• Title/Summary/Keyword: maximum absorption

Search Result 1,131, Processing Time 0.028 seconds

Relationship between Substituents of Aminoazobenzene Disperse Dyes and Dyeing Properties (아미노아조벤젠계 분산염료의 치환기와 염색성과의 관계)

  • Kim, Sung Dong;Kwak, Tae Soo;Lee, In Yeol
    • Textile Coloration and Finishing
    • /
    • v.9 no.6
    • /
    • pp.1-9
    • /
    • 1997
  • Four aminoazobenzene disperse dyes derived from different N-ethyl-N-substitutedalkylanilines and 2-chloro-4-nitroaniline, were synthesized and their chemical structure were analyzed by 500 MHz NMR spectroscopy. The wavelength of maximum absorption of the synthesized dyes, which was dependent on the electron withdrawing ability of the substituent, was in the range of 499.5~526.0nm. As terminal substituent became polar, the dyeing rate of disperse dye increased, and the exhaustion rate of dyes having cyano or hydroxy group became lower, that of the dye having acetoxy group higher. The wash fastness of polyester fabric dyed with disperse dyes possessing the polar group improved probably due to the increased dye-fiber interaction.

  • PDF

Synthesis of a Super Hydrophobic Violet Dye for Pure Polyolefin(PP/UHMWPE) Fibers (순수 폴리올레핀(PP/UHMWPE) 소재용 초소수성 보라색 염료의 합성)

  • Kim, Taekyeong;Lee, Changwhan
    • Textile Coloration and Finishing
    • /
    • v.25 no.3
    • /
    • pp.165-171
    • /
    • 2013
  • A new monoazo violet dye optimized for polyolefin fibers such as polypropylene and ultra high molecular weight polyethylene fibers was synthesized and its dyeability was investigated. Two hexyl groups were introduced to coupler, 2,5-dimethoxyaniline, in order to increase hydrophobicity of the dye. The maximum absorption wavelength was appeared at 580nm, which meant that the dye showed violet color. From the dyeing results at various conditions, the optimum dyeing was determined as $130^{\circ}C$ for 1 hour with 5% owf of dyes. The good fastness ratings to washing, rubbing were obtained showing at least 4 for both fibers. Light fastness was acceptable for polypropylene fibers giving ratings 3~4. However, relatively poor light fastness was obtained in case of ultra high molecular weight polyethylene fibers showing ratings 2.

Analysis of Germanium in the Ore Samples by UV-Visible Spectroscopy

  • Reddy, K. Raghava;Lee, Kwang-Pill;Gopalan, Anantha Iyengar;Showkat, Ali Md;Kim, Sang-Ho;Paek, U-Hyon
    • Analytical Science and Technology
    • /
    • v.17 no.6
    • /
    • pp.476-480
    • /
    • 2004
  • A simple, rapid, reproducible and selective UV-Visible spectrophotometric method has been developed for determination of germanium in a week acid medium (pH = 3.0) in the presence of mandelic acid (MA) and malachite green (MG). A single extraction in chlorobenzene was used for the analysis. The germanium-MA ion association complex exhibits an absorption maximum at ${\lambda}_{max}=618nm$ with MG as counter ion and has an apparent molar absorptivtity of $1.313{\times}10^5L\;mol^{-1}\;cm^{-1}$. The values obtained by this UV-Visible spectrophotometric method are in good agreement with the values from inductively coupled plasma-mass spectrometer analysis.

Geological Mapping using SWIR and VNIR Bands of ASTER Image Data

  • Shanmugam, Sanjeevi;Singaravelu, Jayaseelan
    • Proceedings of the KSRS Conference
    • /
    • 2003.11a
    • /
    • pp.1230-1232
    • /
    • 2003
  • This study aims to extract maximum geological information using the ASTER (Advanced Spaceborne Thermal Emission and Reflection radiometer) images of a part of south India. The area chosen for this study is characterized by rock types such as Migmatite, Magnetite Quartzite, Charnockite, Granite, dykes, Granitoid gneiss and Ultramafic rocks, and minerals such as Bauxite, Magnesite, Iron ores, Calcite etc. Advantage was taken of the characteristic reflectance and absorption phenomenon in the VNIR, SWIR and TIR bands for these rocks and minerals, and they were mapped in detail. Image processing methods such as contrast stretching, PC analysis, band ratios and fusion were used in this study. The results of the processing matched with the field details and showed additional details, thus demonstrating the usefulness of ASTER (especially the SWIR bands) data for better geological mapping.

  • PDF

Numerical Simulation: Effects of Gas Flow and Rf Current Direction on Plasma Uniformity in an ICP Dry Etcher

  • Joo, Junghoon
    • Applied Science and Convergence Technology
    • /
    • v.26 no.6
    • /
    • pp.189-194
    • /
    • 2017
  • Effects of gas injection scheme and rf driving current configuration in a dual turn inductively coupled plasma (ICP) system were analyzed by 3D numerical simulation using CFD-ACE+. Injected gases from a tunable gas nozzle system (TGN) having 12 horizontal and 12 vertical nozzles showed different paths to the pumping surface. The maximum velocity from the nozzle reached Mach 2.2 with 2.2 Pa of Ar. More than half of the injected gases from the right side of the TGN were found to go to the pump without touching the wafer surface by massless particle tracing method. Gases from the vertical nozzle with 45 degree slanted angle soared up to the hottest region beneath the ceramic lid between the inner and the outer rf turn of the antenna. Under reversed driving current configuration, the highest rf power absorption region were separated into the two inner islands and the four peaked donut region.

Purification and partial characterization of bacillus thuringiensis var.thuringiensis exotoxin (Bacillus thuringiensis var. thuringiensis가 생산하는 .betha.-exotoxin의 정제와 특성)

  • 심창범;이형환;이희무
    • Korean Journal of Microbiology
    • /
    • v.23 no.4
    • /
    • pp.271-281
    • /
    • 1985
  • Bacillus thuringiensis var. thuringiensis produces an extracellular insecticidal thermostable .betha.-exotoxin, which was purified through microfiltering, barium precipitation, charcoal absorption chromatography, ion exchange column chromatography and gel filtration. The exotoxin in each purification step was detedted by thin layer chromatography, high pressure liquid chromatography and paper electrophoresis with efficient results. The exotoxin productivity on time course was checked by spectrophotometric absorbance at 258nm with the result that the exotoxin was initially produced in 6 hour culture and reached maximum value in 36 hour culture. Anti-bacterial effect test on Micrococcus flava was applied as toxicity test. The results showed that frowth inhibition of M. flava could be shown in plate assay of cell free filtered supernatant, alkaline eluant from charcoal and purified exotosin obtained from gel filtration column chromatography on Sephadex G-10 appeared to be 740. Heat stability of the exotoxin was confirmed through autoclaving twice.

  • PDF

Fabrication of Ultra Thin Films with (N-docosyl quinolinium)-TCNQ(1:2) complex by the Langmuir -Blodgett Technique (Langmuir-Blodgett법을 이용한 (N-docosyl quinolinium)-TCNQ(1:2) 착물의 초박막 제작)

  • Jeong, Soon-Wook;Jeong, Hwae-Gul
    • Korean Journal of Materials Research
    • /
    • v.9 no.12
    • /
    • pp.1229-1233
    • /
    • 1999
  • In this research, We fabricated Langmuir-Blodgett(LB) ultra-thin films with (N-docosyl quinolinium)- TCNQ(1:2) complex. The characteristics ${\pi}$-A isotherms were studied to find optimum conditions of deposition by varing temperature of subphase, compression speed of barrier and amount of spreading solution. Film formation was verified by measuring transfer ratio, maximum absorption of UV-vis spectra, capacitance and ellipsometry. From the results, it was concluded that the LB film formed well with molecular oder was fabricated.

  • PDF

Dyeing Properties of Protein and Polyamide Fabrics with Arrowroot Extract (칡뿌리를 이용한 단백질 및 폴리아미드 섬유의 염색성)

  • 이정은;이문철;최석철
    • Textile Coloration and Finishing
    • /
    • v.12 no.6
    • /
    • pp.353-360
    • /
    • 2000
  • In this article, arrowroot is extracted in distilled water, and its dyeing properties on wool, nylon, and silk were investigated. Also the effect of mordanting (Al, Cu, Sn, Fe and Cr compounds) on the wash fastness are measured. The wavelength of maximum absorption of the arrowroot extract appears at 250 and 300nm below pH 7, but they shifted to longer wavelength at higher pH values. It appears that the optimum condition of the dyeing of wool, nylon, and silk fabric with arrowroot extract is $60^\circ{C}$, 60 min, and pH 4.0. Mordant treatments are effective in improving wash fastness of polyamide fabrics.

  • PDF

Dyeing Properties of Protein and Synthetic Fibers with the Tumeric Extracts (울금 색소 추출물에 의한 단백질계 및 합성섬유의 염색성)

  • 한신영;최석철
    • Textile Coloration and Finishing
    • /
    • v.12 no.6
    • /
    • pp.396-403
    • /
    • 2000
  • The purpose of this study was to investigate the dyeing properties of silk, wool, nylon and poly(ethylene teraphtlate)〔PET〕 fabrics dyed with Tumeric(Curcuma longa) extracts. The dyeing property and color fastness were investigated by using the extracts and the post mordanting with Aluminum, Copper and Iron salts. In the UV-visible spectra, the maximum absorption of wavelength of the extract with methyl alcohol appeared at 420nm, and that of the extract with distilled water was at 415nm. Increasing the dyeing temperature, the K/S values of dyed fabrics were increased. The optimum dyeing condition was 30∼60 minute of dyeing time at pH 5∼5.6. Surface colors of silk and wool became dark by using mordants compared to those of nylon and PET fabrics. The drycleaning fastness of fabrics dyed with the extracts was good. The laundering and light fastness were improved by using mordants.

  • PDF

The Synthesis of Red-Sensitizing Dye for Color Photography (천연색 사진용 적감색소의 합성)

  • Kim, Yeoung-Chan
    • Journal of the Korean Applied Science and Technology
    • /
    • v.18 no.2
    • /
    • pp.136-141
    • /
    • 2001
  • Naphthothiazolo carbocyanine is of industrial importance as red-sensitizing dye in the spectral sensitization of emulsion microcrystals in negative film-making. In this study, red-sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4,5-naphthothiazolium(inner salt) with triethyl orthoacetate in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, Mass spectrometer, $^{1}H-NMR$ spectrometer, TGA and DSC. The maximum absorption peak in methanol solvent was 573nm. Therefore, it was concluded that naphthothiazolo carbocyanine dye can be used as red0sensitizing dye for the spectral sensitization of photographic emulsion.