• Title/Summary/Keyword: metal salt

Search Result 451, Processing Time 0.024 seconds

Application of Ti-salt Coagulant and Sludge Recycling for Phosphorus Removal in Biologically Treated Sewage Effluent (하수종말처리장의 인 처리시설에 티탄염 응집제 적용 및 슬러지 재활용)

  • Kim, Jong Beom;Park, Hee-Ju;Lee, Ki Won;Jo, A Ra;Kim, Myung Wan;Lee, Young Jun;Park, Se Min;Lee, Kwang Young;Shon, Ho Kyong;Kim, Jong-Ho
    • Korean Chemical Engineering Research
    • /
    • v.51 no.2
    • /
    • pp.257-262
    • /
    • 2013
  • As the regulation of total phosphorus (T-P) concentration in biologically treated sewage effluent is reduced to 0.2~2 mg/L, flocculation process is recommended to remove T-P. In this study, the performance of Ti-salt coagulant was investigated in terms of dosage and pH in removing phosphorus and the collected sludge after Ti-salt flocculation was calcined to produce titania for effective sludge recycling. The flocculation performance was carried out using two methods: sedimentation and air floatation. Both methods were feasible to apply for Ti-salt flocculation. Ti-salt flocculation was effective in reducing phosphorus concentration in sewage effluent, which showed similar performance of alum ($Al_2(SO_4)_3$). The calcined sludge was recycled to titania which is the widely used metal oxide. Titania produed from Ti-salt sludge indicated similar characteristics of commercially-available P-25 in regard to photocatalytic activity and surface area. Therefore, this can be easily adopted to titania application by replacing P-25.

Durability and Crack Control of Concrete Using Fluosilicates Based Composite (규불화염계 복합 조성물을 혼입한 콘크리트의 균열제어 및 내구성)

  • Yun, Hyun-Do;Yang, Il-Seung;Kim, Do-Su;Khil, Bae-Su;Han, Seung-Gu
    • Journal of the Korea Concrete Institute
    • /
    • v.18 no.1 s.91
    • /
    • pp.57-64
    • /
    • 2006
  • The crack presented in concrete structures causes a structural defect, the durability decrease, and external damages etc. Therefore, it is necessary to improve durability through the effort to control the crack. Fluosilicic acid($H_2SiF_6$) is recovered as aqueous solution which absorbs $SiF_4$ produced from the manufacturing of industrial-graded $H_3PO_4$ or HF. Generally, fluosilicates prepared by the reaction between $H_2SiF_6$ and metal salts. Addition of fluosilicates to cement endows odd properties through unique chemical reaction with the fresh and hardened cement. Mix proportions for experiment were modulated at 0.45 of water to cement ratio and $0.0{\sim}2.0%$ of adding ratio of fluosilicate salt based inorganic compound. To evaluate correlation of concrete strength and adding ratio of fluosilicate salt based inorganic compound, the tests were performed about design strength(21, 24, 27 MPa) with 0.5% of adding ratio of fluosilicate salt based inorganic compound. Applications of fluosilicate salt based inorganic compound to reduce cracks resulted from plastic and drying shrinkage, to improve durability are presented in this paper. Durability was evaluated as neutralization, chloride ion penetration depth, freezing thawing resistant tests and weight loss according reinforcement corrosion. It is ascertained that the concrete added fluosilicate salt based inorganic compound showed m ability to reduce the total area and maximum crack width significantly as compared non-added concrete. In addition, the durability of concrete improved because of resistance to crack and watertightness by packing role of fluosilicate salt based inorganic compound obtained and pozzolanic reaction of soluble $SiO_2$ than non-added concrete.

Reductive reaction of U and Lanthanides using Cd-Li metal in LiCl-KCl Molten Salt (LiCl-KCl 용융염에서 Cd-Li 금속을 이용한 U 및 란탄족의 환원반응)

  • 우문식;이병직;김응호;유재형
    • Proceedings of the Korean Radioactive Waste Society Conference
    • /
    • 2004.06a
    • /
    • pp.339-339
    • /
    • 2004
  • 원자로를 이용하여 장수명핵종(long lived nucleus)을 소멸처리하는 과정에서 초우라늄(TRU, transuranium)과 희토류(RE, rare earth) 금속에 포함되어 있는 소량의 핵분열성(fissile) 물질인 우라늄을 제거할 필요가 있다. 본 실험은 LiCl-KCl 용융염계에서 전해제련법(Electrowinning)을 이용하여 용융염욕에 존재하는 우라늄을 제거하기 위하여 필요한 Cd-Li 양전극 물질을 제조하였고, 제조된 금속을 이용하여 우라늄 및 란탄족(Dy, Ce, Y, Nd, Gd) 금속의 환원 특성을 파악하였다.(중략)

  • PDF

The Worldwide Trend of waste Treatment Technology and DAEWOO-TS Gasification & Melting System (세계의 폐기물처리기술 동향과 DAEWOO-TS 열분해 가스화 용융기술)

  • 허일상;김우봉
    • Environmental Analysis Health and Toxicology
    • /
    • v.16 no.2
    • /
    • pp.103-114
    • /
    • 2001
  • Worldwide trend of waste treatment technology is rapidly transferring from "incineration system" to "gasification & melting system" which can derive the resources from waste and charge no more environmental burden to nature. And therefore it is necessary for our country to adopt gasification & melting system urgently to present the land pollution and lack of landfill area. Among several gasification and melting processes Daewoo-Thermoselect gasification and melting system is the representative process which can transfer waste to resources such as sin-gas, molten slag, metal hydroxide, mixed salt and sulfur through the process of compaction, degasification, gasification and melting.

  • PDF

Linear and network structures of polymer electrolyte based on phosphate and polyether copolymers

  • Kim, Jun-Young;Kim, Seong-Hun
    • Proceedings of the Korean Fiber Society Conference
    • /
    • 1998.10a
    • /
    • pp.232-235
    • /
    • 1998
  • ion conducting polymers have been extensively investigated because of their potential application as an electrolyte in solid state batteries [1]. Among the polymer electrolytes, solid polymer electrolytes (SPEs) composed of ion conducting polymer and alkali metal salt have many advantages such as high ionic conductivity, high energy density and light weight. This made them suitable replacement for liquid electrolytes. (omitted)

  • PDF

The Gasification & Melting Treatment Technology of Waste (폐기물 열분해 가스화용융 기술)

  • Huh, Il-Sang
    • 유체기계공업학회:학술대회논문집
    • /
    • 2005.12a
    • /
    • pp.133-138
    • /
    • 2005
  • The worldwide trend of waste treatment technology is rapidly transferring from "incineration system" to "gasification & melting system" which can derive the resources from waste and charge no more environmental burden to nature. And therefore it is necessary to adopt gasification & melting system to prevent the land pollution and to solve the problem of landfill area. Among several thermal waste treatment processes gasification and melting system is the representative process which can transfer waste to resources such as syn-gas, molten slag, metal hydroxide, mixed salt and sulfur through the process of compaction, pyrolysis, gasification and melting.

  • PDF

Characterization of Porous Poly(vinylidene fluoride)/Poly(ethylene carbonate) Membranes for Polymer Electrolytes of Lithium Secondary Batteries (리튬 이차전지 고분자 전해질용 다공성 Poly(vinylidene fluoride)/Poly(ethylene carbonate) 막의 특성 연구)

  • Jeon, Jae-Deok;Kwak, Seung-Yeop
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 2004.05b
    • /
    • pp.69-72
    • /
    • 2004
  • So far the most practical polymer electrolytes are gel systems, which contain a polymeric matrix, a lithium salt, and aprotic organic solvents. This has met with success but has had disadvantages that the addition of solvents promotes deterioration of the electrolyte's mechanical properties and increases its reactivity towards the lithium metal anode.[1](omitted)

  • PDF

Studies on the synthesis of S-trifluoroacetoxy-trihalomethyl mercaptans (S-trifluoroacetoxy-trihalomethyl mercaptan의 형성에 관한 연구)

  • 오동영;김종호
    • YAKHAK HOEJI
    • /
    • v.16 no.2
    • /
    • pp.108-112
    • /
    • 1972
  • S-Trifluoroacetoxy-trihalomethyl mercaptans were prepared by reacting metal salt of trihaloacetic acid with perhalomethyl mercaptans in the closed vessel. And besides, certain decomposed states of these products by heat and U.V. were studied by Infra red, N.M.R., molecular weight determination and chemical analysis methods. The results showed that the more fluorine substituted compounds were more stable than the less fluorine substituted ones.

  • PDF

Rejection Characteristics of Various Heavy Metals by Low-pressure Nanofiltration (저압나노여과에 의한 각종 중금속의 제거 특성)

  • Oh, Jeong-Ik;Kim, Han-Seung;Kim, Chung-Hwan
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.18 no.4
    • /
    • pp.493-499
    • /
    • 2004
  • Rejection characteristics of heavy metals by nanofiltration membranes were investigated. Nanofiltration membranes rejected heavy metals much better than chloride, sulfate and TOC, of which concentration in synthetic wastewater was higher than that of heavy metals. To consider rejection characteristics of various metals by nanofiltration membranes, separation coefficient, which is the ratio of the metal permeation rate to the chloride ion or TOC permeation rate, was introduced. In spite of different materials and different nominal salt rejection of nanofiltration membrane used, the separation coefficients of metals were nearly the same. In particular, the separation coefficient of arsenic against chloride ion and TOC was larger than any other separation coefficient of heavy metals. These phenomena were observed in the relationship between the molar conductivity and the separation coefficient for heavy metals.