• Journal of the Korean Chemical Society
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• v.37 no.3
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• pp.335-343
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• 1993

The maximum absorption wavelengths of charge-transfer complexes of naphthalene, ${\alpha}-and{\beta}-methyl$ naphthalene and 1,2-, 2,3-and 2,6-dimethyl naphthalene with chloranil have been measured with a UV spectrophotometer in ethylene chloride, methylene chloride, and chloroform at 10, 15, 20, and 25$^{\circ}C$. This absorption band was interpreted as the charge transfer band of a 1 : 1 molecular complex, and the maximum absorption wavelength was changed as a function of solvent and temperature. Their formation constants (K$_f$) were decreased with the polarity of solvent and the increase of temperature. Thus, the influences of solvent and temperature on the formation constant have been discussed as consideration of thermodynamic properties, and the electronic and steric effects of electron donors on formation constant have been also discussed.

• Journal of Sensor Science and Technology
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• v.32 no.5
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• pp.285-289
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• 2023

Recently, the demand for lidar systems for autonomous driving is increasing, and research on Shortwave Infrared(SWIR) photodetectors for this purpose is being actively conducted. Most SWIR photodetectors currently being developed are based on InGaAs, and have the disadvantages of complex processes, high prices, and limitations in research due to monopoly. In addition, current SWIR photodetectors use lasers in the 905 nm wavelength band, which can pass through the pupil and cause damage to the retina. Therefore, it is required to develop a SWIR photodetector using a wavelength band of 1400 nm or more to be safe for human eyes, and to develop a material that can replace the proprietary InGaAs. PbS QDs are group 4-6 compound semiconductors whose absorption wavelength band can be adjusted from 1000 to 2700 nm, and have the advantage of being simple to process. Therefore, in this study, PbS QDs having an absorption wavelength peak of 1415 nm were synthesized, and a SWIR photodetector was fabricated using this. In addition, the photodetector's responsivity was improved by applying P3HT and ZnO NPs to improve electron hole mobility. As a result of the experiment, it was confirmed that the synthesized PbS QDs had excellent FWHM characteristics compared to commercial PbS QDs, and it was confirmed that the photodetector had a maximum current change of about 1.6 times.

• Journal of Environmental Science International
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• v.32 no.1
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• pp.25-35
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• 2023

The purpose of this study was to determine the optimal sound absorption conditions by comparing the sound absorption characteristics of fresh and air-dried leaves of Quercus glauca, the main species of evergreen broadleaf trees (EBLT) in southern Korea. The sound absorption coefficients (SACs) obtained under 18 conditions were comparatively analyzed. The SAC of air-dried leaves improved significantly with increasing leaf layer thickness. The highest average SAC in the fresh leaf group was 0.617, which was observed under the condition of a leaf specimen size of 0.5 × 0.5 cm² and a leaf layer thickness of 1.75 cm. In a group of air-dried leaves, this was 0.615 under the condition of a leaf specimen size of 0.5 × 0.5 cm² and a leaf layer thickness of 2.50 cm. The maximum value of SAC for each wavelength was observed under the condition of a leaf layer thickness of 2.50 cm consisting of 0.5 × 0.5 cm² leaf specimens, ranging from 1,400 Hz to 1,500 Hz.

• Journal of Korean Ophthalmic Optics Society
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• v.4 no.2
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• pp.65-71
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• 1999

The optical absorption spectrum was measured of the tinted powder, tinted solution and tinted lens in the visible regions. The tinted powder was very different with color of tinted lens that the optical absorptions was so higher, composed of the thick-gray color. The optical absorptions of tinted solution were just a little appeared by the energy split of a transition metal ion, so constructed with each color space. The optical absorptions of the tinted lens were appeared with the energy split peaks to a transition metal ion, so its were affected by the color constructions. The optical absorption peaks of each lens were depend on the tinted time. Blue color lens had a lot of absorption in the short wavelength regions than 500nm, and had a little appeared in the high wavelength regions than 500nm. In case of a yellow color, the optical absorptions were appeared quite contrary to the blue color, so these colors had the opponent-colors each other. In case of green color, the optical absorptions had a high in the both edges, had a low in the middle regions. In the pink color, by the optical absorptions form of quite contrary to the green color it, these colors had the opponent-colors each other. In the brown color, the optical absorptions had a maximum values in the short wavelength regions, and it gradually decreased goes by the long wavelength regions.

• Textile Coloration and Finishing
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• v.13 no.3
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• pp.165-171
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• 2001

In this study, UV/vis. spectra of color solution extracted from onion shell and dyeing properties of polyamide fibers such as wool, silk, and nylon were investigated. Also, the effect of mordanting on wash fastness and light fastness was Investigated. The amount of colors extracted was increased with extracting temperature and time. The wavelength of maximum absorption of onion shell extract corresponds to flavonol peak and quercetin peak. Also, spectra of color solution were shifted to longer wavelength at higher pH values. It appeared that the optimum condition of the dyeing of wool, nylon, and silk fabrics with onion shell extract was $60^\circ{C}$ , 30min, and pH 4.0 of dyed bath. Surface colors of the dyed fabrics were different according to the used mordants: Al and Cr mordanted fabrics were dyed in yellowish colors, Cu mordanted fabric in greenish color, Sn mordanted fabric in orange color, and Fe mordanted fabric in khaki color. The mordanting was effective at improving wash fastness and light fastness.

• Textile Coloration and Finishing
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• v.10 no.5
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• pp.56-62
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• 1998

In the prior study, the dyeing behaviors of Milling Cyanine 5R on silk fiber in aqueous dyeing liquor including small amount of organic compounds were investigated. The most effective compound was acetophenone which increased dye uptake as well as dyeing rate. In this study, the role of the acetophenone in dyeing of silk with Milling Cyanine 5R was studied. By addition of acetophenone into the dye solution, the molar absorptivity of Milling Cyanine 5R increased, and the wavelength of maximum absorption was shifted to longer wavelength, namely bathochromic shifted. This shows that the acetophenone prevents the dye to aggregate, and increases the number of monomeric dye molecule relative to the dye solution without acetophenone. This fact was also confirmed by the increase of the permeation rate of the dye through cellulose semipermeable membrane from the dye solution including the acetophenone. From these results, the acetophenone acts as a prohibitor of dye aggregation, increases the number of monomeric dye molecules even at relatively low temperature, and makes the dyes penetrate into the fiber easier.

• Textile Coloration and Finishing
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• v.12 no.6
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• pp.353-360
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• 2000

In this article, arrowroot is extracted in distilled water, and its dyeing properties on wool, nylon, and silk were investigated. Also the effect of mordanting (Al, Cu, Sn, Fe and Cr compounds) on the wash fastness are measured. The wavelength of maximum absorption of the arrowroot extract appears at 250 and 300nm below pH 7, but they shifted to longer wavelength at higher pH values. It appears that the optimum condition of the dyeing of wool, nylon, and silk fabric with arrowroot extract is $60^\circ{C}$, 60 min, and pH 4.0. Mordant treatments are effective in improving wash fastness of polyamide fabrics.

• Journal of Photoscience
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• v.9 no.2
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• pp.317-319
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• 2002

All-optical switching has been demonstrated in bacteriorhodopsin (bR) based on nonlinear intensity induced excited state absorption. The transmission of a cw probe laser beam at 410 nm corresponding to the peak absorption of M state through a bR film is switched by a pulsed pump laser beam at 570 nm that corresponds to the maximum initial 8 state absorption. The switching characteristics have been analyzed using the rate equation approach considering all the six intermediate states (B, K, L, M, N and 0) in the bR photocycle. The switching characteristics are shown to be sensitive to life time of the M state, absorption cross-section of the 8 state at probe wavelength ($\sigma$ $\_$Bp/) and peak pump intensity. It has been shown that the probe laser beam can be completely switched off (100 % modulation) by the pump laser beam at relatively low pump powers, for $\sigma$$\_$Bp/ = O. The switching characteristics have been used to design all-optical NOT, OR, AND and the universal NOR and NAND logic gates for optical computing with two pulsed pump laser beams.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.179.1-179.1
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• 2014

Si nanowires have exhibited unique optical characteristics, including nano-antenna effects due to the guided mode resonance, significant optical absorption enhancement in wide wavelength and incident angle range due to resonant optical modes, graded refractive index, and scattering. Since Si poor optical absorption coefficient due to indirect bandgap, all such properties have stimulated proposal of new optoelectronic devices whose performance can surpass that of conventional planar devices. We have carried out finite-difference time-domain simulation studies to design optimal Si nanowire array for solar cell applications. Optical reflectance, transmission, and absorption can be calculated for nanowire arrays with various diameter, length, and period. From the absorption, maximum achievable photocurrent can be estimated. In real devices, serious recombination loss occurring at the surface states is known to limit the photovoltaic performance of the nanowire-based solar cells. In order to address such issue, we will discuss how the geometric parameters of the array can influence the spatial distribution of the optical field (resulting optical generation rate) in the nanowires.

• The Korean Journal of Food And Nutrition
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• v.2 no.1
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• pp.18-26
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• 1989

The objective of this study was to improved the limited functional characteristics of mungbean whole globulin. The mungbean whole globulin was acylated with succinic and acetic anhydride, and the functional properties of acylated protein were investigated, The results obtained ware as follows. 1. The UV-absorption spectra of acylated whole globulins with that of the succinylated 74% whole globulin as large blue shift of the absorption maximum and minimum wavelength from 275 nm to 269 nm, respectively. 2. The mobility of acylated whole globulin were increased on PAGE pattern, and degree of mobility was particularly remarkable in case of succinylation, 3. The water absorption capacity of whole globulin was increased by acylation. The most increased rate of whole globulin was 174,02% from succinylated 74%. The oil absorption capacity of whole globulin was increased by acylation The most increased rate of whole globulin was 165.41% from acetylated 81.77%. 4. The bulk density of whole globulin was decreased by acylation. and the greater the extent of acylation, the smaller the bulk density. 5. The foaming capacity and stability of whole globulin was increased by acylation, and remarkably high in 74% succinylated whole globulin. In contrast, however, the foaming capacity and stability of native and acylated whole globulin were decreased by heat treatment.