• Journal of the Korean Chemical Society
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• v.10 no.1
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• pp.4-10
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• 1966

A new method of cobalt determination has been developed by employing ethylenediamine tetrabutyl acetate(EDTA-butyl ester) synthesized from EDTA and Butyl alcohol. The synthesized EDTA ester dissolved in butyl alcohol extracts various metal ions from aqueous solutions. Cobaltous ion extracted into organic phase containing EDTA ester to form Co (II)-EDTA butyl ester complex is back extracted into alkaline aqueous phase forming a stable pink colored complex of Co (III). The optimum condition for spectrophotometric determination of cobalt via the new complex has been established. The absorption peak occurs at 540$m{\mu}$ and Beer's law was obeyed over the concentration range of 0∼50 ${\mu}g/ml$ of cobalt.

• Bulletin of the Korean Chemical Society
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• v.25 no.2
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• pp.177-181
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• 2004

A PVC membrane electrode for silver ion based on a new cone shaped calix[4]arene (CASCA) as membrane carrier was prepared. The electrode exhibits a Nernstian response for $Ag^+$ over a wide concentration range ($1.0{\times}10^{-1}-8.0{\times}10^{-6}$M) with a slope of 58.2 {\pm}$ 0.5 mV per decade. The limit of detection of the sensor is $5.0{\times}10^{-6}$M. The sensor has a very fast response time (~5 s) in the concentration range of ${\leq}=1.0{\times}10^{-3}$ M, and a useful working pH range of 4.0-9.5. The proposed sensor displays excellent discriminating ability toward $Ag^+$ ion with respect to common alkali, alkaline earth, transition and heavy metal ions. It was used as an indicator electrode in potentiometric titration of $Ag^+$ with EDTA and in direct determination of silver ion in wastewater of silver electroplating.

• Journal of the Korean Chemical Society
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• v.51 no.2
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• pp.141-146
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• 2007

The present paper describes a procedure for separation, preconcentration and determination of trace amount of copper in natural water samples by using 2-mercaptobenzimidazol as the complexing agent. The proposed method is based on the surfactant aggregation formed on γ-alumina by mixing sodium dodecyl sulfate and γ-alumina in water; 2-mercaptobenzimidazol was incorporated into inner hydrophobic part of produced ad-micelles in acidic media to produce an assemble suitable for preconcentration and determination of copper ion. Optimum experimental conditions for adsorption of μg/ml levels of copper ions from aqueous solution by the adsorbent have been reported. The copper ions were quantitively adsorbed by the sorbent over the pH range of 7.1-8.0 and were quantitatively desorbed afterward by using sulfosalycilic acid as the eluent. The determination of copper was not interfered in the presence of common metal ions. The procedure was applied for analysis of river water sample. Relative standard deviation was found to be 4.91%.

• Journal of the Korean Vacuum Society
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• v.22 no.5
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• pp.262-269
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• 2013

Though focused ion beam (FIB) is one of the candidates to fabricate the nanoscale patterns, precision milling of nanoscale structures is not straightforward. Thus this poses challenges for novice FIB users. Optimal determination in FIB parameters is a crucial step to fabricate a desired nanoscale pattern. There are two main FIB parameters to consider, beam current (beam size) and dose (beam duration) for optimizing the milling condition. After fixing the dose, the proper beam current can be chosen considering both total milling time and resolution of the pattern. Then, using the chosen beam current, the metal nano hole structure can be perforated to the required depth by varying the dose. In this experiment, we found the adequate condition of $0.1nC/{\mu}m^2$ dose at 1 pA Ga ion beam current for 100 nm thickness perforation. With this condition, we perforated the periodic square array of elliptical nano holes.

• Journal of Korea Society of Digital Industry and Information Management
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• v.14 no.4
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• pp.101-107
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• 2018

In the stripping scan square wave voltammetry (SV+SWV) polarography that is often used to analyze the concentration of heavy metals in water, we must measure the point where the faradic current that flows by the pure oxidation-reduction reaction at the electrode is greater than the capacitive current, the frequency cannot be too high. Therefore we wanted to find the frequency range that can be measured. In order to do this, we came up with a method to analyze the signal using FPGA Soc. With this method, the frequency of the square wave was increased from 10Hz to 400Hz by 10Hz, and the measuring time of the square wave was changed from 96.695% to 96.765% by 0.005% while 1600 experiments were conducted. As a result, the frequency of the square wave maintained a stable area of potential-current within 320Hz and it was possible to measure the potential-current signal when calculating the measuring time within the frequency range of 96.7155%.

• Resources Recycling
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• v.21 no.5
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• pp.88-92
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• 2012

We tried to measure the fixed quantity of $Ni^{2+}$ion among the metals which were eluted by distilled water from the Fly Ash Leach Liquor(FALL) with a spectrophotometric method. In addition, we researched absorbance values which had different contained quantity of $V^{3+}$ion in contrast with $Ni^{2+}$ion ppm to find out the influence of the $V^{3+}$ion existed in the FALL on the spectrophotometric fixed quantity of $Ni^{2+}$ion. As a result, when $V^{3+}$ ion has below 50% of amount of $Ni^{2+}$ion, the fixed quantity of $Ni^{2+}$ion among the FALL was able to be confirmed by spectrophotometry.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2005.05a
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• pp.327-328
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• 2005

Trace anions in high-sulfate wastewater from mainly derelict mines were determined by ion chromatography with on-line preconcentration and preelution technique. As the sample was preconcentrated and more strongly held ions were preeluted to the principal separation system, this approach was highly effective in removing large concentration of sulfate in high-sulfate wastewater. With this practical on-line preelution treatment, the peaks of fluoride and chloride showed good resolution even when the sulfate concentration was as high as 2000 mg/L and the analyzed total metal concentration was above 500 mg/L.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.03a
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• pp.68-68
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• 2011

A new chemosensor based on rhodamine B (1) for $Hg^{2+}$ and $Cu^{2+}$ was synthesized by one-step condensation reaction of rhodamine B hydrazide and Azo dye. Studying for its fluorogenic and colorimetric behaviors towards various metal ions, extreme sensitivity and selectivity were achieved by the detection of $Hg^{2+}$ and $Cu^{2+}$ over other commonly coexistent metal ions, which were accompanied by ring opening of a rhodamine spirocycle framework. In acetonitrile, the presence of $Hg^{2+}$ and $Cu^{2+}$ induces the formation of a Dye 1-ion complex, which was deduced by spectroscopy.

• Journal of the Korean Chemical Society
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• v.25 no.1
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• pp.21-25
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• 1981

A study was made of the influence of butyl alcohol on the distribution coefficients of barium and mercury ions between the ion exchange resin, Dowex 50w-x8, 200~400 mesh and solutions containing hydrochloric acid, butyl alcohol and water. The determination of the distribution coefficients of barium and mercury are made by using the batch method. The distribution coefficients of metal ions decrease generally as the number of branches of carbon in the molecule of butyl alcohol increase. It shows that solubility in water and stereo-isomerism of the butyl alcohol have influence upon the distribution coefficient of barium and mercury.

• Korean Journal of Optics and Photonics
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• v.2 no.2
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• pp.59-66
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• 1991

Resonance angle and optimum thinckness of various thin metal films for surface plasmon resonance were calculated using an admittance diagram and optical constants and thickness of thin Ag films and Al films were determined by fitting the measured reflectance of surface plasmon resonance. Two wavelengths of an Ar ion laser were employed to select the unique optical constants which have the same thickness at two wavelengths. Also, when these films were exposed to the air, the shift of surface plasmon resonance was measured and the optical constants of modified thin films were determined.