• 제목/요약/키워드: maximum wavelength of spectrum

검색결과 88건 처리시간 0.198초

Bebq2에 (pq)2Ir(acac)가 선택 도핑된 2-파장 유기발광다이오드 (2-Wavelength Organic Light-Emitting Diodes Using Bebq2 Selectively Doped with (pq)2Ir(acac))

  • 김민영;지현진;장지근
    • 한국재료학회지
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    • 제21권4호
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    • pp.212-215
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    • 2011
  • New organic light-emitting diodes with structure of indium-tin-oxide[ITO]/N,N'-diphenyl-N, N'-bis-[4-(phenyl-m-tolvlamino)-phenyl]-biphenyl-4,4'-diamine[DNTPD]/1,1-bis-(di-4-poly-aminophenyl) cyclohexane[TAPC]/bis(10-hydroxy-benzo(h)quinolinato)beryllium[Bebq2]/Bebq2:iridium(III)bis(2-phenylquinoline-N,C2')acetylacetonate[(pq)2Ir(acac)]/ET-137[electron transport material from SFC Co]/LiF/Al using the selective doping of 5%-(pq)2Ir(acac) in a single Bebq2 host in the two wavelength (green, orange) emitter formation were proposed and characterized. In the experiments, with a 300${\AA}$-thick undoped emitter of Bebq2, two kinds of devices with the doped emitter thicknesses of 20${\AA}$ and 40${\AA}$ in the Bebq2:(pq)2Ir(acac) were fabricated. The device with a 20${\AA}$-thick doped emitter is referred to as "D-1" and the device with a 4${\AA}$-thick doped emitter is referred to as "D-2". Under an applied voltage of 9V, the luminance of D-1 and D-2 were 7780 $cd/m^2$ and 6620 $cd/m^2$, respectively. The electroluminescent spectrum of each fabricated device showed peak emissions at the same two wavelengths: 508 nm and 596 nm. However, the relative intensity of 596 nm to 508 nm at those wavelengths was higher in the D-2 than in the D-1. The D-1 and D-2 devices showed maximum current efficiencies of 5.2 cd/A and 6.0 cd/A, and color coordinates of (0.31, 0.50) and (0.37, 0.48) on the Commission Internationale de I'Eclairage[CIE] chart, respectively.

Studies on the interaction of Azo dyes with cationic surfactant(1)

  • Cho, Yung-Mee;Lee, Wang-Kyu;Kim, Bak-Kwang
    • Archives of Pharmacal Research
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    • 제4권2호
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    • pp.75-84
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    • 1981
  • As the cetyltrimenthy ammonium bromide (CTAB) concentration increases to $2{\times}10^{-4}$/M the absorption maximum of ethyl orange (EO) makes a blue shift from 475 mm to 395 mm. At higher concentration of CTAB than $2{\times}10^{-4}$ / M the absorption maximum shifts to higher wavelength than 395 nm. A new peak at 395 nm is shown to result from the mixed micelle due to dye stacking interaction rather than from a change in dye geometry. Because Raman spectra of EO on interaction with varying amount of CTAB are similar to that of EO in water. EO retains trans azo type on interaction with CTAB. There is a change of c.m.c.s. of CTAB for the mixed micelle in the presence of salt. The effect of added salt on C. M. C. of CTAB for the mixed micelle is given that the logarithm of the c. m. c. is a linear function of the logarithm of the sum of the c. m. c. and the concentration of added salt.

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Vector Passive Harmonic Mode-locking Fiber Laser Based on Topological Insulator Bi2Se3 Interacting with Fiber Taper

  • Li, Jian Ping
    • Journal of the Optical Society of Korea
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    • 제20권1호
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    • pp.135-139
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    • 2016
  • I propose a vector passive harmonic mode-locked fiber laser based on topological insulator Bi2Se3 interacting with a fiber taper with a diameter of 7 μm. The particles of topological insulator are deposited uniformly onto the fiber taper with light pressure effect. By incorporating the fabricated saturable absorber into an Er-doped fiber laser cavity, stable mode-locked fiber is obtained. Due to the intense evanescent field of the fiber taper, strong confinement of light enhances the nonlinearity of the laser cavity, and passive harmonic mode-locking is performed. I observe a maximum harmonic mode-locking of 356th, corresponding to a frequency of 3.57 GHz. The pulse duration is 824 fs, and the full width at half maximum of the spectrum is about 8.2 nm. The polarization dependent loss of the saturable absorber is ~ 2.5 dB in the wavelength range of the C band. As the cavity contains no other polarization dependent device, the mode-locked laser is functioning in the vector state. The harmonic order vs pump power is investigated. To the best of our knowledge, this report is the highest frequency mode-locked fiber laser based on Bi2Se3. Experimental results indicate that the topological insulator Bi2Se3 functioning with a thin fiber taper is effective for vector harmonic mode-locking.

다양한 상대 양이온을 갖는 Cy3 염료의 제조 및 특성 연구 (Preparation and Characterization of Cy3 Dye with Various Counter Cations)

  • 이상동;현동균;정연태
    • 한국전기전자재료학회논문지
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    • 제28권5호
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    • pp.314-319
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    • 2015
  • In this research, we focused on the development of cy3 dye with high thermal stability and good solubility for LCD color filter. Cy3 dyes were prepared through the synthetic procedure of two steps. The synthesized cy3 dyes were characterized by using NMR, FT-IR, UV/Vis spectroscopy, and TGA. These cy3 dyes showed maximum absorption wave length (${\lambda}_{max}$) in the range of 549~555 nm in UV/Vis spectrum. And we confirmed that solubility characteristics and thermal stability of cy3 dyes were dependent on the structure of counter cation. Cy3 dyes with methyl counter cation and ethyl counter cation have good solubility in organic solvents such as chloroform, ethanol, and PGME. Moreover, Cy3 dye with ethyl counter cation gave excellent thermal stability in TGA thermograms. And Cy3 dye with ethyl counter cation showed good result in photoresist film test.

대기오염 측정용 DIAL의 오차해석에 관한 연구 (Numerical Analysis of Differential Absorption Lidar for Measuring Atmospheric Pollutants)

  • 박진화;이용우
    • 대한환경공학회지
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    • 제22권1호
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    • pp.113-120
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    • 2000
  • 본 논문은 차분흡수 라이다의 알고리즘을 구성하고, UV-Bank를 이용하여 파장에 대한 $O_3$, $SO_2$ $NO_2$의 흡수스펙트럼을 조사하고, 최적파장 모텔을 설정하였다. 여기서, 선택된 파장들은 $O_3$에 대해 292.00(${\lambda}_{on}$), 295.20(${\lambda}_{off}$), $SO_2$에 대해 299.38 (${\lambda}_{on}$), 300.05(${\lambda}_{off}$) 이고 $NO_2$에 대해 448.00(${\lambda}_{on}$), 449.85(${\lambda}_{off}$) 이다. 특히, 차분흡수 라이다의 가상모델을 설정하고, 선택된 최적파장을 사용하여 측정거리에 대한 오차를 시뮬레이션 하였다. 망원경의 지름이 300 mm인 모델-I 에서 레이저의 에너지를 3 mJ 과 10000 shots을 송신했을 때, 10% 이내의 오차범위에서 최대 측정거리는 $O_3$의 경우 4 km이고, $SO_2$$NO_2$의 경우 5 km이다. 또한, 망원경의 지름이 600 mm인 모델-II에서 레이저의 에너지를 30 mJ과 10000 shots을 송신했을 때, 10%이내의 오차범위에서 최대 측정거리는 $SO_2$$NO_2$의 경우 13 km이다.

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대기오염 측정용 DIAL시스템의 오차해석 (Numerical Analysis of Differential Absorption Lidar for Measuring Atmospheric Pollutants)

  • 박진화;이용우
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2003년도 추계종합학술대회
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    • pp.428-433
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    • 2003
  • 본 논문은 차분흡수 라이다의 알고리즘을 구성하고, UV-Bank를 이용하여 파장에 대한 $O_3$, S $O_2$ N $O_2$의 흡수스펙트럼을 조사하고, 최적파장 모델을 설정하였다. 여기서, 선택된 파장들은 $O_3$에 대해 292.00(λ$_{on}$ ), 295.20(λ$_{off}$), S $O_2$에 대해 299.38 (λ$_{on}$ ), 300.05(λ$_{off}$)이고 N $O_2$에 대해 448.00(λ$_{on}$ ), 449.85(λ$_{off}$)이다. 특히, 차분흡수 라이다의 가상모델을 설정하고, 선택된 최적파장을 사용하여 거기에 대한 오차를 시뮬레이션 하였다. 망원경의 지름이 300 mm인 모델-I에서 레이저의 에너지를 3 mJ과 10000 shots을 송신했을 때, 10%이내의 오차범위예서 최대 측정거리는 $O_3$의 경우 4 km이고, S $O_2$와 N $O_2$의 경우 5km이다. 또한, 망원경의 지름이 600 mm인 모델-II에서 레이저의 에너지를 30 mJ과 10000 shots을 송신했을 때, 10%이내의 오차범위에서 최대 측정거리는 S $O_2$와 N $O_2$의 경우 13 km이다. km이다.

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Analysis of Solar Irradiance Measurement From a Multi-Filter Radiometer At Kwangju, South Korea.

  • Ogunjobi, K.O.;Kim, Y.J.;He, Z.;Ryu, S.Y.
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2001년도 추계학술대회 논문집
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    • pp.335-335
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    • 2001
  • Direct-normal, total horizontal and diffuse horizontal irradiance data obtained from a multi-filter rotating shadowband radiometer over seven different wavelength bands (416nm, 151nm, 616nm, 675nm, 870nm and 940nm and the entire spectrum) has been analyzed at Kwangju, South Korea from June 1998 December 2000. The maximum hourly global radiation flux ranged from 0.44 MJ/$m^2$ to 2.68 MJ/$m^2$ at around 11:00-12:00 Hr local time while the maximum hourly diffuse radiation flux ranged from about 0.96 MJ/$m^2$ to 1.37 MJ/$m^2$. The maximum hourly direct irradiance ranged from 1.42 MJ/$m^2$ to 2.92 MJ/$m^2$ from June1998-2000. During the period under consideration, the average monthly global radiation recorded were 13.09 MJ/$m^2$/day, 10.58MJ/$m^2$/day and 9.78MJ/$m^2$/day for years 1998, 1999 and 2000 respectively, while the diffuse irradiance were 6.54 MJ/$m^2$/day, 5.33 MJ/$m^2$/day and 5.14 MJ/$m^2$/day for f998, 1999 and 2000 respectively. The direct irradiance values at the site were 11.63 MJ/$m^2$/day, 8.24MJ/$m^2$/day and 7.75 MJ/$m^2$/day for 1998, f999 and 2000 respectively. It was observed that each of the years has its own unique meteorological parameters that affect the quality and quantity of radiation received for each month. The annual average daily fractions of the diffuse to the global radiation (KD) were 0.51, 0.61 and 0.59 for years 1998, 1999 and 2000 respectively. Analysis indicated that the average daily KD ranged from 0.13 to a maximum value of 0.99 in May for irradiance measured at the broadband channel while the maximum and minimum KD value of 0.91 and 0.23 was recorded at wavelength band 870nm and 940nm in January and September respectively. The lowest average daily clearness index (Kt) value recorded was 0.03 in May (Spring) and the annual average daily clearness indexes are 0.45, 0.34 and 0.35 for years 1998, f999 and 2000 respectively. The frequency of clear days annually at Kwangju is 67.95%, 29.57% and 40.72% for years 1998, 1999 and 2000 respectively.

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형광 광도계 설계인자 도출을 위한 기름의 형광 스펙트럼 분석 (Oil Fluorescence Spectrum Analysis for the Design of Fluorimeter)

  • 오상우;서동민;안기영;김재우;이문진;전태병;서성규
    • 한국해양환경ㆍ에너지학회지
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    • 제18권4호
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    • pp.304-309
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    • 2015
  • 해양에서 기름 유출 사고로 인한 오염도를 정량적으로 평가하기 위해서, 사고 현장에서 기름을 직접 탐지할 수 있는 센서의 적용이 필요하다. 여러 형태의 기름 탐지 센서 중에서, 기름 성분에 의한 형광 현상(fluorescence)을 탐지 원리로 하는 센서는 해수 중에 존재하는 기름의 농도를 측정할 수 있으므로 효용성이 높은 장점을 갖고 있다. 그러나 이런 종류의 센서는 기름의 형광 현상을 야기시키기 위해서, 수은 램프(mercury lamp)와 같은 자외선 광원(ultraviolet light source)이 필요하고 다양한 종류의 광학 필터와 광전증배관(photomultiplier tube, PMT)과 같은 광학 센서가 주로 사용된다. 이러한 이유로 형광 측정을 기반으로 하고 있는 센서는 측정 플랫폼의 크기가 크기 때문에 현장에서 원활히 사용하기에 한계가 있으며, 고가의 부품들이 집적되어 있어, 센서의 가격이 높은 단점을 갖고 있다. 이러한 단점을 극복하기 위해서, 본 논문에서는 소형의 크기와 가격 경쟁력을 갖고 있는 형광 광도계 기반의 기름 탐지 센서를 설계하는 방법에 대해서 제시하였다. 형광 광도계의 설계 인자를 파악하기 위한 방법으로, 본 연구에서는 5종의 원유 샘플과 3종의 정제유를 이용하여, 기름의 여기 스펙트럼(excitation spectrum)과 발광 스펙트럼(emission spectrum)을 측정하였다. 여기 스펙트럼과 발광 스펙트럼의 측정을 위해서는 형광 분광기(fluorescence spectrometer)를 이용하였고, 측정된 스펙트럼 자료를 분석하여 형광 광도계(fluorimeter) 설계에 필요한 유종에 따른 공통 스펙트럼 파장 대역을 도출하였다. 본 실험을 통해서 모든 종류의 기름 샘플의 경우, 여기 스펙트럼과 발광 스펙트럼의 최고 값을 갖는 파장의 차이는 약 50 nm인 것으로 파악되었다. 실험 중에서, 여기광의 파장을 365 nm와 405 nm로 고정하였을 경우, 280 nm와 325 nm로 고정하였을 경우에 비해서 최대 발광(emission)의 세기가 작아지는 것을 확인할 수 있었다. 따라서 형광 광도계의 광원 파장을 365 nm 또는 405 nm로 사용할 경우, 광학 센서의 민감도(sensitivity)가 발광되는 빛의 세기를 측정할 수 있도록 설계에 반영해야 할 것으로 판단된다. 본 연구의 실험에서 도출된 결과를 통해서, 기름 탐지를 위한 형광 광도계의 광원, 광학 센서 그리고 광학 필터의 유효 파장 대역을 선택하는데 필요한 설계 인자를 파악할 수 있었다.

Physical modeling of dust polarization spectrum by RAT alignment and disruption

  • Lee, Hyeseung;Hoang, Thiem
    • 천문학회보
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    • 제46권2호
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    • pp.38.1-38.1
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    • 2021
  • Dust polarization depends on the physical and mechanical properties of dust, as well as the properties of local environments. To understand how dust polarization varies with grain mechanical properties and the local environment, in this paper, we model the wavelength-dependence polarization of starlight and polarized dust emission by aligned grains by simultaneously taking into account grain alignment and rotational disruption by radiative torques (RATs). We explore a wide range of the local radiation field and grain mechanical properties characterized by tensile strength. We find that the maximum polarization and the peak wavelength shift to shorter wavelengths as the radiation strength U increases due to the enhanced alignment of small grains. Grain rotational disruption by RATs tends to decrease the optical-near infrared polarization but increases the ultraviolet polarization of starlight due to the conversion of large grains into smaller ones. In particular, we find that the submillimeter (submm) polarization degree at 850㎛(P850) does not increase monotonically with the radiation strength or grain temperature (Td), but it depends on the tensile strength of grain materials. Our physical model of dust polarization can be tested with observations toward star-forming regions or molecular clouds irradiated by a nearby star, which have higher radiation intensity than the average interstellar radiation field. Finally, we compare our predictions of the P850-Td relationship with Planck data and find that the observed decrease of P850 with Td can be explained when grain disruption by RATs is accounted for, suggesting that interstellar grains unlikely to have a compact structure but perhaps a composite one. The variation of the submm polarization with U (or Td)can provide a valuable constraint on the internal structures of cosmic dust

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전면 유기 발광 소자의 유기물층과 반투명 전극의 두께 변화에 따른 광학적 특성 (Organic-layer and semitransparent electrode thickness dependent optical properties of top-emission organic light-emitting diodes)

  • 안희철;주현우;나수환;한원근;김태완;이원재;정동회
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.57-58
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    • 2008
  • We have studied an organic layer and semitransparent Al electrode thickness dependent optical properties and microcavity effects for top-emission organic light-emitting diodes. Manufactured top-emission device structure is Al(100nm)/TPD(xnm)/Alq(ynm)/LiF(0.5nm)/Al(25nm). While a thickness of total organic layer was varied from 85nm to 165n, a ratio of those two layers was kept to be about 2:3. Semitransparent Al cathode was varied from 20nm to 30nm for the device with an organic layer total thickness of 140nm. As the thickness of total organic layer increases, the emission spectra show a shift of peak wavelength from 490nm to 580nm, and the full width at half maxima from 90nm to 35nm. The emission spectra show a blue shift as the view angle increases. Emission spectra depending on a transmittance of semitransparent cathode show a shift of peak wavelength from 515nm to 593nm. At this time, the full width at half maximum was about to be a constant of 50nm. With this kind of microcavity effect, we were able to control the emission spectra from the top-emission organic light-emitting diodes.

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