• Title/Summary/Keyword: membrane performance

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The effect of MEA fabrication procedure on PEMFC performance (고분자전해질 연료전지의 MEA 제조방법에 따른 성능비교)

  • Cho Yong-Hun;Cho Yoon-Hwan;Park In-Su;Choi Baeckbom;Jung Dae-Sik;Sung Yung-Eun
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.291-295
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    • 2005
  • The PEMFC behavior is quite complex and is influenced by several factors, including composition and structure of electrodes and membrane type. Fabrication of MFA is important factor for proton exchange membrane fuel cell. MFA of PEMFC with hot pressing and direct coating method were prepared, and performances were evaluated and compared each other. The effect of MEA preparation methods, hot pressing methods and direct coating methods, on the cell performance was analyzed by impedance spectroscopy and SEM. The performance of PEMFC wi th direct coat ing method was better than wi th hot pressing method because membrane internal resistance and membrane-:-interfacial resistance were reduced by elimination of hot pressing process in MEA fabrication. In addition the micro structure of MEA with direct coating method reveals uniform interface between membrane and catalyst layer.

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Combined Effects of Metal Coagulants and Monochloramine on Polyamide RO Membrane Performance (금속성 응집제와 모노클로라민의 상호작용이 Polyamide계 RO막 성능에 미치는 영향)

  • Kim, Kyunghwa;Hong, Seungkwan;Park, Chanhyuk;Yoon, Seongro;Hong, Seongpyuo;Lee, Jonghwa
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.4
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    • pp.637-643
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    • 2006
  • The bench-scale chlorine exposure study was performed to investigate the effect of pretreatment by free chlorine and monochloramine ($NH_2Cl$) on the performance of RO membranes made of polyamide (PA). Feed monochloramination at 2mg/L did not cause significant productivity loss compared to free chlorine. However, metal coagulants reacted with monochloramine, the PA membrane suffered from a gradual loss of membrane integrity by chlorine oxidation, which was characterized as a decrease in salt rejection. Especially, RO membranes exposed to alum coagulants with monochloramine revealed the salt rejection lower than those exposed to iron coagulants. XPS membrane surface analysis demonstrated that the chlorine uptake on the membrane surface increased and carbon peaks were shifted significantly when exposed to alum coagulants with monochloramine.

Recent Progress in Surface Science and Its Application in Advanced Water Treatment by Membrane Processes

  • Matsuura, Takeshi
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.06a
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    • pp.21-35
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    • 1997
  • As environmental regulations become more stringent, water, used either as drinking water or as industrial process water, becomes increasingly better in its quality. As a result, an increasingly more advanced water treatment technology is required. It is believed that membrane technology will be able to satisfy such a requirement. The heart of the membrane technology is membrane. The advancement in water treatment technology using membranes, therefore, depends on the development of novel membranes which are superior in performance to the currently available membranes. In this paper, a brief review will be made how the recent progress in surface science, such as surface modification and surface characterization, has aided to improve the performance of the membranes used for water treatment. Some suggestions will also be made regarding the future direction of the research in this area.

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A Study on Architectural Acoustic Characteristics of an Open Air Performance Hall with the Membrane Structure (테프론(TEFRON)막 구조 야외공연장의 건축음향특성 분석에 관한 연구)

  • Kim, Jung-Joong;Sohn, Jang-Yeul;Park, Hye-Na
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.11a
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    • pp.649-653
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    • 2005
  • Recently, many membrane structure buildings are constructed with the trend of multi functional and high technological construction. The membrane structure has the characteristics such as distinguished architectural shape which can make variable space creation and can make economic use of material. Therefore, it is in the spotlight of sport complex, various concert hall, and public service buildings. However, the acoustic study of membrane structure has not been following up the increasing demand for the membrane structure. In this study, the acoustic characteristics of membrane structure will be studied and analyzed using architectural acoustic factors based on acoustic design theory And also, the differences between theoretical exhortation value and outcome of study will be studied with the basis of architectural acoustic material study.

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Performance Test Method on the Influence Waterproofing as Behavior of Concrete Structure (지하 콘크리트 구조물의 거동에 대한 방수층의 대응성 평가에 관한 실험적 연구)

  • Noh Jong-Soo;Kwon Shi-Won;Kwak Kyu-Sung;Kwon Kee-Joo;Oh Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • v.y2004m10
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    • pp.77-81
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    • 2004
  • The massive structures are not free to move with vibration, differential settlement, thermal stresses because, construction and expansion joint, crack etc., can be large enough to cause leakage as deformation of waterproofing. It has been depended on the test method of tensile/tear strength which is waterproofing performance as behavior of concrete structure crack. However, not to practically confirm the creep applied to concrete surface, even waterproofing membrane have more performance than definite strength and elasticity. Therefore, in this study will focus on the test method to consider a resistance performance about loose adhesion and deformation of waterproofing and behavior of concrete structure as construction/expansion joint, crack. Performance test method on the influence as behavior of concrete structure crack is to choose waterproofing materials and construction method which possible to confront with behavior of 50mm crack in the atmosphere and low temperature. Examine the deformation of waterproofing membrane and loose adhesion which can occur to structure in general job site, suggest standard testing method to analyze correlation waterproofing membrane and structure with 5-types of materials used in this study, such as Adhesion membrane and sheet complex, sheet and urethane complex, self-adhesive sheet, spray poly-urea, spray membrane of rubberized Asphalt.

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Performance of Large Electrode Single Cell for Proton-Exchange-Membrane Fuel Cells (고체고분자 연료전지용 대면적 단위전지의 특성)

  • Chun, Y.G.;Kim, C.S.;Peck, D.H.;Jung, D.H.;Shin, D.R.
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1255-1257
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    • 1997
  • In order to obtain key technologies for a kW class internal humidifying proton-exchange-membrane fuel cell (PEMFC) a single cell with a large electrode area has been designed and manufactured and the performance of large area membrane/electrode assemblies (MEAs) has been evaluated by using the single cell. A small area MEA made of commercial E-TEK electrode and Nafion 117 membrane showed a performance of 0.7V, $300mA/cm^2$ whereas large area MEA made of catalyst layer on carbon support and Nafion 117 showed a lower performance. To improve the performance of large MEA direct coating of catalyst was carried out on the membrane using a screen printer.

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Influence of the Catalyst Composition on Electrode Performance for Polymer Electrolyte Membrane Fuel Cells (촉매조성이 PEM용 연료전지의 전극특성에 미치는 영향)

  • 임재욱;최대규;류호진
    • Journal of the Microelectronics and Packaging Society
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    • v.9 no.3
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    • pp.43-48
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    • 2002
  • In this study, high performance electrode catalyst was developed in fabrication of membrane electrode assembly for PEMFCs(Polymer Electrolyte Membrane Fuel Cells). The I-V characteristics were measured to evaluate the influence of Nafion solution and Pt loading amount in the catalyst composition. The electrode characteristics were also investigated with respect to temperature change. The electrode performance was optimized at Nafion 5 wt% and 0.5 mg Pt/$\textrm{cm}^2$ content. The increase in the concentration of Nafion solution resulted in the decrease in electrode performance. At $80^{\circ}C$ of unit cell, I-V characteristics excelled those obtained at lower temperature. There was no difference in performance at low current density, but the improvement of voltage value in higher temperature could be found at high current density.

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Effects of surface modification of $Nafion^{(R)}$ Membrane on the Fuel Cell Performance

  • Prasanna, M.;Cho, E.A.;Ha, H.Y.;Hong, S.A.;Oh, I.H.
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2004.11a
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    • pp.133-138
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    • 2004
  • Proton exchange membrane fuel cell (PEMFC) is considered as a clean and efficient energy conversion det ice for mobile and stationary applications. Anions all the components of the PEMFC, the interface between the electrolyte ,and electrode catalyst plays an important role in determining tile cell performance since the electrochemical reactions take place at the interface in contact with tile reactant gases. Therefore, to increase the interface area and obtain a high-performance PEMFC, surface of the electrolyte membrane was roughened by Ar$^{+}$ beam bombardment. The results imply that by modifying surface of the electrolyte membrane, platinum loading can be reduced significantly without performance loss. To optimize the surface treatment condition, effects of ion dose density on characteristics of the membrane/electrode interface were examined by measuring the cell performance, impedance spectroscopy, and cyclic voltammograms. Surface of the modified membranes were characterized using scanning electron microscopy and FT-IR.R.

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Characteristics of Adsorption on the RO Membrane Surface by Coagulants Types (응집제 종류에 따른 RO막 표면 흡착 특성)

  • Jeong, Youngmi;Park, Chanhyuk;Lee, Sanghyup;Kweon, Jihyang
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.4
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    • pp.477-483
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    • 2007
  • A coagulation process for RO (reverse osmosis) membrane pretreatment system was an effective technology to remove colloidal and particulate matters. However, coagulant residuals from the pretreatment process may negatively affect RO membrane performance. The bench-scale coagulant exposure study was performed to investigate the effect of their residual on adsorbed mass which related to the membrane performance. Coagulant addition in this study ranged from 0 to 5mg/L ferric chloride, alum, and 2mg/L cationic polymer(poly-di-methyldiallyl ammonium chloride) as coagulant aids. This results showed that adsorbed mass is not significantly increased during short-time period, however, accumulated mass of coagulants on the membrane surface is significantly increased during long-time experimental period. The effect of pH on coagulants adsorption characteristics was significantly differed due to the electrostatic repulsive interactions between soluble coagulants and membrane surface charge. This data suggest that the RO membrane performance of drinking water treatment plant could be decreased by adsorption of residual coagulants when applied for the coagulant pretreatment process.

Field Application of the Membrane System for the Recovery of VOCs from the Automobile Painting Process (도장공정 휘발성 유기화합물 회수를 위한 분리막 시스템의 현장 적용성 평가)

  • Choi, Whee Moon;Cho, Soon Haing;Kim, Soon Tae;Lee, Chung Seop;Nam, Sang Yong
    • Membrane Journal
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    • v.23 no.2
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    • pp.129-135
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    • 2013
  • To recover of volatile organic compounds (VOCs) induced by painting process, we prepared separation system using hollow fiber membrane modules and evaluated the recovery performance of VOCs with different feed pressure and operating time. Concentration of volatile organic compound in permeate through the membrane increased with increasing operating time and pressure. Performance of the membrane for removing the VOCs when we applied 2-stage process showed better performance than that of single stage process.