• Title/Summary/Keyword: membrane transport

Search Result 815, Processing Time 0.028 seconds

Separation of Chromium(VI) Ion in Industrial Waste Water throunh Liquid Surfactant Membrane (산업폐수중 유화액막에 의한 크롬(VI)의 분리)

  • 초민승;강안수;우인성;이영순
    • Journal of the Korean Society of Safety
    • /
    • v.4 no.1
    • /
    • pp.15-24
    • /
    • 1989
  • The transport of Chromium(Vl) ion from waste water throughl the liquid surfactant membrane containing tri-n-octylamine as a carrier, was analyzed by a slab model and was investigated through experiments. For the experiment of membrane stability, concentrations of surfactant and liquid parafnn oil were analyzed. Extraction euperiments were carried out to observe the effect of system variables, such as stirring speed, concentration of carrier, and NaOH in internal aqueous phase, and concentrations of H$_2$SO$_4$and initial chromium(VI) ion in external aqueous phase at $25^{\circ}C$. It is concluded that the most stable formation of liquid membrane emulsion was obtained when surfactant concentration is above 3 wt. % and liquid parafnn oil concentration is 50 vol. %. The transport of chromium(VI) ion in bacth extractor increased with increasing carrier concentration, the volume ratio of emulsion to external aqueous phases, and initial concentration of chromium(VI) ion under the optimum stirring speed of chromium(VI) ion below 2 ppm. The theoretical equation on the transport of chromium(Vl) ion agreed well with the experimental results.

  • PDF

Silver Polymer Electrolyte Membranes for Facilitated Olefin Transport: Carrier Properties, Transport Mechanism and Separation Performance

  • Kim, Jong-Hak;Kang, Yong-Soo
    • Macromolecular Research
    • /
    • v.12 no.2
    • /
    • pp.145-155
    • /
    • 2004
  • Facilitated transport membranes for the separation of olefin/paraffin mixtures have long been of interest in separation membrane science because olefins, such as propylene and ethylene, which are important chemicals in petrochemical industries, are currently separated by energy-intensive cryogenic distillation processes. Recently, solid polymer electrolyte membranes containing silver ions have demonstrated remarkable performance in the separation of olefin/paraffin mixtures in the solid state and, thus, they can be considered as alternatives to cryogenic distillation. Here, we review recent progress, and critical issues affecting in the use of facilitated olefin transport membranes; in particular, we provide a general overview with reference to carrier properties, transport mechanisms, and separation performance.

Effect of Valine on facilitated O1e1in Transport Membranes (올레핀 촉진수송 분리막의 성능향상을 위한 Valine의 효과)

  • Yong Soo Kang;Sang Wook Kang;Jong Hak Kim;Jongok Won;Kookheon Char
    • Membrane Journal
    • /
    • v.13 no.2
    • /
    • pp.125-129
    • /
    • 2003
  • A remarkable separation performance of olefin/paraffin mixtures has been observed through facilitated olefin transport membranes consisting of silver ions dissolved in polymer matrices. In this research, valine, an amino acid, was introduced in poly (2-ethyl-2-oxazoline) (POZ)/$AgBF_4$ membranes to increase the separation performance. FT-IR spectra show that the cationic sites ($-NH_3^+$) of valine interact with the counter anion of the silver salt, resulting in the enhanced activity of the silver ions and consequently improved separation perfornance. Therefore, the $POZ/AgBF_4$ membranes containing valines exhibit the higher permeance as well as the higher selectivity of propylene/propane than those without valine.

Diffusion Coefficients and Membrane Potential within Carrier Membrane by Reverse Transport System

  • Yang, Wong-Kang;Jeong, Sung-Hyun;Lee, Won-Chul
    • Korean Membrane Journal
    • /
    • v.4 no.1
    • /
    • pp.36-40
    • /
    • 2002
  • The diffusion coefficients of ions in the reverse transport system using the carrier mediated membrane were estimated from the diffusional membrane permeabilities and the ion activity in membrane system. In the aqueous alkali metal ions-membrane system diffusional flux of alkali metal ions driven by coupled proton was analyzed. The aqueous phase I contained NaOH solution and the aqueous phase II also contained NaCl and HCl mixed solution. The concentration of Na ions of both phases were $10^{0},\;10^{-1},\;10^{-2},\;5{\times}10^{-1}\;and\;5{\times}10^{-2}\;mol{\cdot}dm^{-3}$ and the concentration of HCI in aqueous phase II was always kept at $1{\times}10^{-1}\;mol{\cdot}dm^{-3}$. Moreover, the carrier concentration in liquid membrane was $10^{-2}\;mol{\cdot}dm^{-3}$. The results indicated that the diffusion coefficients depend strongly on the concentration of both phases electrolyte solution equilibriated with the membrane. The points were interpreted in terms of the energy barrier theory. Furthermore, eliminating the potential terms from the membrane equation was derived.

Interhospital Transport System for Critically Ill Patients: Mobile Extracorporeal Membrane Oxygenation without a Ventilator

  • Yeo, Hye Ju;Cho, Woo Hyun;Park, Jong Myung;Kim, Dohyung
    • Journal of Chest Surgery
    • /
    • v.50 no.1
    • /
    • pp.8-13
    • /
    • 2017
  • Background: Extracorporeal membrane oxygenation (ECMO) has been successfully used as a method for the interhospital transportation of critically ill patients. In South Korea, a well-established ECMO interhospital transport system is lacking due to limited resources. We developed a simplified ECMO transport system without mechanical ventilation for use by public emergency medical services. Methods: Eighteen patients utilized our ECMO transport system from December 2011 to September 2015. We retrospectively analyzed the indications for ECMO, the patient status during transport, and the patient outcomes. Results: All transport was conducted on the ground by ambulance. The distances covered ranged from 26 to 408 km (mean, $65.9{\pm}88.1km$) and the average transport time was $56.1{\pm}57.3minutes$ (range, 30 to 280 minutes). All patients were transported without adverse events. After transport, 4 patients (22.2%) underwent lung transplantation because of interstitial lung disease. Eight patients who had severe acute respiratory distress syndrome showed recovery of heart and lung function after ECMO therapy. A total of 13 patients (70.6%) were successfully taken off ECMO, and 11 patients (61.1%) survived. Conclusion: Our ECMO transport system without mechanical ventilation can be considered a safe and useful method for interhospital transport and could be a good alternative option for ECMO transport in Korean hospitals with limited resources.

Hidered transport of concentrated latex particles through well-defined membrane pores (진한 라텍스 입자의 Well-defined 막기공을 통한 제한적 이동)

  • 황장연;강은아;전명석;김재진
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 1998.04a
    • /
    • pp.56-58
    • /
    • 1998
  • 1. 서론 : 무한한(unbounded) 용매 속에 떠 있는 구형입자의 확산계수는 Stokes-Einstein 식에 의해 주어지며, 이를 이용하여 입자의 반지름을 결정하기도 한다. 입자가 그 크기정도(order-of-magnitude)의 공간에 제한되는 경우에는 제한하는 벽이 입자의 운동에 많은 영향을 주게 된다. 이런 제한적 이동(hidered transport)은 막이나 크로마토그래피를 이용하는 분리공정이나 촉매를 이용하는 반응공정에서 이용되고 있다. (생략)

  • PDF