• Proceedings of the Materials Research Society of Korea Conference
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• 1998.08a
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• pp.118.1-118
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• 1998

• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.2
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• pp.19-26
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• 2000

This paper presents the effects of initial pressure of mixture on CO, $CO_2$ and NOx emissions in constant volume combustion chamber. The CO, $CO_2,O_2,N_2$ concentrations in the chamber are determined by thermal conductivity detection (Gas-chromatograph) wile the NOx concentration is measured by chemiluminescent detection (NOx Analyser). Methane-air mixture is used as premixed fuel and the measurements are taken with equivalence ratios($\phi$) varing from 0.6 to 1.3, and initial pressures of methane-air mixture varing from 0.1MPa to 0.8MPa in constant volume combustion chamber. The NOx concentration steadily increases with increasing equivalence ratio, peaks in lean flame ($\phi$=0.85~0.9), and then rapidly decreases. However, as the initial pressure of mixture is increased, the equivalence ratio corresponding to the point of peak [NOx] shifts towards leaner conditions. This is caused by a similar shift in the peak [CH], which is caused by the variation with pressure and equivalence ratio of the rate of CH production from $CH_2$ and OH. The maximum combustion pressure peaks at $\phi$ =1.05 and the $CO_2$ concentration peaks at $\phi$=0.95~1.0 while the CO concentration rises sharply at the condition of fuel-rich mixtures. This is caused by complete combustion at $\phi$=0.95.

• Journal of the Korean Institute of Gas
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• v.12 no.2
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• pp.48-52
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• 2008

According to extremely industrial growth, gas facilities, equipments and chemical plants are gradually increased due to incremental demands of annual amount of gases. The safety management of gases, however, is still far from their requirements. Methane, the principal ingredient of natural gas, is inflammable and explosive and is much used in factories and houses. Therefore, these gas safety management is essential. So, we, with a program of the gas safety management, hope to develop the detection system of methane gas leak using mid-infrared ray LED and PD with $3.2\;{\mu}m$. The cryogenic cooling device is indispensible at laser but needless at LED driven on the room temperature if manufacturing optical sensor with $3.2\;{\mu}m$. It, consequently, is not only possible to implement for subminiature and portable type but also able to speedily detect methane of extremely small quantities because the $CH_4$ absorption intensity at $3.2\;{\mu}m$ is stronger than that at $1.67\;{\mu}m$. Our objective of research is to prevent gas leak accidents from occurring previously and to minimize the extent of damage from them.

• Journal of the Korean Institute of Gas
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• v.28 no.1
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• pp.53-58
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• 2024

Due to the development of industry and improvement of living standards, the amount of natural gas used in the world is constantly increasing, and related industrial facilities such as power plants, storage facilities, and supply pipelines are constantly increasing. Natural gas is a convenient and clean fuel that does not pollute the environment, but in the event of an accident due to leakage, it can cause human casualties, large-scale property damage, and negative effects on the global warming effect. In addition to the severe penalties under the Severe Disaster Punishment Act, it is necessary to ensure safety. Therefore, by applying the principle of laser-based absorption spectroscopy, we developed a long-range portable methane leakage gas detection system that can detect the concentration of methane leaking from a distance of up to 30 meters and verified its effectiveness.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.24 no.6
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• pp.769-776
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• 2000

Visible spectral characteristics of cross-sectional emissions from a partially premixed methane/air and propane/air flames have been investigated. An optical train with a two-axis scanning mirror system was used to record line-of-sight emission spectra from 354nm to 618nm, and inversion technique was adapted to obtain cross-sectional emission spectra. By analyzing the reconstructed emission spectra, cross-sectional intensities of CH and $C_2$ radicals were separated from the background emissions. The blue flame edge and yellow flame edge were also obtained by image processing technique for edge detection with color photograph of flame. These edges were compared with radial distributions of CH, $C_2$ radicals and background emissions. The CH radicals were observed at blue flame edge. The background emissions were generated by soot precursor at upstream of flame and by soot at downstream of flame. The $C_2$ radicals in propane/air flame were observed more than those in methane/air flame.

• Journal of the Korean Institute of Gas
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• v.21 no.5
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• pp.1-8
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• 2017

Currently gas safety management in the industrial field has been done by LDAR as contact method or methane leak detector as non-contact method. But LDAR method requires a lot of man-power and methane leak detector have the limitation of methane only. Therefore the Research on the OGI(optical gas image) has big attention by industry. This research was undertaken to see the effect of background temperature difference of gas cloud on the clarity of OGI. The background temperature control panel was constructed to cool down the background temperature. OGI was taken at the various methane gas ejection rate and the designed temperature difference. The experimental results showed that the OGI(when the temperature difference is $-6^{\circ}C$) is more clear thane the OGI(when the temperature difference is zero). To quantify the clarity difference, MATLAB's RGB analysis method was employed. The RGB value of the OGI at ${\Delta}T-6^{\circ}C$ was 20% lower than the OGI at ${\Delta}T0^{\circ}C$. The clarity difference by T difference can be explained by the total radiation law. When the background temperature of the gas is lower than the air temperature, the radiation energy coming into the OGI lens is increasing. As the energy is increasing, the OGI image becomes clear.

• 한국신재생에너지학회:학술대회논문집
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• 2006.11a
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• pp.47-49
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• 2006

The Sea of Okhotsk is the unique area providing the highest methane production rate of the northern hemisphere. The area of focused fluid venting offshore the NE Sakhalin continental slope was investigated during the CHAOS (Hydro-Carbon Hydrate Accumulations in the Okhotsk Sea) expeditions onboard of RV "Akademik Lavrentyev" In 2003, 2005 and 2006. The International Research Project CHAOS (Russia-Korea-Japan) aimed at the study of gas hydrate formation processes associated with the fluid venting in the Sea of Okhotsk. Several new gas hydrate accumulations were discovered during the cruise. Hydrate-associated structures have been named as KOPRI, VNIIOKeangeologia, POI and KIT (the names of cruise participant institutes) Some of hydrate-bearing cores contain big amount of gas hydrates: massive gas hydrate layers (up to 35cm thick) were recovered. The shallowest submarine gas hydrate accumulations in the world (at the depth less then 400m) were discovered during the cruise.

• Journal of Korean Society for Atmospheric Environment
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• v.30 no.1
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• pp.77-87
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• 2014

In this study, an experimental approach to measure a suite of low weight hydrocarbons was investigated with an emphasis on ethylene (EL) along with many others (ethane (EA), propane (PA), propylene (PL), n-butane (BA), acetylene (AL), methyl acetylene (ML)). Their concentrations were quantified using GC-FID system equipped with thermal desorption (TD) system. The TD-based analysis was conducted using both Link Tube/Thermal Desorber (LT/TD) method and Modified Injection through a Thermal Desorption (MITD) method. The results of these analyses were evaluated in a number of respects. The system allowed the detection of all compounds except methane with the mean response factor (RF) of 10.28 (EA) to 11.94 (PL). The method detection limits of target compounds were seen in the range of 0.027 (ML) to 0.146 ng (BA). The emission flux of some environmental samples (fruits), when measured using a small flux chamber system, fell in the range of 0.14 (AL: Kiwi) to $181ng{\cdot}g^{-1}{\cdot}hr^{-1}$ (EL: Apple Peel). The results of this study confirm that the experimental approach developed in this study allows to accurately measure emissions of low weight hydrocarbons (LWHC) like ethylene from various natural and man-made source processes.

• Journal of the Korean Chemical Society
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• v.17 no.5
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• pp.353-356
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• 1973

A unique method of destructive analysis has been developed for the study of gaseous impurities in minerals. Samples are crushed in a high vacuum sample system of a research mass spectrometer. This is done by means of a suitably designed crusher which is incorporated in the inlet system of the instrument. Crusher elements are constructed of tungsten carbide. The mass spectrometer used for this preliminary study has a detection sensitivity of about $10^{-10}cc$at STP. In a study of rhodolite garnets obtained from near Lavonia, Georgia, U.S.A., the gases$H_2$, $O_2$, $H_{2}O$, $CO_2$, CO, and $CH_4$have been identified and their composition determined.

• Journal of the Korean Society of Safety
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• v.11 no.3
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• pp.126-136
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• 1996

Synthesis of perfluoromethanesulfonyl fluoride(PFMSF) which is a valuable precursor of perfluoro-chemicals such as surface modifier and fine chemicals was studied by electrochemical fluorination (ECF). In order to determine the termination of preelectrolysis, it was carried to monitor the variation of current during preelectrolysis by means of constant cell voltage operation. In a batch cell, chronopotentiometric electrolysis and various chemical analysis such as GC, GC/MS and If were used to understand the potential change of electrode and synthesis and control of hazardous gases products. Termination of preelectrolysis was determinated by measurement the current and/or detection of $F_2$ gas generation. And during the preelectrolysis, an amount of generated $OF_2$ was shown that a lot of moisture was absorbed from air when a cell was filled with anhydrous hydrogen fluoride( AHF ). Above 4V cell voltage, $F_2$ gas was generated and acted on any form of fluorinating agents. In the ECF of MSC (methane sulfonyl chloride) by constant current operation, the potential of anode was intimately relation with generation of $SO_2F_2$. Exchange of Cl to F was dominatly occured in a initial stage. There were various gaseous products including PFMSF as main product and $C_4$ compounds.