• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.1
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• pp.377-383
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• 1996

Interaction of flames in a lean-rich concentration field is studied numerically adopting a counterflow as a model problem. Detailed kinetic mechanism is adopted in analyzing the structure of various type of flames which can be found in lean-rich interaction. Flow field is simplified to quasi one-dimensional by using boundary layer approximation and similarity formulation. Triple flames are identified and its structure shows that a diffusion flame is located in the middle of two premixed flames. Such a diffusion flame is formed by $H_2$ and CO generated from the rich premixed flame and $O_2$ leaked from the lean premixed flame. The flame position can be identified either from the hydrogen production rate or the heat release rate. Transition from single diffusion flame to triple flame is observed as degree of premixing is increased.

• Proceedings of the KSME Conference
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• 2000.04b
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• pp.949-955
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• 2000

Numerical study with detailed chemistry has been conducted to investigate the NOx formation and structure in $CH_4/Air-CO_2$ counterflow diffusion flames. The importance of radiation effect is identified and the role of $CO_2$ addition is addressed to thermal and chemical reaction effects, which can be precisely specified through the introduction of an imaginary species. Also NO separation technique is utilized to distinguish the contribution of thermal and prompt NO formation mechanisms. The results are as follows : The radiation effect is dominant at low strain rates and it is intensified by $CO_2$ addition. Thermal effect mainly contributes to the changes in flame structure and the amount of NO formation but the chemical reaction effect also cannot be neglected. It is noted that flame structure is changed considerably due to the addition of $CO_2$ in such a manner that the path of methane oxidation prefers to take $CH_4 {\rightarrow}CH_3{\rightarrow}C_2H_6{\rightarrow}C_2H_5$ instead of $CH_4 {\rightarrow}CH_3{\rightarrow}CH_2{\rightarrow}CH$. At low strain rate(a=10) the reduction of thermal NO is dominant with respect to reduction rate, but that of prompt NO is dominant with respect to total amount.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.3
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• pp.315-321
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• 2017

A combustion chamber is designed and fabricated for studying the combustion characteristics of counterflow flames at elevated pressure and establishing the fundamental combustion database of counterflow flames. The combustion chamber design aims to allow the maximum operating pressure of 11 bar and be able to conduct flame visualization and the measurements of flame extinction limits, flame temperature and combustion emissions at elevated pressure. Preliminary tests for counterflow nonpremixed $CH_4-NH_3-N_2$/air flames at 1-3 bar have been conducted, and the results confirm the proper operation of the designed chamber.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.325-328
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• 2012

Radiation effects on the partially premixed methane flames diluted with water vapor in the air stream were numerically investigated. OPPDIF code and GRI-v3.0 were used in the numerical simulation. Adiabatic condition was compared with two different radiation models, optically-thin and WSGGM models. It was found that the radiation effect on the flame structure for the equivalence ratio (${\Phi}$) of 2.5 was less than ${\Phi}=1.5$. Extinction limit was not affected significantly, however, local flame structure was markedly influenced by the radiation models as increasing the water vapor concentration.

• Journal of Advanced Marine Engineering and Technology
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• v.22 no.1
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• pp.108-116
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• 1998

In this paper it is investigated the roles of key elementary reactions for NO formation in methane-air one-dimensional premixed flame and counterflow diffusion flame, which were studied numerically by using NO kinetics and $C_{2}$ -chemistry complied by Miller and Bowman. The spatial distributions of the reaction rates of 9 main elementary reactions directly related to NO formation and destruction were calculated. Integration of the rates of all reactions in the NO formation across the flame yields the quantitative reaction path diagram, which shows clearly relative importance of each reaction path in NO formation and how it changes with the type and parameters of the flame. The results show that the thermal and Fenimore mechanisms are dominant respectively for learn and rich premixed flames, and the latter is dominant for diffusion flames. In addition, it was found that the HCN recycle route is important for diffusion flame, and that the routes of mutual transformation between NO and NO$^{2}$, and between NO and HNO do not contribute to the net NO formation.

• Journal of the Korean Society of Combustion
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• v.21 no.4
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• pp.48-60
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• 2016

Experimental and numerical studies were conducted to investigate flame behaviors near flammable limits for downstream-interacting SNG-air premixed flames in a counter-flow configuration. The SNG fuel consisted of a methane, a propane, and a hydrogen with volumetric ratios of 91, 6, and 3%, respectively. The most appropriate priority for some reliable reaction mechanisms examined was given to the mechanism of UC San diego via comparison of lean extinction limits attained numerically with experimental ones. Flame stability map was presented with a functional dependencies of lower and upper methane concentrations in terms of global strain rate. The results show that, at the global strain rate of $30s^{-1}$, lean extinction boundary is slanted while rich extinction one is relatively less inclined because of the dependency of such extinction boundary shapes on deficient reactant Lewis number governed by methane mainly. Further increase of global strain rate forces both extinction boundaries to be more slanted and to be shrunk, resulting in an island of extinction boundary and subsequently one flame extinction limit. Extinction mechanisms for lean and rich, symmetric and asymmetric extinction boundary were identified and discussed via heat losses and chemical interaction.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.93-101
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• 2003

The extinction of unsteady diffusion flame was experimentally studied in an opposing jet counterflow burner using diluted methane. The stabilized flame was perturbed by linearly varying velocity change that was generated by pistons installed on both sides of the air and fuel stream. As the results, the extinction of unsteady flame is dependent not only on the history of unsteadiness, but also on the initial condition. We found that there are several unsteady effects on the flame extinction. First, the extinction strain rates of unsteady cases are extended well beyond steady state extinction limits. Second, as the slope of the strain rate change increases, the unsteady extinction strain rate becomes larger. Third, the extension of unsteady extinction strain rate becomes smaller as the initial strain rate increases. We also found that the extension of the extinction limit mainly results from the unsteady response of the reaction zone because there is no retardation effect of a mixing layer for our experimental condition.

• Journal of the Korean Society of Combustion
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• v.3 no.2
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• pp.41-50
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• 1998

Numerical simulations of nonpremixed $CH_4/C_2HCl_3$(Trichloroethylene, TCE)/Air flames are conducted at atmospheric pressure in order to understand the effect of hydrocabon bound chlorine on methane/air flames. A chemical kinetic mechanism is employed, the adopted scheme involving 48 gas-phase species and 445 elementray reaction steps containing 223 backward reactions. The calculated temperature, velocity, and critical strain rate are compared with the experiments for the flame (16.1% TCE by Vol.) estabilished at a strain rate of $175s^{-1}$. Whereas there is overall good agreement between predictions and the measurements, it appears that the critical strain rate is higher than measured, and some areas of further refinement in the kinetic mechanism are required.

• Journal of the Korean Society of Safety
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• v.17 no.4
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• pp.61-65
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• 2002

Nonpremixed counterflow flames at low strain rates, $ag=12s^{-1}$ and $12s^{-1}$, were numerically simulated to investigate the effects of the duct thickness on the flame structure in normal gravity. For small values of the duct thickness, the positions of the flame and stagnation point were highly sensitive to the duct thickness. When the duct thickness was greater than 6mm, however, the effects of the duct thickness on the flame structure were negligible. The computed temperature along the duct centerline agreed well with measurements.

• Journal of the Korean Society of Safety
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• v.16 no.4
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• pp.74-81
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• 2001

A direct numerical simulation (DNS) was applied to nonpremixed counter-flow diffusion flames between oxidizer and fuel ducts. The objective of this study is to evaluate the numerical method for simulation of axisymmetric counterflow diffusion flames. Effects of computational domain size and grid size were scrutinized, and then the method was applied to air-methane diffusion flames. The results at zero gravity conditions were in good agreement with those obtained by the one-dimension flame code OPPDIF. It was confirmed thai the numerical method is applicable to the diffusion flames at the normal gravity conditions since the results clearly showed the effects of buoyancy and velocity ratio.