• Journal of Environmental Science International
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• v.11 no.12
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• pp.1299-1305
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• 2002

Thirty sediment samples of the <63${\mu}{\textrm}{m}$ fraction collected from the southwestern coast of Korea were analysed for their heavy metal (Fe, Mn, Cr, Co, Cu, Ni, Zn and Pb) concentration. The results show that sediment texture plays a controlling role on the total metal concentrations and their spatial distribution. A single lM HCl extraction procedure was used in order to assess the environmental risk of heavy metals in bottom sediments. The non-residual fraction was the most abundant pool for Mn and Pb in most samples, which means that this metals are highly avaliable in these sediments. Cr, Ni, Fe, Co, Zn and Cu were mainly associated with the residual fraction, suggesting that their concentrations are controlled significantly by transport processes with the fine particles as carriers from diffuse pollution source. Concentration enrichment ratios(CER) were calculated from the non-residual contents and their values allowed us to classify the sediments according to their environmental risk.

• Journal of Powder Materials
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• v.27 no.4
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• pp.287-292
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• 2020

The subject of this study is a zeolite generated as a by-product of recycling LAS (lithium-aluminum-silicate) resources, a kind of glass and ceramic produced by induction. The zeolite by-product is modified into Mg-zeolite using Mg as a cation to absorb Pb, a heavy metal generated from water pollution caused by recent industrial wastewater. An ion-exchange method is used to carry out the modification process, from zeolite byproduct to Mg-zeolite, and simultaneously absorb the Pb in the heavy-metal solution (99.032 mg/L). It is found that the sodium zeolite in the raw material residue can be modified to magnesium zeolite by reacting it with a mixture solution at 1 M concentration for 24 h. As a result, it is found that the residual Pb (0.130 mg/L) in the heavy metal solution is shown to be absorbed by 99.86%, with successful formation of a Mg-modified zeolite.

• The Korean Journal of Ecology
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• v.19 no.6
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• pp.519-527
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• 1996

To examine the possibility of biomonitoring of heavy metal removal ability and soil, a study was performed to investigate the heavy metal removal ability and metal-binding protein (MBP) as detoxification process using Oenanthe stolonifera. After O. stolonifera was exposed to individuals (cadmium, zinc) and mixture (cadmium+zinc)for 4 days, removal rate of heavy metal and pH in the treatment medium was measured. MBP was assayed by means of ion exchange column chromatography. The exposure to mixture (Cd:76.8%, Zn:75%) rather than individuals (Cd:82.9%, Zn:90.4%) showed a synergism raising the toxic effect. Initial removal rate was different for each heavy metal : in case of exposure to cadmium it was over 60% on day 1, while for zinc it was 75~90% on day 4. Throughout the experimental period, pH value of treatment medium continuously decreased, since cortex in the roots may secret organic acid to adjust and prevent toxicity of metals. The existence or MBP in the 70~80 fraction and the presence of Zn-enzyme pool was ascertained with the column chromatography. This study demonstrated a possibility that heavy utilized as a biomarker of heavy metal pollution.

• Journal of the Korean Society for Marine Environment & Energy
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• v.18 no.4
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• pp.245-253
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• 2015

Total acid digestion and 1 M HCl extraction methods were used to investigate the pollution status and the degree of ecological risk of trace metals in surface sediments from the Ulsan-Onsan coast. Total concentrations of trace metals (Cu, Cd, Pb, Zn, and Hg) were two-fold higher in surface sediments from Onsan coast than in those from Ulsan coast. The mean labile fractions of the total concentrations of Cd and Pb were 72% and 78%, respectively, indicating a high contribution from anthropogenic sources, whereas Cr, Li, Ni, and As in the residual fraction exceeded 80%, indicating a high contribution from natural sources. According to the results of assessment of trace metal pollution using the sediment quality guidelines in Korea, the concentrations of Cu, Pb, Zn, and Hg were higher than the values of the probable effects level (PEL) at some stations of Onsan coast, and the concentrations of Cr and Ni were lower than the values of the threshold effects level (TEL). The pollution level and ecological risk of the trace metals were analyzed using various indexes (EF, $I_{geo}$, m-PEL-Q, and ERI). Our results showed that the degree of pollution by trace metals (Cu, Cd, Pb, Zn, and Hg) on the Ulsan-Onsan coast was high, and Hg and Cd were the major potential ecological risk factors.

• Proceedings of the KIEE Conference
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• 2006.07b
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• pp.1012-1013
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• 2006

Marine technology must advance to meet the needs of a wealthier and more demanding public while at the same time provide greater environmental protection. Pollution noise and vibration is the specific issue being discussed in this paper Noise is of course due to vibration from high speed engines driving generators, entilators, winch and other gear, while underwater noise pollution results from the propellers and the resistance produced by the hull of the ship moving through the water. Vibration is also a factor in potential damage to sensitive electronic gear and metal fatigue. The issue of noise pollution does not cease when a vessel enters her berth and the main engines shut down. There is still the matter of ventilation and other mechanical factors at work to maintain a comfortable, efficient environment. We measured the noise level and vibration displacement in the training ship A-Ra at underway and Berth. The authors analyzed the frequency of noise and maximum vibration displacement in the position.

• Journal of Korean Society on Water Environment
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• v.20 no.5
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• pp.525-533
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• 2004

The object ofthis study was to test for STORMSYS process that composed Catch Basin and Stormsys(three units: vortex solids separator, filter media bed and vegetated filter strips). It could be applied to treat the first-flush non-point pollution materials on the road(especially, motorway). This study investigated that the runoff characteristics of non-point pollutions containing the heavy metal(Fe, Zn and Cu) by rainfall showed relatively high pollution concentration in the early-stage storm runoff on the road, which seems to be caused by the vehicular traffic, and showed the rapid reduction of pollution concentration on the basis of about 5mm rainfall volume. As the number of the non-rainy days were increased, the pollution concentration by storm runoff was increased, also. As a test result of this process, the average removal efficiency of BOD, $COD_{mn}$, SS, T-N and T-P over the testing period were 92.7%,88.6%,97.4%,93.0% and 93.3%, respectively. Also, the average removal efficiency of n-Hexane, Fe, Zn and Cu were 86.7%, 96.1%, 84.4% and 78.4%, respectively. As shown in the characteristics of storm runoff, the non-point pollution materials have high pollution concentration in the early-stage storm runoff on the road, the installation of STORMSYS process is expected to reduce considerable amount of non-point pollutions.

• Asian-Australasian Journal of Animal Sciences
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• v.18 no.11
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• pp.1623-1627
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• 2005

Heavy metal pollution has become a serious health concern in recent years. Dogs are a very good indicator of the pollution load on the environment. They share people's environment and are exposed to the action of the same pollutants. This study estimated the heavy metal contents in the serum of dogs in domestic districts, and assessed the age, sex, feeding habits, living area, breeding environment and smoking habit of the owners. The findings suggest that dogs can be used to monitor the environmental quality of heavy metals. The mean concentrations of heavy metals in the dog serum from 204 samples (108 male and 96 female) were 0.22${\pm}$0.01 $\mu$g/ml, 0.24${\pm}$0.04 $\mu$g/ml, 0.61${\pm}$0.08 $\mu$g/ml, and 0.50${\pm}$0.06 $\mu$g/ml (for Cd, Hg, Pb, and Cr), respectively. Concentrations of Pb, Cd, Hg, and Cr in the dog serum were higher in Yeongnam including Ulsan, and Seoul higher than those of Chungchong and Honam, especially Pb concentration, which was significantly higher (p<0.01). Concentrations of Cd, Hg, Pb, and Cr in serum, were increased by age (p<0.05). When commercial pet food was provided to dogs, Cd and Cr concentrations were significantly higher in dog serum than dogs fed a human diet (p<0.01 in Cd and p<0.05 in Cr). Heavy metal concentrations of dogs owned by smoking owners, were higher than non-smoking owners although there was no significant difference.

• Economic and Environmental Geology
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• v.37 no.1
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• pp.99-106
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• 2004

Pollution reduction and/or control technology becomes one of the pressing post-semiconductor research field to lead an advanced industrial structure. Soil/groundwater remediation techniques may act as a core technology which will create many demands on pollution reduction areas. A plenty numbers of abandoned metal mines were left without any remediation action in Korea, and it may be potential sources of heavy metal and As contamination in the ecosystem. In order to bring this soil contamination to a settlement, the emerging soil/groundwater remediation techniques should be introduced. Main research topics in the United States and Europe move towards the clean remediation technology without any secondary impact and the feasible application of developing technique into the field scale study. With these advantages, several soil/groundwater techniques such as electrokinetic soil processing, permeable reactive barrier, stabilization/solidification, biosorption, soil flushing with biosurfactant, bioleaching and phytoremediation will be summarized in this paper.

• Journal of Ecology and Environment
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• v.33 no.1
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• pp.15-18
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• 2010

Mangroves are special plant communities that live along intertidal zones in tropical and subtropical areas. They are regarded as one of the most important types of natural ecosystem in the world because of the many ecosystem functions that they perform, of which water purification is the most complex. Mangrove ecosystems are conducive to the deposition and retention of heavy metals. So it is important to understand the impact of heavy metals on mangrove ecosystems, and especially on soil subsystems. We examined the levels of heavy metals in the soil of mangroves in the Dongzhaigang Mangrove National Nature Reserve. Dongzhaigang, the first mangrove nature reserve established in China, is located south of Haikou in Hainan Island and encompasses $33.37\;km^2$, of which mangroves comprise $20.56\;km^2$. To assess the impact of human activities, we collected a large number of soil samples in four sampling areas (the protection station, the harbor, a tour area, and Yeboluo island) in the study area. We measured the concentrations of Cu, Pb, Zn and Cd in the soil samples using the spectra of polyatomic molecules. The average concentrations of Cu, Pb, Zn and Cd were $5.04\;{\mu}g/g$, $10.36\;{\mu}g/g$, $20.06\;{\mu}g/g$ and $0.06\;{\mu}g/g$, respectively, and the heavy metal concentrations were lowest in the protected area, highest in the harbor, and intermediate in Yeboluo Island and the tour area. The heavy metal concentrations in the soil collected from different sample plots are related not only to the physical and chemical properties of the soil, but also to the heavy metal emitted by nearby pollution sources. Our analysis indicates that tourist boats are the main pollution sources in the study area.

• Economic and Environmental Geology
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• v.28 no.3
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• pp.221-229
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• 1995

The heavy metal contents and their dispersion patterns in stream water, stream sediments, land plants and aquatic larvae collected from the hydrologic system flowing via the wasted ore dump of the Moak Au-Ag mine were investigated systematically in order to evaluate the environmental impacts of the abandoned metal mine. The heavy metal content increases abruptly in the vicinity of the wasted ore dump, then attenuated with increasing distance from the mine area. Attenuating rates were stream water > stream sediments > land plants > aquatic larvae. On the other hand, the cumulative content of heavy metals was stream sediments >aquatic larvae > land plants > stream water. Each element tends to be enriched selectively according to media; Zn > Cu > Cd > Pb in stream water, Zn > Pb > Cu > Cd in stream sediments and land plants, and Zn > Cu > Pb > Cd in aquatic larvae. These results show that the degree of enrichment and dispersion of pollutant extruded from the wasted ore dump are different according to elements and media, and that the circulation system of materials of each medium is different. The heavy metals, especially Cu, Pb and Zn, of polluted downstream sediments occur in high proportions of Fe-Mn oxides and organic bounded forms, which show high potential of a secondary pollution source. The content of heavy metals and their dispersion patterns in stream sediments are different from those of ten years ago; pollution levels of heavy metals were degraded in various ranges. The Zn and Cu-polluted areas were widened whereas Fe and Pb-polluted areas were reduced. In crops collected from the farm lands in downstream area, the pepper was more concentrated in all heavy metal than rice. The pepper showed some contaminated level in Cu(9.7ppm) and Zn(149ppm), and the rice in Zn(90ppm). However, both crops showed no significant level in Cd(<0.2ppm) and Pb(<0.5ppm).