412
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    • 2013
  • The paper is to study on the simulation of the micro/macroscale thermo-electrochemical model of a single cell of anode-supported SOFC with direct internal reforming. The coupled heat and mass transport, electrochemical and reforming reactions, and fluid flow were simultaneously simulated based on mass, energy, charge conservation. The micro/macroscale model first calculates the detailed electrochemical and direct internal reforming processes in porous electrodes based on the comprehensive microscale model and then solve the macroscale processes such as heat and mass transport, and fluid flow in SOFCs with assumption of fully-developed flow in gas channel. The simulation results evaluate the overall performance by analyzing distributions of mole fraction, current density, temperature and microstructural design in co/counter flow configurations.

Modeling for the Performance Analysis of a Tubular SOFC/MGT Hybrid Power System (원통형 고체산화물 연료전지와 마이크로 가스터빈 하이브리드 시스템의 성능해석을 위한 모델링)

  • Song, T.W.;Sohn, J.L.;Kim, J.H.;Kim, T.S.;Ro, S.T.;Suzuki, K.
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.2070-2075
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    • 2004
  • Performance of a solid oxide fuel cell (SOFC) can be enhanced by converting thermal energy of its high temperature exhaust gas to mechanical power using a micro gas turbine (MGT). A MGT plays also an important role to pressurize and warm up inlet gas streams of the SOFC. In this study, the influence of performance characteristics of the tubular SOFC on the hybrid power system is discussed. For this purpose, detailed heat and mass transfer with reforming and electrochemical reactions in the SOFC are mathematically modeled, and their results are reflected to the performance analysis. The analysis target is 220kWe SOFC/MGT hybrid system based on the tubular SOFC developed by Siemens-Westinghouse. Special attention is paid to the ohmic losses in the tubular SOFC counting not only current flow in radial direction, but also current flow in circumferential direction through the anode and cathode.

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Study on the Durability Characteristics of the PEM Fuel Cells having Gas Diffusion Layer with Different Micro Porous Layer Penetration Thicknesses (기체확산층의 미세다공층 침투 깊이에 따른 고분자 전해질형 연료전지의 내구성능 저하 분석에 관한 연구)

  • Park, Jaeman;Oh, Hwanyeong;Cho, Junhyun;Min, Kyoungdoug;Lee, Eunsook;Jyoung, Jy-Young
    • Journal of Hydrogen and New Energy
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    • v.24 no.3
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    • pp.216-222
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    • 2013
  • Durability characteristics of Gas Diffusion Layer(GDL) is one of the important issues for accomplishing commercialization of Proton Exchange Membrane Fuel Cell(PEMFC). It is strongly related to the performances of PEMFC because one of the main functions of GDL is to work as a path of fuel, air and water. When the GDL does not work on their proposed functions due to the degradation of durability, mass transfer in PEMFC is disturbed and it might cause the flooding phenomenon. Thus, investigating the durability of GDL is important and understanding the GDL degradation process is needed. In this study, electrochemical degradation with carbon corrosion is introduced. The carbon corrosion experiment is carried out with GDLs which have different MPL penetration thicknesses. After the experiment, the amount of degradation of GDL is measured with various properties of GDL such as weight, thickness and performance of the PEMFC. The degraded GDL shows loss of their properties.

Performance Comparison of Molten Carbonate Fuel Cell Hybrid Systems Minimizing Carbon Dioxide Emissions (이산화탄소 배출을 최소화하는 용융탄산염 연료전지 하이브리드 시스템들의 성능 비교)

  • AHN, JI HO;YOON, SUK YOUNG;KIM, TONG SEOP
    • Journal of Hydrogen and New Energy
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    • v.28 no.1
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    • pp.30-39
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    • 2017
  • Interests in fuel cell based power generation systems are on the steady rise owing to various advantages such as high efficiency, ultra low emission, and potential to achieve a very high efficiency by a synergistic combination with conventional heat engines. In this study, the performance of a hybrid system which combined a molten carbonate fuel cell (MCFC) and an indirectly fired micro gas turbine adopting carbon dioxide capture technologies was predicted. Commercialized 2.5 MW class MCFC system was used as the based system so that the result of this study could reflect practicality. Three types of ambient pressure hybrid systems were devised: one adopting post-combustion capture and two adopting oxy-combustion capture. One of the oxy-combustion based system is configured as a semi-closed type, while the other is an open cycle type. The post-combustion based system exhibited higher net power output and efficiency than the oxy-combustion based systems. However, the semi-closed system using oxy-combustion has the advantage of capturing almost all carbon dioxide.

Cathode Properties of Sm-Sr-(Co,Fe,Ni)-O System with Perovskite and Spinel Structures for Solid Oxide Fuel Cell (고체산화물 연료전지의 페로브스카이트와 스피넬 구조를 갖는 Sm-Sr-(Co,Fe,Ni)-O 시스템의 공기극 특성)

  • Baek, Seung-Wook;Kim, Jung-Hyun;Baek, Seung-Whan;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.133-136
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    • 2007
  • Perovskite-structured samarium strontium cobaltite (SSC), which is mixed ionic electronic conductor (MIEC), is considered as a promising cathode material for intermediate temperature-operating solid oxide fuel cell (SOFC) due to its high electrocatalytic property. Cathode material containing cobalt (Co) is unstable at high temperature and has a relatively high thermal expansion property. In this paper, Sm-Sr-(Co,Fe,Ni)-O system with perovskite and spinel structures was investigated in terms of electrochemical property and thermal expansion property, respectively. Area specific resistance (ASR) was measured by ac impedance spectroscopy to investigate the electrochemical property of cathode, and thermal expansion coefficient (TEC) was measured by using dilatometer. Micro structure of cathode was observed by scanning electron microscopy. Perovskite-structured $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$ showed the ASR of $0.87{\Omega}/cm^{2}$, and $Sm_{0.5}Sr_{0.5}NiO_{3-\delta}$, which actually has a spinel structure, showed the lowest TEC value of $13.3{\times}10^{-6}/K$.

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Vacuum Die Casting Mold Design of Fuel Cell Bipolar Plate using Die Filling Simulation and Experimental Verification (금형 충전 해석을 이용한 연료전지 분리판 진공 다이캐스팅 금형 설계 방안 및 실험 검증)

  • Jin, Chul-Kyu;Jang, Chang-Hyun;Kang, Chung-Gil
    • Journal of Korea Foundry Society
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    • v.32 no.2
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    • pp.65-74
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    • 2012
  • In this paper, we present the results of our studies on optimal die design towards development of a vacuum die casting process to fabricate fuel cell bipolar plate with micro-channel array. Cavity and overflow shape is designed by computational filling analysis of MAGMA soft. Optimal die design consists of seven overflows at the end of cavity and three overflows at each side wall of cavity. The molten metal that passed the gate and reached the side wall flowed into the side overflow, no turbulent flow occurred, and the filling behavior and velocity distribution were uniform. In addition, partially solidified molten metal passing through the channel was perfectly eliminated by overflow without back-flow. When vacuum pressure, injection speed of low and high region was 300 mbar, 0.3 m/s and 2.5 m/s respectively with Silafont 36 die casting alloy, sound sample without casting defects was obtained. The experimental results are nearly consistent with simulation results.

Design Factors of Membrane Electrode Assembly for Direct Methanol Fuel Cells. (직접 메탄올 연료전지용 막-전극 접합체의 설계 인자에 관한 연구)

  • Cho, Jae-Hyung;Hwang, Sang-Youp; Kim, Soo-Kil;Ahn, Dong-June;Lim, Tae-Hoon;Ha, Heung-Yong
    • Clean Technology
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    • v.13 no.4
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    • pp.293-299
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    • 2007
  • Direct coating of catalyst layer on the $Nafion^{(R)}$ membrane has been optimized in the process of fabrication of membrane electrode assembly (MEA) to enhance the performance of direct methanol fuel cell (DMFC). In this method, the contact resistance at the interface of the catalyst layer and the membrane was found to be low. The effect of catalyst loading, thickness of membrane and the gas diffusion layer (GDL) with or without the presence of micro-porous layer (MPL) on the performance of the MEA was also investigated. The MEA fabricated by the above-mentioned method exhibited a performance of $147\;mW/cm^2$ and $100\;mW/cm^2$ at $80^{\circ}C$ and $60^{\circ}C$, respectively, with the catalysts loading of $4\;mg/cm^2$.

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