• Transactions of the Korean hydrogen and new energy society
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• v.15 no.3
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• pp.201-207
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• 2004

Redox characteristics of metal oxide for hydrogen production by thermochemical water-splitting were investigated. $CuFe_2O_4$ as a redox pair that had a different molar ratio of Cu and Fe were prepared by co-precipitation method. Hydrogen production consisted of water-splitting step and thermal reduction step was performed below 1200K. Redox characteristics of Cu-ferrites were studied using the thermal gravimetric analysis technique. Also, structure change of Cu-ferrite during thermal reduction was investigated using the high temperature controlled XRD. In results, oxygen release of Cu-ferrite during the thermal reduction was initiated at oxygen site combined with Cu. Consequently, oxygen release amount of Cu-ferrite was increased with increase of Cu molar ratio of Cu-ferrite. It was found that thermal reduction of Cu-ferrite was begun at $875^\circ{C}$. It was confirmed that structure of Cu-ferrite was changed to metal and cation excess metal oxide during the thermal reduction step.

• Transactions of the Korean Society of Mechanical Engineers
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• v.8 no.2
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• pp.111-118
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• 1984

On the basis of plasticity theory for porous metal, an analysis of ring compression is carried out, employing the upper bound approach. The plastic flowability and the neutral radius of porous metal ring are calculated and deformation characteristics of power forging are obtained from this result. The experiments on ring compression are carried out for sintered iron porous metal with various relative densities under various friction conditions. A good agreement is observed between the shapes of the calculated curves and the experimental results from the ring compression test. The friction factor for powder metal forming can be determined not only from the relationship between reduction in height and reduction in internal diameter but independently from the relationship between reduction in height and relative density, if the initial relative density is known.

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.3
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• pp.143-147
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• 2014

The ECU which is operating inductive actuator like motor or solenoid should be designed with considering the heat removal performance and the EMC performance. In most cases, these two performances are trade-off. Especially, the metal cover with plastic housing for improving heat removal performance can affect EMC performance by coupling the noise source to harness cable and connector. Therefore, after analyzing the EMC effectiveness of the metal cover, countermeasures for EMC noise reduction should be established. In this paper, by simulating and testing of AHB Gen3 ECU, the influence of the metal cover to EMC performance is analyzed. And based on this result, we propose solutions for EMC noise reduction.

• Bulletin of the Korean Chemical Society
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• v.27 no.11
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• pp.1763-1768
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• 2006

The application of poly(Co(II)-(1,8-diaminonaphthalene))(poly(Co-DAN)) and poly(1,8-diaminonaphthalene) (Poly(1,8-DAN)) to the electrocatalytic reduction of molecular oxygen was investigated, which were electrochemically grown by the potential cycling method on the glassy carbon electrodes. The reduction of oxygen at the polymer and its metal complex polymer coated electrodes were irreversible and diffusion controlled. The Poly(1,8-DAN) and Poly(Co-DAN) films revealed the potential shifts for the oxygen reduction to 30 mV and 110 mV, respectively, in an aqueous solution, compared with that of the bare electrode. Hydrodynamic voltammetry with a rotating ring-disk electrode showed that Poly(1,8-DAN) and Poly(Co-DAN) coated electrodes converted respectively 84% and 22% of $O_2$ to $H_2O$ via a four electron reduction pathway.

• Journal of Environmental Science International
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• v.7 no.1
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• pp.46-51
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• 1998

The effects of aloe on the MDA(malondialdehyde) and the blood biochemical components of heavy metal poisoning in SD rat were examined and the following results were obtained. In rat liver homogenate intoxicated with $CdCl_2$, lipidperoxide was increased each 2.37times(24h), 3.31times(72h) but lipidperoxide In aloe administration groups was lower each 47% , 64% than in heavy metal group. In rat kidney homo- genate intoxicated with $CdCl_2$, lipidperoxide was increased 1.85times(24h), 1.33times(72h) but lipidperoxide in groups was almost the same as that of normal group. Lipidperoxide of kidney homogenate was slightly decreased as time passed. Also heavy metal poisoning rats showed high levels(1.38-2.50times) of serum AST, ALT and BUN. However. the administration of aloe significantly inhibited the reduction of them. These results suggest that Cd-induced hepatic and renal injury, via increase llpidpero)Ode and release of AST, ALT and BUN. Aloe may be used to inhibit or prevent the hepatic and renal toxicity which results from the heavy metal.

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.129-132
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• 2007

Advanced structure of metal-supported solid oxide fuel cells was devised to overcome sealing problem and mechanical instability in ceramic-supported solid oxide fuel cells. STS430 whose dimensions were 26mm diameter, 1mm thickness and 0.4mm channel width was used as metal support. Thin ceramic layer composed of anode(Ni/YSZ) and electrolyte(YSZ) was joined with STS430 metal support by using a cermet adhesive. $La_{0.8}Sr_{0.2}Co_{0.4}Mn_{0.6}O_{3}$ perovskite oxide was used as cathode material. It was noted that oxygen reduction reaction of cathode governed the overall cell performance from oxygen partial pressure dependance.

• Bulletin of the Korean Chemical Society
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• v.32 no.9
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• pp.3274-3280
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• 2011

Monodispersed porous NiO and $Co_3O_4$ microcapsules with a hollow core were synthesized using SBA-16 silica sol and PS as a hard template. The porous hollow microcapsules were characterized by XRD, TEM and $N_2$ adsorption/desorption analysis. After $H_2$ reduction of metal oxide microspheres, they were conducted as an active catalyst in the reduction of chiral butylronitrile and cyanobenzene. The mesoporous metals having a hollow structure showed a higher activity than a nonporous metal powder and an impregnated metal on the carbon support.

• Transactions of the Korean Society of Automotive Engineers
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• v.21 no.5
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• pp.176-180
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• 2013

After-treatment apparatus ceramic DPF (diesel particulate filter) have been applied to reduce harmful particulate matters(PM) among emissions from diesel engines so far, but they are easy to be fragile and weak in thermal shock. This research aims to investigate a metal type filter which is superior in mechanical strength and heat conduction rate and is beneficial economically in manufacturing. Basic performance of metal DPF such asloading test, temperature gradient test, thermal shock test, heat resistant test and back pressure was carried out. And then their experimental data provided key informations in designing and manufacturing such as detailed structures of metal mesh filter. Also diesel engine and vehicle of 2957cc displacement was tested under lug-down 3 mode and CVS-75 mode. PM reduction efficiency was 54.5% using metal DPF without loss of performance and fuel consumption.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2005.11b
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• pp.39-50
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• 2005

Electrolytic reduction of uranium oxide to uranium metal was studied in a $LiCl-Li_{2}O$ molten salt system. The reduction mechanism of the uranium oxide to a uranium metal has been studied by means of a cyclic voltammetry. Effects of the layer thickness of the uranium oxide and the thickness of the MgO on the overpotential of the cathode and the anode were investigated by means of a chronopotentiometry. From the cyclic voltamograms, the decomposition potentials of the metal oxides are the determining factors for the mechanism of the reduction of the uranium oxide in a $LiCl-3\;wt{\%} Li_{2}O$ molten salt and the two mechanisms of the electrolytic reduction were considered with regards to the applied cathode potential. In the chronopotentiograms, the exchange current and the transfer coefficient based on the Tafel behavior were obtained with regard to the layer thickness of the uranium oxide which is loaded into the porous MgO membrane and the thickness of the porous MgO membrane. The maximum allowable currents for the changes of the layer thickness of the uranium oxide and the thickness of the MgO membrane were also obtained from the limiting potential which is the decomposition potential of LiCl.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2006.05a
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• pp.295-299
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• 2006

The inner-structure bonded(ISB) sheet metal is defined as a composite sheet metal which has middle layer of truss-structure between two skin sheets. The characteristics such as ultra-light weight, high rigidity, high strength, etc are required especially for automobile parts. The characteristic of ISB sheet metal depends on inner-structure pattern or method of bonding. Pyramid type of crimped expanded metal is used for inner-structure and both of resistance welding and adhesive bonding are applied to make a specimen. As a result of compression test, it is appeared that forming limit is 10% reduction in thickness under a load of 8kgf per unit element(one inner-structure). In case of uniaxial tensile test the non-uniform surface integrity rather than the buckling of inner-structure happened at a load of 450kgf, which indicates elongation of 7.2% and thickness reduction of 13%. The eye-inspection method was applied to examine the defects occurring on the specimen during stretch forming. In case of biaxial stretch forming only the non-uniform deformation on the surface of a skin sheet could be observed. The forming limit in stretching of ISB sheet metal with the hemi-spherical punch of 150mm in diameter was 3mm in forming depth and 5% reduction in thickness.