• Title/Summary/Keyword: metal matter

Search Result 382, Processing Time 0.035 seconds

Prediction of Sediment-Bound Metal Bioavailability in Benthic Organisms: Acid Volatile Sulfide (AVS) Approaches

  • Song, Ki-Hoon
    • Korean Journal of Environmental Biology
    • /
    • v.20 no.2
    • /
    • pp.101-108
    • /
    • 2002
  • Benthic organisms dwell in sediment-water interface that contains significant amount of organic and inorganic contaminants. Their feeding behavior is highly related with sediment itself and pore water in the sediments, especially in ease of deposit feeder (i.e. polychaete, amphipod). The acid volatile sulfide (AVS) is one of the important binding phases of sediment-bound metals in addition to organic matter and Fe and Mn oxide fractions in sediments, particularly in anoxic sediments. The AVS model is a powerful tool to predict metal bioavailability and bioaccumulation in benthic organisms considering SEM/AVS mole ratios in surficial sediments. However, several biogeochemical factors must be considered to use AVS model in the sediment-bound metal bioavailability.

WITNESSING DISSOLUTION OF A STAR CLUSTER IN THE SEXTANS DWARF GALAXY

  • Kim, Hak-Sub;Han, Sang-Il;Joo, Seok-Joo;Yoon, Suk-Jin
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.43 no.1
    • /
    • pp.32.3-32.3
    • /
    • 2018
  • We report a possible discovery of a relic of a dissolved star cluster in the Sextans dwarf spheroidal galaxy. Using the hk index (${\equiv}$(Ca-b)-(b-y)) as a photometric metallicity indicator, we have successfully discriminated the metal-poor and metal-rich stars in the galaxy and found an unexpected number density peak of metal-poor stars near the galaxy center. The analysis of color-magnitude diagrams reveals that they appear to be originated from an old, metal-poor globular cluster which might be slightly farther than the bulk of field stars in the galaxy. This supports the presence of the star cluster remnants in the galaxy which have been suggested by previous studies. If confirmed, dissolution of a star cluster provides a piece of evidence of a cored dark-matter halo profile for the Sextans dwarf galaxy.

  • PDF

PM Reduction Characteristics of Gasoline Direct Injection Engines with Different Types of GPFs (GPF 종류에 따른 직접분사식 가솔린 엔진의 입자상 물질 저감특성)

  • Yi, Ui Hyung;Park, Cheolwoong;Lee, Sunyoup;Lim, Jong Han
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.39 no.4
    • /
    • pp.351-358
    • /
    • 2015
  • In the recent times, the use of gasoline direct injection (GDI) engines has been regarded as a means of enhancing conformance to emission regulations and improving fuel efficiency. GDI engines have been widely adopted in the recent years for their better engine performance and fuel economy compared to those of conventional MPI gasoline engines. However, they present some disadvantages related to the mass and quantity of particulate matter generated during their use. This study investigated the nanoparticle characteristics of the particulate matter exhausted from a GDI engine vehicle installed with different types of gasoline particulate filters, after subjecting it to ultra-lean burn driving conditions. Three metal foam and metal fiber filters were used for each experimental condition. The number concentrations of particles were analyzed for understanding their behavior, and the reduction characteristics were obtained for each type of filter.

Study of the Photodegradation Properties of Toluene using Photocatalysts Modified by Metal Matter (금속물질로 개질된 광촉매를 이용한 톨루엔 광분해특성 연구)

  • Jang, Hyun Tae;Cha, Wang Seog
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.15 no.11
    • /
    • pp.6952-6957
    • /
    • 2014
  • In photocatalysis, the addition of metal matter to $TiO_2$ can alter the surface properties. As such, the metal can increase the rate of the photodegradation reaction. In this study, a range of modified $TiO_2$ photocatalysts were prepared and tested to improve the activity of photodegradation at a batch-typed photoreactor. To obtain a good sol solution of the $TiO_2$ photocatalyst, several types of dispersion agents and stabilizers were investigated. The photocatalyst solutions were modified with isoproply alcohol as the dispersion agent and sodium silicate as the stabilizer. The effects of various metallic elements on enhancing the photocatalytic activity of $TiO_2$ on the degradation of toluene were examined. Palladium-added $TiO_2$ was found to be the best, whereas copper or tungsten-added also showed good results. In the case of palladium addition, the increase in removal efficiency was 25%. On the other hand, Fe-added $TiO_2$ showed a notable decrease in photocatalytic degradation. Additional doping of copper or tungsten on the $Pd/TiO_2$ had no positive effect on the photodegradation activity.

Evaluation of Heavy Metal Contamination in Intertidal Surface Sediments of Coastal Islands in the Western Part of Jeollanam Province Using Geochemical Assessment Techniques (지화학적 평가기법을 이용한 전남 서해 도서갯벌 퇴적물내 중금속 오염도 평가)

  • Hwang, Dong-Woon;Kim, Seong-Gil
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.44 no.6
    • /
    • pp.772-784
    • /
    • 2011
  • We measured grain size, organic matter, and metallic elements (Fe, Cu, Pb, Zn, Cd, Cr, Mn, Hg, and As) in intertidal sediments collected from six islands in the western part of Jellanam Province in order to evaluate heavy metal contamination in the tidal flat sediments of coastal islands. The evaluation of metal contamination was carried out using geochemical assessment techniques such as sediment quality guidelines (SQGs), enrichment factor (EF), and geoaccumulation index ($I_{geo}$). Surface sediments were classified into four sedimentary facies: sand, gravelly muddy sand, slightly gravelly mud, and silt. The concentrations of heavy metals in intertidal sediments from Jaeun, Amtae, Biguem, and Docho islands showed good positive correlations with mean grain size and ignition loss, indicating that the concentrations of metallic elements in these sediments were dependent on grain size and the organic matter content. The concentrations of heavy metals in sediments from almost all of the stations were lower than two criterion values proposed by the National Oceanic and Atmospheric Administration (NOAA) in the United States. Based on the EF and $I_{geo}$ results, surface sediments were a little polluted for Cr and were moderately polluted for As. Our results suggest that more intensive studies are necessary in the future in order to determine the major source of As in intertidal sediment and to evaluate the As pollution level in macrobenthos.

Study of Degradation of Organic matter using prepared Titania by Metal ions substitution process (금속이온 치환법으로 제조된 티타니아를 이용한 유기물 분해에 대한 연구)

  • Lee, Gyu-Hwan;Rhee, Dong Seok
    • Journal of Industrial Technology
    • /
    • v.28 no.A
    • /
    • pp.19-22
    • /
    • 2008
  • In recent years, much attention has been paid to "Photocatalytic oxidation" as an alternative technique, where the pollutants are degraded by UV-irradiation in the presence of a semiconductor suspension such as titanium dioxide. $TiO_2$ is the most often used photocatalyst due to its considerable photocatalytic activity, high stability, non-environmental impact and low cost. 1n this research, the photocatalytic degradation of humic acid, acetaldehyde and methylene blue in $UV/TiO_2$ systems has been stydied. The effect of calcination temperature for manufacturing of $TiO_2$ photocatalysts and type of photocatalysts on photodegradation has been investigated. Photocatalysts with various metal ions(Mn, Fe, Cu and Pt) loading are tested to evaluate the effects of metal ions impurities on photodegradation. The photodegradation efficiency with $Pt-TiO_2$ or $Fe-TiO_2$ or $Cu-TiO_2$ is higher than Degussa P-25 powder. However, the photodegradation efficiency with $Mn-TiO_2$ is lower than Degussa P-25 powder. The photocatalytic properties of the nanocrystals were strongly dependent upon the crystallinity, particle size, standard reduction potential of various transition metal and electronegativity of various transition metal. As a result photocatalysts with various metal ion loading evaluated the effect of photodegradation.

  • PDF

Heavy metals leaching behavior and ecological risks in water and wastewater treatment sludges

  • Wuana, Raymond A.;Eneji, Ishaq S.;Ugwu, Ezekiel C.
    • Advances in environmental research
    • /
    • v.6 no.4
    • /
    • pp.281-299
    • /
    • 2017
  • Single (0.005 M DTPA), sequential (six-step) and kinetic (0.05 M EDTA) extractions were performed to assess Cd, Cr, Cu, Ni, Pb, and Zn mobilization and their potential ecological risks in Abuja (Nigeria) water (WTS) and wastewater (WWTS) treatment sludges. Total metal levels (mg/kg) in WTS and WWTS, respectively were: Cd(3.67 and 5.03), Cr(5.70 and 9.03), Cu(183.59 and 231.53), Ni(1.33 and 3.23), Pb(13.43 and 17.87), Zn(243.45 and 421.29). DTPA furnished metal extraction yields (%) in WTS and WWTS, respectively as: Cd(11 and 6), Cr (15 and 7), Cu(17 and 13), Ni(23 and 3), Pb(11 and 12), and Zn(37 and 33). The metals were associated with the soluble/exchangeable, carbonate, Mn/Fe-oxide, organic matter and residual forms to varying degrees. Kinetic extractions cumulatively leached metal concentrations akin to the mobilizable fractions extracted sequentially and the leaching data fitted well into the Elovich model. Metal mobilities were concordant for the three leaching procedures and varied in the order:WTS>WWTS. Calculated ecological risk indices suggested moderate and considerable metal toxicity in WTS and WWTS, respectively with Cd as the worst culprit. The findings may be useful in predicting heavy metals bioavailability and risks in the sludges to guide their disposal and use in land applications.

Changes of Nitrogen Fixation Activity and Heavy Metal Accumulation of Vicia amoena Community from Kumho Riverside (금호강유역 갈퀴나물군락의 중금속 축적과 질소고정 활성의 변화)

  • 박태규;박용목;송은주;송승달
    • The Korean Journal of Ecology
    • /
    • v.22 no.3
    • /
    • pp.131-137
    • /
    • 1999
  • This study was carried out to investigate the activity of nitrogen fixation and accumulation of heavy metal and inorganic matter in Vicia amoena community at lower region in Kumho riverside, including Youngchon, Chimsangyo, Paldalgyo, Talseochon and Kumhogyo. The contents of inorganic matter and heavy metal of Kumho riverside soil increased in the down stream in each organ of the plant growing in the riverside. Generally, V. amoena community showed rapid growth of shoot and high value of Top/Root ratio. V. amoena community showed higher water content of shoot at late growth stage and higher chlorophyll content. The root nodule of V. amoena community appeared in April and increased by 0.30, 0.27, 0.24, 0.06 and 0.14 g/plant, and nitrogen fixation activity of nodule attained 20.1, 16.8, 15.4, 8.5 and 5.3 μmol·C₂H₄·g fw nodule/sup -1/·h/sup -1/ for non-contaminated area Youngchon, Chimsangyo, Paldalgyo, Talseochon and Kumhogyo, respectively, in June:. Nodule formation and nitrogen fixation activity were reduced in the down stream by the soil contamination and heavy metal accumulation and showed minimum values. at Talseochon and Paldalgyo. V. amoena showed growth adaptation against heavy metal toxicity by restricting heavy metal such as Pb, Cu, Zn, Fe from transport, and by accumulating high Ca ion in shoot, nitrogen and phosphorus in root at late growth stage than those at early one, respectively, but total heavy metal per plant showed higher values in shoot than those in root by high T/R ratio of plant growth.

  • PDF