• Title/Summary/Keyword: maximum absorption

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Studies on Isolative Determination of dl- Methylephedrine hydrochloride from Complex Preparation (복합제제(複合製劑) 성분중(成分中) dl-Methylephedrine hydrochloride의 분리정량(分離定量))

  • Kim, Byung-Hi;Yong, Jae-Ick
    • Journal of Pharmaceutical Investigation
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    • v.3 no.1_2
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    • pp.5-15
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    • 1973
  • Fluorometric determination of dl-Methylephedrine hydrochloride from complex preparation were studied. According to the experimental results and considerations obtained the results for the following. (1) dl-Methylephedrine hydrochloride in Hydrochloric acid media occurs the fluorescens by Picrolonic acid and Cuppric acetate. (2) The maximum absorption fluorescence wave length of dl-Methylephedrine hydrochloride standard solution is $365m{\mu}$. (3) The relationship between the fluorescence proportions to concentration of standard solution at range of $4.2{\times}10^{-4}\;M$. $6{\times}10^{-4}M$. (4) dl-Methylephedrine hydrochloride was precisely determined even in the presence of various components, especially Chloropheniramine maleate, Dextromethorphan hydrobromide and Diphenylhydramine hydrochloride. (5) This method has high sensitivity and is simple in precedure. (6) This method be applicable with 99.79% accuracy and was 99.5% in complex preparation.

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Studies on the Synthesis of (3 - Alkyl benzimidazolium)-TCNQ Complexes (유기전하 이동착체의 합성에 관한 연구)

  • Sohn, Byoung-Chung;Hwang, Kyo-Hyun;Jeong, Soon-Wook
    • Journal of the Korean Applied Science and Technology
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    • v.11 no.1
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    • pp.33-37
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    • 1994
  • In this research, (3-alkyl benzimidazalium)-TCNQ complexes were synthesized to obtain the necessary components for Langmuir-Blodgett Technique. (3- Alkyl benzimidazolium)-TCNQ complexes were prepared by the reaction of LiTCNQ with 3-alkyl benzimidazolium bromides and the products were confirmed by elemental analysis. FT-IR, UV-Visible spectroscopies. FT-IR spectra of (3-alkyl benzimidazolium) TCNQ(1:2) complexes were characterized by a broad band with a maximum at about $2900cm^{-1}$ appears and were ascribed to electronic rather than vibrational absorption.

VUV luminescence properties of a novel green-emitting $(Y,Gd)Ga_3(BO_3)_4$:Tb phosphor

  • Moon, Young-Min;Choi, Sung-Ho;Lim, Sang-Ho;Jung, Ha-Kyun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1561-1564
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    • 2007
  • $Tb^{3+}-activated$ green-emitting $(Y,Gd)Ga_3(BO_3)_4$ phosphor has been investigated. The main absorption was in the $120{\sim}238$ nm and exhibited a green emission with the 545 nm and several peaks due to inner shell transition of $Tb^{3+}$ ion. With the optimized $Tb^{3+}$ concentrations, the maximum emission brightness was 90% of the $Zn_2SiO_4$:Mn phosphor.

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Spectrophotometric study of the cadmium (II) complex of 1-isonicotinyl-2-furfurylidene hydrazine (1-isonicotinyl-2-furfurylidene hydrazine-Cd(II) 착화합물에 관한 분석화학적연구)

  • 백남호;박만기
    • YAKHAK HOEJI
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    • v.13 no.1
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    • pp.33-37
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    • 1969
  • A new organic reagent, 1-isonicotynyl-2-furfurylidene hydrazine synthesized from isonicotinic acid hydrazid and furfural, gives yellow liquid with cadmium (II). Cadmium complex of the reagent is soluble in water with yellow coloration. The complex has a maximum absorption at 363 m${\mu}$ and molar ratio of cadmium to reagent was estimated as 1:1 by continuous variation method and slope method. Molecular extinction coefficient and apparent formation constant of this complex was spectrophotometrically determined. K=4.48 $\times$ 10$^{3}$ (Babko's method) K=1.33 $\times$ 10$^{3}$ (Anderson's method)

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Vanillin의 신미량검출법 (제1보)

  • 이상섭;김용덕
    • YAKHAK HOEJI
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    • v.3 no.1
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    • pp.48-50
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    • 1957
  • The micro-assay methods of vanillin have been shown quite few, though several methods have been introduced for determination. A new sensitive micro-determination of vanillin, applying the yellow color reaction of vanillin and anillin, is shown in this paper. The absorption maximum of the yellow coloring matter, 4-Oxy-3-methoxy-henzal aniline, was 435 mu. The one dimensional ascending paper chromatographic method is applyed for isolation of vanillin from the mixed sample. The microdetection of vanillin is studied only in this paper. Vanillin was detected by the yellow spot on paper trip by the coloring reagent of aniline after several hours paper strip chromatographic at the following condition; paper strip ................ 2.5 X 35cm Whatman Filter Paper No.2 developing Solvent ......... petroleum-benzene-methanol n-butanol-water coloring agent ............. aniline. The Rf-value on petroleum benzene and methanol was 0.63 and that on n-butanol and water was 0.90. The minimum detectable amount of vanillin by this method was 10 micrograms. It is recommendable, if interference substances as aromatic aldehydes present, that the application of this aniline reaction and Foline Denis reaction on the same paper chromatogram is appreciable.

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Studies on 1-Isonicotinoyl-2-furfurylidene hydrazine-Cu(II) Complex Compound. (1-Isonicotinoyl-2-furfurylidene Hydrazine-Cu(II) 착화합물에 관한 분석화학적연구)

  • 백남호;최윤수
    • YAKHAK HOEJI
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    • v.9 no.1_2
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    • pp.18-22
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    • 1965
  • A new organic reagent, 1-isonicotinoyl-2-furfurylidene hydrazine was synthesized from isonicotinic acid hydrazide and furfural, gives precipitate with copper(II), mercury(II) and argent(I), whereas, it gives a water soluble yellow complex with iron(III). Copper complex of the reagent is soluble in EtOH MtOH, pyridine, dioxane and dimethylformamide with green yellow coloration. The complex has a maximum absorption at 385 m.$\mu$ and molar ratio of copper; reagent was estimated as 1:1 by continuous variation method, slop method and chelate titration method. Molar extinction coefficient (9600) and apparant formation constant of this complex was spectrophotometrically determined. K=1.7 * $10^{7}$ (Babko's method) K=2.1 * $10^{7}$ (Anderson's method). This reagent reacted with copper so sensitive that it would be available for determination of Cu (II).

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Synthesis, Characterization, and Properties of Ethoxylated Azo Dyes

  • Shen, Kaihua;Choi, Dong Hoon;Li, Zongshi
    • Fibers and Polymers
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    • v.4 no.1
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    • pp.32-37
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    • 2003
  • The nonionic surfactant properties of ethoxylated azo dyes, such ai cloud point and surface tension have been investigated. The synthesized ethoxylated azo dyes could dye polyester fabric without any special pre-treatment. When the average number of ethylene oxide (EO) in the ethoxylated azo dye reached 6, its fixation could exceed $90^{\circ}C$ from the thermosol dyeing process. The average degree of condensation of ethylene glycol in the chain was interrelated with the dyeing results and did not affect on the maximum absorption wavelength (λmax) of the polyoxyethylene dye. When the average length of polyoxyethylene chain decreased, the molecular weight of dyes became smaller and the fixation of dyes was improved.

Electrical Relaxation in Silica Glasses and Nonlinearity in Electrical Conductivity (실리카 유리의 전기이완 특성과 비선형적 전기전도도)

  • 신동욱
    • Journal of the Korean Ceramic Society
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    • v.36 no.9
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    • pp.923-929
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    • 1999
  • The cause of optical nonlinearity induced in thermally poled silica glass is believed to be the space charge polarization. Since the second order optical nonlinearity (electro-optic effect) can be used in optical switches the optical nonlinearity in silica glass has drawn a large attention. Space charge polarization occurs when an ionic conducting material is subjected to dc electric field by the blocking electrode. Thermal poling performed to induce the optical nonlinearity in silica glass is basically identical to the process generating space charge polarization. As a first step to understand the mechanism of space charge polarization in silica glass hence the induced optical nonlinearity the absorption currents as functions of time were measured for various types of silica glasses and analyzed by the theory of space charge polarization. It was found that the electrical relaxation exhibited a step by the space charge polarization in the relatively long time range and dielectric loss peak showed a maximum at a specific temperature which is depending on type of silica glass. It was turned out that this relaxation might be a cause of nonlinearity in electrical conductivity of silica glass.

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Molecular Design of New Organic Electroluminescence Materials: DCM Derivatives

  • Seong, See-Yearl;Park, Sung-Soo;Seo, Jeong-In;No, Kyoung-Tai;Hong, Jong-In;Park, Su-Jin;Choi, Seung-Hoon;Lee, Han-Yong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.178-180
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    • 2003
  • We performed semiempirical (AMl and ZINDO) and ab initio (HF and DFT) calculations, to investigate molecular structures and optical properties of DCM and its derivatives. DCM and its derivatives are used as a red fluorescent dopant of the organic electroluminescent host materials, $Alq_3$. We have studied the relationship between the molecular structure and the optical properties of these molecules for the improvement of EL efficiencies. Wavelength at the absorption maximum was found to be red-shifted when the molecule is substituted with both strong electron donating and withdrawing functional groups. A new red fluorescent dye was predicted by QSPR study based on calculations and experimental data.

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Polarizing Photovoltaic Polymer Films for Reflective Solar-LCDs (편광 흡수성 광기전성 고분자 박막 연구)

  • Kim, Young-Chan;Huh, Yoon-Ho;Park, Byoung-Choo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.7
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    • pp.525-530
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    • 2012
  • We present the results of a study of the polarizing photovoltaic (PV) effects in an aligned polymer bulk heterojuction PV layer. The fairly uniform in-plane uniaxial alignment of the PV layer with a macroscopic axial orientational order parameter of 0.40 was achieved by means of a simple rubbing technique. Moreover, reflective polarizing PSCs having the aligned PV layers were applied to power-generating reflective type liquid crystal displays (LCDs), which exhibited a maximum contrast ratio of 1.7. These results form a promising foundation for various energy harvesting polarization dependent opto-electrical LCD device applications.