• 펄프종이기술
• /
• 제39권4호
• /
• pp.1-6
• /
• 2007

Paper is a composite consisted of various solid materials including pulp, filler and other additives. The pore is also one of components consisting the paper structure. Thus the characterization of pore structure of paper is very helpful in the understanding the structural properties of paper. Mercury intrusion technique is frequently used for the characterization of the porous paper, giving access to parameters such as pore size and pore distribution. But some researchers pointed out the problem that the distortion of the pore structure can be occurred by the application of high pressure during mercury intrusion. Thus in this study, we tried to evaluate the potential of SEM and image analysis method as means for analyzing pore structure of the paper. The new pore analysis technique with SEM and image analysis does not require the application of high pressure, and gave better relation between the measured pore characteristics and the bulk of sheet than mercury intrusion method.

• 한국펄프종이공학회:학술대회논문집
• /
• 한국펄프종이공학회 2007년도 추계학술발표논문집
• /
• pp.179-186
• /
• 2007

The best way to understand paper properties is to study paper structure. Paper is composed solid materials (pulp and other additives) and air three-dimensionally, it's important to understand pore structure of the paper. There are several method to analysis pore structure of the paper. Mercury intrusion technique is frequently used for the characterization of the porous paper, giving access to parameters such as pore size and pore distribution. But some researchers indicated mercury intrusion distorts the structure due to application of high pressure. So this paper suggest new analysis technique to pore structure of the paper. New pore analysis technique with SEM does not require high pressure, gives good resolution and measures pore structure.

• Journal of the Korean Wood Science and Technology
• /
• 제46권6호
• /
• pp.681-691
• /
• 2018

The typical methods of mercury intrusion porosimetry (MIP) and capillary flow porometry (CFP) were used to evaluate the pore size of cross-section of wood and the effect of the pore structure on the permeability of wood was analyzed in this study. The results of this study were as followings: The pore size of wood measured by CFP was larger than that measured by MIP except for Lime tree, Korean red pine and Paulownia. Among the three pore types of porous materials defined by IUPAC (through pores, blind pores, and closed pores), only through pores are related to permit fluid flow. MIP measures the pore size of both through pores and blind pores, while CFP measures the pore size of only constricted through pores. Therefore, pore size measured by MIP was not related to gas permeability, however pore size measured by CFP had a proportional relationship with gas permeability.

• 한국토양비료학회지
• /
• 제26권4호
• /
• pp.284-288
• /
• 1993

토양수분조건에 따른 공극(孔隙) 크기별 분포(分布)의 변화를 구명하기 위하여 Vertisol과 Alfisol을 가지고 수분조건(水分條件)이 각각 0.033MPa, 1.5Mpa 및 건조상태(乾燥狀態)에서 동결건조(凍結乾燥)시켜 수은(水銀) 침투법(浸透法)과 보수력(保水力)으로 공극(孔隙)의 크기별 분포(分布)를 측정(測定)하였다. 수은(水銀) 침투법(浸透法)으로 측정한 공극량은 보수력법(保水力法)보다 대공극량(大孔隙量)이 많았고 냉동건조전(冷凍乾燥前)의 수분조건(水分條件)에 따라서도 공극분포(孔隙分布)는 큰 차이가 있었다.

• 한국결정성장학회지
• /
• 제13권2호
• /
• pp.73-78
• /
• 2003

Tetraethyl orthosilicate (TEOS)로부터 유도된 동결건조 실리카 젤의 기공구조에 미치는 하소온도의 영향이 질소 등온흡착 및 수은압입법에 의하여 조사되었다. 동결건조물은 다소간의 마이크로기공을 함유하고 있었으나 주로 4~6nm 크기의 매크로기공 및 7~20$\mu\textrm{m}$ 크기의 매크로기공으로 구성되어 있었다. 하소온도의 증가에 따른 기공구조변화는 치밀화 정도에 의존하였다.

• 한국지반공학회:학술대회논문집
• /
• 한국지반공학회 2009년도 세계 도시지반공학 심포지엄
• /
• pp.1517-1521
• /
• 2009

A variation of pore structure of shotcrete matrix was experimented by Mercury Intrusion Porosimetry, and the relation with compressive strength was also examined. As a result of the Mercury Intrusion Porosimetry(MIP) test, RM-P1 Batch the macropore diameter of the RM-BFS2 and RM-BFS3 Batch than to have a relatively macropore can see a lot of long-term durability performance degradation. Also, K and N Batch the current is applied to the mine if the factors on shotcrete durability performance of the macropore volume of the entire appears to be a long-term durability performance in the fall.

• International Journal of Concrete Structures and Materials
• /
• 제11권1호
• /
• pp.59-68
• /
• 2017

Mercury intrusion and nitrogen sorption porosimetry were employed to investigate the pore structure of calcium sulfoaluminate ($C{\bar{S}}A$) and portland cement pastes with cement-to-water ratio (w/c) of 0.40, 0.50, and 0.60. A unimodal distribution of pore size was drawn for $C{\bar{S}}A$ cement pastes, whereas a bimodal distribution was established for the portland cement pastes through analysis of mercury intrusion porosimetry. For the experimental results generated by nitrogen sorption porosimetry, the $C{\bar{S}}A$ cement pastes have a smaller and coarser pore volume than cement paste samples under the same w/c condition. The relative dynamic modulus and percentage weight loss were used for investigation of the concrete durability in freeze-thaw condition. When coarse aggregate with good freeze-thaw durability was mixed, air entrained portland cement concrete has the same durability in terms of relative dynamic modulus as $C{\bar{S}}A$ cement concrete in a freeze-thaw environment. The $C{\bar{S}}A$ cement concrete with poor performance of durability in a freeze-thaw environment demonstrates the improved durability by 300 % over portland cement concrete. The $C{\bar{S}}A$ concrete with good performance aggregate also exhibits less surface scaling in a freeze-thaw environment, losing 11 % less mass after 297 cycles.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2017년도 추계 학술논문 발표대회
• /
• pp.20-21
• /
• 2017

In this study, fundamental properties by pore structure and heat of microhydration test were determined. As a result of pore structure analysis, BS(AA) specimen showed showed the maximum peak value of significantly lower incremental intrusion than the maximum peak value of incremental intrusion at smaller pore size than that of BS. As a result of heat of microhydration test, the maximum heating value was in the order of OPC > BS > BS(AA), and initial drying shrinkage and compressive strength of BS(AA) were expected to be improved.

• 한국지반공학회:학술대회논문집
• /
• 한국지반공학회 2000년도 가을 학술발표회 논문집
• /
• pp.427-434
• /
• 2000

Hydraulic conductivity of soil-cement was measured as a function of some selected construction variables that are often encountered in practice. They are initial (or compaction) water content, delayed compaction after mixing, and repeated freezing and thawing. Sandy and clayey soils were used. The hardening agent used was a cement based soil stabilizer consisting of 80% of ordinary Portland cement and 20% of a combination of supplementary materials. Hydraulic conductivity of soil-cement with varying initial water content was, in trend, similar to that of compacted clay. Hydraulic conductivity of soil-cement decreased with increasing initial water content and reached its minimum when compacted wet of optimum water content. Pore size distributions of soil cement at different initial water contents were analyzed using mercury intrusion porosimetry. The analysis showed that dryer condition led to the formation of larger pores with lesser total pore volume; smaller pores with larger total pore volume at wetter condition. Hydraulic conductivity of soil-cement increased by orders in magnitude when specimen underwent delayed compaction of longer than 4 hours after mixing and repeated freezing and thawing.

• 콘크리트학회논문집
• /
• 제16권2호
• /
• pp.277-282
• /
• 2004

In a hardened concrete, diffusion of oxygen, carbon dioxide, aggressive ions, and moisture from the environment to the concrete takes place through the pore network. It is well known that making dense cement matrix enhances the durability of concrete as well as all the characteristics including strength of concrete. In this paper,9 mix concretes with water to cementitious material ratio (40,45, and $50\%$) and replacement ratio of GGBFS (40 and $60\%$ of cement by weight) were studied on the micro-pore structure by mercury intrusion porosimetry and the accelerated chloride diffusion test by potential difference. From the results the average pore diameter and accelerated chloride diffusivity of concrete were ordered NPC > G4C > G6C. It is concluded that there is a good correlation between the average pore diameter and the chloride diffusivity, and the mineral admixtures has a filling effect, which increases the tortuosity of pore and makes large pores finer, on the pore structure of cement matrix due to the latent hydraulic reaction with hydrates of cement.